Citation: Yu-Peng HUA, Jing-Lin PANG, Yan-Peng GAO, Xue-Hong WEI. N, N, O-Tridentate One-dimensional Methyl-bridged Heterobimetallic Complex: Synthesis, Crystal Structure and Catalytic Activity[J]. Chinese Journal of Structural Chemistry, ;2020, 39(7): 1343-1349. doi: 10.14102/j.cnki.0254–5861.2011–2772 shu

N, N, O-Tridentate One-dimensional Methyl-bridged Heterobimetallic Complex: Synthesis, Crystal Structure and Catalytic Activity

Yu-Peng HUA ^{a, b} ,
Jing-Lin PANG ^a,, ,
Yan-Peng GAO ^a ,
Xue-Hong WEI ^b,,

a.
Ordos Institute of Technology, Ordos 017000, Inner Mongolia, China
b.
Scientific Instrument Center, Shanxi University, Taiyuan 030006, China

Corresponding author: Jing-Lin PANG, luozi139@163.com Xue-Hong WEI, luozi139@163.com
Received Date: 19 February 2020
Accepted Date: 14 April 2020

Fund Project: the Inner Mongolia Natural Science Foundation 2017BS0202the Major project of Ordos science and technology 2019ZD065the Scientific Research Project of Ordos Institute of Technology KYZD2018001Colleges and Universities' Scientific Research Project NJZY17401

Figures(2)

The sequential reaction of the N, N, O-tridentate ligand HOC(CH₂)₅CH₂N(Me)CH₂ CH₂NMe₂ (LH) in diethyl ether with AlEtCl₂ and MeLi afforded a lithium-aluminum complex containing a polymeric structure of one-dimensional chain [{-LiOC(CH₂)₅CH₂N(Me)CH₂CH₂NMe₂}AlMe₂CH₃-}_n] (1), which was characterized by ¹H, ¹³C NMR spectra, elemental analyses and single-crystal X-ray diffraction analysis. Complex 1 crystallizes in triclinic, space group P\begin{document}$ \overline 1 $\end{document} with a = 10.526(3), b = 10.949(3), c = 17.799(4) Å, β = 76.211(11)°, V = 1915.3(8) Å³, D_c = 1.014 g·cm^–3, F(000) = 648 and μ = 0.104 mm^–1. In addition, the heterobimetallic complex 1 was used to catalyze the Meerwein-Ponndorf-Verley (MPV) reaction and exhibited excellent catalytic activities in good yield (up to 97%).
- heterobimetallic complex,
- synthesis,
- characterization,
- catalytic reaction
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