Citation: Fei-Yan ZHANG, Kui XIE. Porous Iron- and Cobalt-based Single Crystals with Enhanced Electrocatalysis Performance[J]. Chinese Journal of Structural Chemistry, ;2021, 40(1): 61-69. doi: 10.14102/j.cnki.0254–5861.2011–2745 shu

Porous Iron- and Cobalt-based Single Crystals with Enhanced Electrocatalysis Performance

Fei-Yan ZHANG ^{a, b} ,
Kui XIE ^{a, b,,}

a.
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China
b.
Key Laboratory of Design & Assembly of Functional Nanostructures, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Kui XIE, kxie@fjirsm.ac.cn
Received Date: 20 January 2020
Accepted Date: 23 March 2020

Fund Project: the Natural Science Foundation of China 91845202the Natural Science Foundation of China 21750110433Dalian National Laboratory for Clean Energy DNL180404Strategic Priority Research Program of Chinese Academy of Sciences XDB2000000

Figures(8)

Porous single crystals have the characteristics of long-range ordering structure and large specific surface area, which will significantly enhance their electrochemical performance. Here, we report a method different from the conventional porous single crystal growth method. This method is to directly convert single crystal precursors Co₃O₄ and Fe₃O₄ into Co₂N and Fe₂N, and then further reduces them to porous single crystals Co and Fe particles under H₂/Ar atmosphere. The removal of O^2– in the lattice channel at the pressure of 25~300 torr and the temperature of 300~600 ℃ will promote nitridation of the single-crystalline Co–O and Fe–O frames, and further remove N^3– in H₂/Ar atmosphere and recrystallize as Co and Fe. These porous single crystals exhibit enhanced electrochemical properties due to their structural coherence and highly active surface. We demonstrated that the aminobenzene yield was up to 91% and the selectivity reached 92% in the electrochemical reduction of nitrobenzene.
- porous single crystal,
- crystal growth,
- electrocatalysis
1. [1]
  Krishna, R. Diffusion in porous crystalline materials. Chem. Soc. Rev. 2012, 8, 3099–3118.
2. [2]
  Valtchev, V.; Tosheva, L. Porous nanosized particles: preparation, properties, and applications. Chem. Rev. 2013, 8, 6734–6760.
3. [3]
  Qiu, H. J.; Xu, H. T.; Liu, L.; Wang, Y. Correlation of the structure and applications of dealloyed nanoporous metals in catalysis and energy conversion/storage. Nanoscale 2015, 2, 386–400.
4. [4]
  Hoang, T. T. H.; Verma, S.; Ma, S.; Fister, T. T.; Timoshenko, J.; Frenkel, A. I.; Kenis, P. J. A.; Gewirth, A. A. Nanoporous copper silver alloys by additive-controlled electrodeposition for the selective electroreduction of CO₂ to ethylene and ethanol. J. Am. Chem. Soc. 2018, 17, 5791–5797.
5. [5]
  Zhu, H. W.; Jing, Y. K.; Pal, M.; Liu, Y. P.; Liu, Y.; Wang, J. X.; Zhang, F.; Zhao, D. Y. Mesoporous TiO₂@N-doped carbon composite nanospheres synthesized by the direct carbonization of surfactants after sol-gel process for superior lithium storage. Nanoscale 2017, 4, 1539–1546.
6. [6]
  Sheberla, D.; Bachman, J. C.; Elias, J. S.; Sun, C. J.; Shao-Horn, Y.; Dinca, M. Conductive MOF electrodes for stable supercapacitors with high areal capacitance. Nat. Mater. 2017, 2, 220–224.
7. [7]
  Yang, L.; Zeng, X. F.; Wang, W. C.; Cao, D. P. Recent progress in MOF-derived, heteroatom-doped porous carbons as highly efficient electrocatalysts for oxygen reduction reaction in fuel cells. Adv. Funct. Mater. 2018, 7, 1704537–21.
8. [8]
  Dhakshinamoorthy, A.; Asiri, A. M.; Garcia, H. Metal-organic framework (MOF) compounds: photocatalysts for redox reactions and solar fuel production. Angew. Chem. Int. Ed. 2016, 18, 5414–5445.
9. [9]
  Huang, Y. B.; Liang, J.; Wang, X. S.; Cao, R. Multifunctional metal-organic framework catalysts: synergistic catalysis and tandem reactions. Chem. Soc. Rev. 2017, 1, 126–157. doi: 10.15199/62.2017.10.21
10. [10]
  Chen, C. L.; Sun, S. J.; Chou, M. M. C.; Xie, K. In situ inward epitaxial growth of bulk macroporous single crystals. Nat. Commun. 2017, 8, 2178–8. doi: 10.1038/s41467-017-02197-6
