Citation: Xi-Lai XUE, Xiang-Xin ZHANG, Jun-Hong LIN, Su-Jing CHEN, Yuan-Qiang CHEN, Yong-Chuan LIU, Yi-Ning ZHANG. Effects of Bulky LATP in PEO-based Hybrid Solid Electrolytes[J]. Chinese Journal of Structural Chemistry, ;2020, 39(11): 1941-1948. doi: 10.14102/j.cnki.0254–5861.2011–2738 shu

Effects of Bulky LATP in PEO-based Hybrid Solid Electrolytes

Xi-Lai XUE ^{a, b} ,
Xiang-Xin ZHANG ^{a, c} ,
Jun-Hong LIN ^{a, c} ,
Su-Jing CHEN ^{a, c} ,
Yuan-Qiang CHEN ^{a, c} ,
Yong-Chuan LIU ^{a, b, c} ,
Yi-Ning ZHANG ^{a, b, c,,}

a.
Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China
c.
Dalian National Laboratory for Clean Energy, Chinese Academy of Sciences, Dalian 161000, China

Corresponding author: Yi-Ning ZHANG, ynzhang@fjirsm.ac.cn
Received Date: 15 January 2020
Accepted Date: 6 March 2020

Fund Project: the Fujian Provincial Science and Technology Program 2018H0042the Fujian Provincial Science and Technology Program No. 2018H0042, 2019T3017Putian Municipal Science and Technology Program 2019HJSTS009the DNL Cooperation Fund, CAS DNL180308

Figures(5)

Solid polymer electrolytes (SPEs) have been considered as the spotlight in recent years due to their high safety, non-flammability and good flexibility. Nonetheless, high crystallinity of polymer matrix leads to low ionic conductivity at ambient conditions and retards the practical applications of SPEs. Herein, we report hybrid solid electrolytes (HSE) containing bulky LATP in poly(ethylene oxide) (PEO) matrix, which significantly enhances the electrochemical properties. LATP has been easily obtained by an accessible solid-state method. The solid electrolyte based on 20 wt% LATP in PEO polymer matrix (abbreviated as PEO-20) exhibits an ionic conductivity of 2.1 ×10^–5 S·cm^–1 at 30 ℃, an order of magnitude higher than 2.9 × 10^–6 S·cm^–1 of the pristine PEO solid electrolyte (abbreviated as PEO–0), mainly resulting from the decline of crystallinity in polymer matrix. The electrochemical window of PEO-20 can reach 4.84 V at room temperature, compared with 4.40 V for PEO-0, which could be compatible with high-voltage cathode materials.
- hybrid solid electrolytes,
- bulky LATP,
- polyethylene oxide
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