Citation: Ying-Qun YANG, Lu-Yao TUO, Wei LI. Synthesis, Structure and Properties of a New Terbium(Ⅲ) Complex Tb₂(C₁₅H₁₁O₃)₆(2,2'-bipy)₂[J]. Chinese Journal of Structural Chemistry, ;2020, 39(7): 1331-1336. doi: 10.14102/j.cnki.0254–5861.2011–2789 shu

Synthesis, Structure and Properties of a New Terbium(Ⅲ) Complex Tb₂(C₁₅H₁₁O₃)₆(2,2'-bipy)₂

Ying-Qun YANG ^{a, b,,} ,
Lu-Yao TUO ^b ,
Wei LI ^{a, b,,}

a.
Key Laboratory of Functional Metal-organic Compounds of Hunan Province & Key Laboratory of Functional Organometallic Materials of Hunan Province College, Hengyang 421008, China
b.
Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008, China

Corresponding author: Ying-Qun YANG, yingqunyq@163.com Wei LI, li_weihnxy@163.com
Received Date: 26 February 2020
Accepted Date: 7 April 2020

Fund Project: the Foundation of Key Laboratory of Functional Metal-organic Compounds of Hunan Province MO20K05Hunan Provincial Natural Science Foundation of China 2019JJ60021Hunan Provincial Natural Science Foundation of China 2019JJ50013the Scientific Research Found of Hunan Provincial Education Department of China 17A049Industry and Research Key Project of Hengyang City 2019jhzx1093Industry and Research Key Project of Hengyang City 2018KJ016Industry and Research Key Project of Hengyang City 2017KJ155Industry and Research Key Project of Hengyang City 2017KJ193

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A new terbium(Ⅲ) complex Tb₂(C₁₅H₁₁O₃)₆(2,2'-bipy)₂ has been synthesized with 2-(4-methylbenzoyl)benzoic acid and 2,2'-bipy ligands. Crystal data for the complex: monoclinic, space group P2₁/n, a = 14.9738(5), b = 13.5469(4), c = 23.0683(7) Å, β = 103.950(3)°, V = 4541.4(3) Å³, D_c = 1.511 g/cm³, Z = 2, μ(MoKα) = 1.620 mm^-1, F(000) = 2088, the final R = 0.0318 and wR = 0.0727. The Tb(Ⅲ) ion is coordinated by eight atoms to give a distorted square antiprism coordination geometry. The complex shows three fluorescence emission bands arising from the transitions of Tb³⁺: ⁵D₄ → ⁷F₆ (490 nm), ⁵D₄ → ⁷F₅ (545 nm) and ⁵D₄ → ⁷F₄ (584 nm). The complex exhibits antiferromagnetism in the temperature range of 300~2 K. Also reported are the thermal stability properties of the complex.
- terbium(Ⅲ) complex,
- crystal structure,
- fluorescent and magnetic properties
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Synthesis, Structure and Properties of a New Terbium(Ⅲ) Complex Tb₂(C₁₅H₁₁O₃)₆(2,2'-bipy)₂