11. [11]
  Lin, G. M.; Xi, S. B.; Pan, C. C.; Lin, W. L.; Xie, K. Growth of 2 cm metallic porous TiN single crystals. Mater. Horiz. 2018, 5, 953–960. doi: 10.1039/C8MH00494C
12. [12]
  Zhang, F. Y.; Xi, S. B.; Lin, G. M.; Hu, X. L.; Lou, X. W.; Xie, K. Metallic porous iron nitride and tantalum nitride single crystals with enhanced electrocatalysis performance. Adv. Mater. 2019, 7, 1806552–7.
13. [13]
  Cheng, F. Y.; Lin, G. M.; Hu, X. L.; Xi, S. B.; Xie, K. Porous single-crystalline titanium dioxide at 2 cm scale delivering enhanced photoelectrochemical performance. Nat. Commun. 2019, 10, 3618–9. doi: 10.1038/s41467-019-11623-w
14. [14]
  Xi, S. B.; Lin, G. M.; Jin, L.; Li, H.; Xie, K. Metallic porous nitride single crystals at two-centimeter scale delivering enhanced pseudocapacitance. Nat. Commun. 2019, 10, 4727–9. doi: 10.1038/s41467-019-12818-x
15. [15]
  Zhang, J. H.; Kong, Q. H.; Du, J.; Ma, D. K.; Xi, G. C.; Qian, Y. T. Formation, characterization, and magnetic properties of Fe₃O₄ microoctahedrons. J. Cryst. Growth 2007, 1, 159–165.
16. [16]
  Xiao, X. L.; Liu, X. F.; Zhao, H.; Chen, D. F.; Liu, F. Z.; Xiang, J. H.; Hu, Z. B.; Li, Y. D. Facile shape control of Co₃O₄ and the effect of the crystal plane on electrochemical performance. Adv. Mater. 2012, 42, 5762–5766.
17. [17]
  Kresse, G.; Furthmuller, J. Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set. Phys. Rev. B 1996, 54, 11169–11186. doi: 10.1103/PhysRevB.54.11169
18. [18]
  Sheng, T.; Qi, Y. J.; Lin, X.; Hu, P.; Sun, S. G.; Lin, W. F. Insights into the mechanism of nitrobenzene reduction to aniline over Pt catalyst and the significance of the adsorption of phenyl group on kinetics. Chem. Eng. J. 2016, 293, 337–344. doi: 10.1016/j.cej.2016.02.066
19. [19]
  Zhang, Y. Q.; Ouyang, B.; Xu, J.; Jia, G. C.; Chen, S.; Rawat, R. S.; Fan, H. J. Rapid synthesis of cobalt nitride nanowires: highly efficient and low-cost catalysts for oxygenevolution. Angew. Chem. Int. Ed. 2016, 55, 8670–8674. doi: 10.1002/anie.201604372
20. [20]
  Soto, G.; de la Cruz, W.; Farias, M. H. XPS, AES, and EELS characterization of nitrogen-containing thin films. J. Electron Spectrosc. Relat. Phenom. 2004, 135, 27–39. doi: 10.1016/j.elspec.2003.12.004
21. [21]
  Biwer, B. M.; Bernasek, S. L. Electron spectroscopic study of the iron surface and its interaction with oxygen and nitrogen. J. Electron Spectrosc. Relat. Phenom. 1986, 40, 339–351. doi: 10.1016/0368-2048(86)80044-5
22. [22]
  Soto, G.; de la Cruz, W.; Farias, M. H. XPS, AES, and EELS characterization of nitrogen-containing thin films. J. Electron Spectrosc. Relat. Phenom. 2004, 135, 27–39. doi: 10.1016/j.elspec.2003.12.004
1. [1]
  Hao WANG , Kun TANG , Jiangyang SHAO , Kezhi WANG , Yuwu ZHONG . Electro-copolymerized film of ruthenium catalyst and redox mediator for electrocatalytic water oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2193-2202. doi: 10.11862/CJIC.20240176
2. [2]
  Rui PAN , Yuting MENG , Ruigang XIE , Daixiang CHEN , Jiefa SHEN , Shenghu YAN , Jianwu LIU , Yue ZHANG . Selective electrocatalytic reduction of Sn(Ⅳ) by carbon nitrogen materials prepared with different precursors. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1015-1024. doi: 10.11862/CJIC.20230433
3. [3]
  Zhijia Zhang , Shihao Sun , Yuefang Chen , Yanhao Wei , Mengmeng Zhang , Chunsheng Li , Yan Sun , Shaofei Zhang , Yong Jiang . Epitaxial growth of Cu_2-xSe on Cu (220) crystal plane as high property anode for sodium storage. Chinese Chemical Letters, 2024, 35(7): 108922-. doi: 10.1016/j.cclet.2023.108922
4. [4]
  Fengyu Zhang , Yali Liang , Zhangran Ye , Lei Deng , Yunna Guo , Ping Qiu , Peng Jia , Qiaobao Zhang , Liqiang Zhang . Enhanced electrochemical performance of nanoscale single crystal NMC811 modification by coating LiNbO₃. Chinese Chemical Letters, 2024, 35(5): 108655-. doi: 10.1016/j.cclet.2023.108655
5. [5]
