Citation: Yu LIANG, Xiu-Dian XU, Jian-Ling NI, Jun-Feng LI, Fang-Ming WANG. Synthesis, Structure and Fluorescence Property of New Cd-MOFs Based on a Tetraphenylethylene (TPE) Ligand[J]. Chinese Journal of Structural Chemistry, ;2021, 40(2): 193-198. doi: 10.14102/j.cnki.0254–5861.2011–2794 shu

Synthesis, Structure and Fluorescence Property of New Cd-MOFs Based on a Tetraphenylethylene (TPE) Ligand

School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China

Corresponding author: Fang-Ming WANG, wangfmzj@just.edu.cn
Received Date: 2 March 2020
Accepted Date: 15 May 2020

Fund Project: the National Natural Science Foundation of China 21671084

Figures(5)

A very stable Cd^Ⅱ-organic framework, {[Cd₃(Tipe)_1.5(bpodc)₂Cl₂]·(H₂O)₂}_n (compound 1, Tipe = 1, 1, 2, 2-tetrakis(4-(imidazol-1-yl)phenyl)ethene, bpodc = benzophenone-4, 4-dicarboxylic acid), has been successfully synthesized under hydrothermal conditions. Compound 1 crystallizes in the triclinic system, space group P\begin{document}$ \overline 1 $\end{document}, with a = 12.289(3), b = 15.951(4), c = 20.755(5) Å, α = 81.248(2)°, β = 83.905(2)°, γ = 89.452(2)°, V = 3998.2(17) Å³, Z = 2, M_r = 1839.59, D_c = 1.528 g/cm³, μ = 0.925 mm^-1, F(000) = 1844, R = 0.0508 and wR = 0.1571 for 13998 observed reflections (I > 2σ(I)). Its overall structure is a three-dimensional stacking with a porosity of 10.1% based on a calculation by PLATON. Compound 1 shows a blue fluorescence emission with the peak maximum of 501 nm (λ_ex = 397 nm) by ligand-to-ligand charge transfer of TPE chromophore. And it exhibits excellent performance in detecting Fe³⁺ and Cr₂O₇^2- ions in aqueous solutions as a multi-response sensor.
- tetraphenylethane,
- sensor,
- luminescent,
- metal-organic framework
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