Citation: Qiang-Qiang JIA, Jun-Yi LI, Hao-Xi ZHANG, Li-Zhuang CHEN, Guo-Xi WANG. Synthesis, Crystal Structure and Properties of a Copper(I) Coordination Polymer Based on Benzimidazole Derivative[J]. Chinese Journal of Structural Chemistry, ;2020, 39(11): 2021-2026. doi: 10.14102/j.cnki.0254–5861.2011–2739 shu

Synthesis, Crystal Structure and Properties of a Copper(I) Coordination Polymer Based on Benzimidazole Derivative

School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China

Corresponding author: Li-Zhuang CHEN, clz1977@sina.com
Received Date: 16 January 2020
Accepted Date: 24 March 2020

Fund Project: the National Natural Science Foundation of China NSFC21671084

Figures(8)

A novel copper(I) coordination polymer [C₃₀H₁₈Cu₃Cl₃N₄]_n was solvethermally synthesized with 1-(prop-2-en-1-yl)-2-{4-[1-(prop-2-en-1-yl)-1H-1, 3-benzodiazol-2-yl]phenyl}-1H-1, 3-benzodiazole as the flexible ligand. It crystalizes in orthorhombic system, space group Pbcn with a = 22.0890(7), b = 6.3626(2), c = 18.2480(6) Å, V = 2564.64(14) Å³ and M_r = 365.73. The compound characterized by elemental analysis, infrared spectroscopy and powder X-ray diffraction analysis displays a 2D structure. The complex shows strong green luminescence at 506 nm and better property of electrochemical oxygen evolution.
- bisbenzimidazole ligand,
- copper(I) coordination polymer,
- crystal structure,
- electrocatalytic property
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