  Min Chen , Boyu Peng , Xuyun Guo , Ye Zhu , Hanying Li . Polyethylene interfacial dielectric layer for organic semiconductor single crystal based field-effect transistors. Chinese Chemical Letters, 2024, 35(4): 109051-. doi: 10.1016/j.cclet.2023.109051
6. [6]
  Zhenfei Tang , Yunwu Zhang , Zhiyuan Yang , Haifeng Yuan , Tong Wu , Yue Li , Guixiang Zhang , Xingzhi Wang , Bin Chang , Dehui Sun , Hong Liu , Lili Zhao , Weijia Zhou . Iron-doping regulated light absorption and active sites in LiTaO₃ single crystal for photocatalytic nitrogen reduction. Chinese Chemical Letters, 2025, 36(3): 110107-. doi: 10.1016/j.cclet.2024.110107
7. [7]
  Ran HUO , Zhaohui ZHANG , Xi SU , Long CHEN . Research progress on multivariate two dimensional conjugated metal organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2063-2074. doi: 10.11862/CJIC.20240195
8. [8]
  Wenli Xu , Yingzhao Zhang , Rui Wang , Chenyang Liu , Jialin Liu , Xiangyu Huo , Xinying Liu , He Zhang , Jianxu Ding . In-situ passivating surface defects of ultra-thin MAPbBr3 perovskite single crystal films for high performance photodetectors. Chinese Journal of Structural Chemistry, 2025, 44(1): 100454-100454. doi: 10.1016/j.cjsc.2024.100454
9. [9]
  Jiakun Bai , Junhui Jia , Aisen Li . An elastic organic crystal with piezochromic luminescent behavior. Chinese Journal of Structural Chemistry, 2024, 43(6): 100323-100323. doi: 10.1016/j.cjsc.2024.100323
10. [10]
  Pingfan Zhang , Shihuan Hong , Ning Song , Zhonghui Han , Fei Ge , Gang Dai , Hongjun Dong , Chunmei Li . Alloy as advanced catalysts for electrocatalysis: From materials design to applications. Chinese Chemical Letters, 2024, 35(6): 109073-. doi: 10.1016/j.cclet.2023.109073
11. [11]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542
12. [12]
  Jun Lu , Jinrui Yan , Yaohao Guo , Junjie Qiu , Shuangliang Zhao , Bo Bao . Controlling solid form and crystal habit of triphenylmethanol by antisolvent crystallization in a microfluidic device. Chinese Chemical Letters, 2024, 35(4): 108876-. doi: 10.1016/j.cclet.2023.108876
13. [13]
  Ce Liang , Qiuhui Sun , Adel Al-Salihy , Mengxin Chen , Ping Xu . Recent advances in crystal phase induced surface-enhanced Raman scattering. Chinese Chemical Letters, 2024, 35(9): 109306-. doi: 10.1016/j.cclet.2023.109306
14. [14]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
15. [15]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273
16. [16]
  Chen Chen , Jinzhou Zheng , Chaoqin Chu , Qinkun Xiao , Chaozheng He , Xi Fu . An effective method for generating crystal structures based on the variational autoencoder and the diffusion model. Chinese Chemical Letters, 2025, 36(4): 109739-. doi: 10.1016/j.cclet.2024.109739
17. [17]
  Peng Jia , Yunna Guo , Dongliang Chen , Xuedong Zhang , Jingming Yao , Jianguo Lu , Liqiang Zhang . In-situ imaging electrocatalysis in a solid-state Li-O₂ battery with CuSe nanosheets as air cathode. Chinese Chemical Letters, 2024, 35(5): 108624-. doi: 10.1016/j.cclet.2023.108624
18. [18]
  Ze Zhang , Lei Yang , Jin-Ru Liu , Hao Hu , Jian-Li Mi , Chao Su , Bei-Bei Xiao , Zhi-Min Ao . Improved oxygen electrocatalysis at FeN₄ and CoN₄ sites via construction of axial coordination. Chinese Chemical Letters, 2025, 36(2): 110013-. doi: 10.1016/j.cclet.2024.110013
19. [19]
  Na Wang , Wang Luo , Huaiyi Shen , Huakai Li , Zejiang Xu , Zhiyuan Yue , Chao Shi , Hengyun Ye , Leping Miao . Crystal engineering regulation achieving inverse temperature symmetry breaking ferroelasticity in a cationic displacement type hybrid perovskite system. Chinese Chemical Letters, 2024, 35(5): 108696-. doi: 10.1016/j.cclet.2023.108696
20. [20]
  Zhi-Yuan Yue , Hua-Kai Li , Na Wang , Shan-Shan Liu , Le-Ping Miao , Heng-Yun Ye , Chao Shi . Dehydration-triggered structural phase transition-associated ferroelectricity in a hybrid perovskite-type crystal. Chinese Chemical Letters, 2024, 35(10): 109355-. doi: 10.1016/j.cclet.2023.109355

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(498)
HTML views(14)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142