Citation: Zhao-Ting LIN, Yu-Ling WANG, Qing-Yan LIU. Crystal Structure and Luminescence of a Cd(II) Compound Based on the 3, 3΄, 5, 5΄-Tetrafluorobiphenyl- 4, 4΄-dicarboxylate and Adenine Ligands[J]. Chinese Journal of Structural Chemistry, ;2020, 39(11): 2041-2045. doi: 10.14102/j.cnki.0254–5861.2011–2736 shu

Crystal Structure and Luminescence of a Cd(II) Compound Based on the 3, 3΄, 5, 5΄-Tetrafluorobiphenyl- 4, 4΄-dicarboxylate and Adenine Ligands

College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China

Corresponding author: Qing-Yan LIU, qyliuchem@jxnu.edu.cn
Received Date: 13 January 2020
Accepted Date: 15 March 2020

Fund Project: the National Natural Science Foundation of China 21661014Natural Science Foundation of Jiangxi Province 20171ACB20008Natural Science Foundation of Jiangxi Province 20181BAB203001

Figures(5)

A one-dimensional (1D) coordination polymer, [Cd₂(TFBPDC)₂(ad)₂(CH₃OH)₂]_n (1), based on the 3, 3΄, 5, 5΄-tetrafluorobiphenyl-4, 4΄-dicarboxylate (TFBPDC^2–) and adenine (ad) ligands, was synthesized. Compound 1 crystallizes in the triclinic system, space group P\begin{document}$ \overline 1 $\end{document} with a = 9.7067(3), b = 9.9501(3), c = 11.6903(4) Å, α = 93.036(3), β = 107.793(3), γ = 107.107(3)°, V = 1014.77(6) Å³, Z = 2, C₄₀H₂₆F₈N₁₀O₁₀Cd₂, M_r = 1183.51, D_c = 1.937 g/cm³, μ = 1.160 mm^–1, F(000) = 584, the final R = 0.0284 and wR = 0.0635 for 3791 observed reflections with I > 2σ(I). In 1, a pair of adenine (ad) ligands bridge two octahedrally coordinated Cd(II) atoms to form a dinuclear [Cd₂(ad)₂] unit, which is linked by TFBPDC^2– to generate a 1D double chain. The neighboring chains are connected by N–H⋅⋅⋅O hydrogen bonds to give a two-dimensional (2D) layer, which is further linked by the O–H⋅⋅⋅N hydrogen bonds to give a three-dimensional (3D) supramolecular framework. IR spectrum, thermo- gravimetric analysis, and powder X-ray diffraction of 1 were provided. Compound 1 shows luminescent emission.
- cadmium coordination polymer,
- 3,
- 3΄,
- 5,
- 5΄-tetrafluorobiphenyl-4,
- 4΄-dicarboxylate,
- adenine,
- luminescence,
- crystal structure
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