Citation: Jian-Han ZHANG, Sheng-Hua ZHOU, Hua LIN. Dimensionality Reducing from Three-dimensional RbLu₅Te₈ to Two-dimensional CsMnGdTe₃: Syntheses, Crystal and Electronic Structures[J]. Chinese Journal of Structural Chemistry, ;2020, 39(10): 1770-1780. doi: 10.14102/j.cnki.0254–5861.2011–2724 shu

Dimensionality Reducing from Three-dimensional RbLu₅Te₈ to Two-dimensional CsMnGdTe₃: Syntheses, Crystal and Electronic Structures

Jian-Han ZHANG ^{a, b} ,
Sheng-Hua ZHOU ^b ,
Hua LIN ^b,,

a.
School of Resources & Chemical Engineering, Sanming University, Sanming 365004, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Hua LIN, linhua@fjirsm.ac.cn
Received Date: 20 January 2020
Accepted Date: 13 February 2020

Fund Project: the National Natural Science Foundation of China 21771179the National Natural Science Foundation of China 21301175the Natural Science Foundation of Fujian Province 2019J01133the Foundation of State Key Laboratory of Structural Chemistry 20190033Distinguished Young Scientific Research Talents Plan in Universities of Fujian Province [2018]47

Figures(9)

Two new rare-earth metal chalcogenides, namely RbLu₅Te₈ and CsMnGdTe₃, have been successfully synthesized under high-temperature solid-state reaction conditions and structurally characterized by single-crystal X-ray diffraction analysis. RbLu₅Te₈ belongs to the monoclinic space group C2/m (no. 12) with two formula units in a unit cell: a = 22.075(5), b = 4.2987(8), c = 10.588(2) Å, β = 103.89(2)°, V = 975.4(4) Å³, whereas CsMnGdTe₃ crystallizes in the orthorhombic space group Cmcm (no. 63) with four formula units in a unit cell: a = 4.4872(8), b = 16.769(3), c = 11.807(2) Å and V = 888.4(3) Å³. In the structure of RbLu₅Te₈, face-, edge- and vertex-sharing [LuTe₆] octahedra are interconnected to produce a three-dimensional (3D) framework with Rb⁺ lying in the tunnels. The crystal structure of CsMnGdTe₃ consists of two-dimensional (2D) [MnGdTe₃]^– layers of edge- and vertex-sharing [GdTe₆] octahedra with Mn atoms filling the tetrahedral interstices, which stack along the b-axis. The Cs atoms are located between the [MnGdTe₃]^– layers and surrounded by eight Te atoms to form a [CsTe₈] bicapped trigonal prism. Moreover, theoretical studies have aided the understanding of their electronic structures.
- rare-earth telluride,
- structural dimension,
- high-temperature solid-state reaction,
- crystal structure,
- electronic structures
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Dimensionality Reducing from Three-dimensional RbLu5Te8 to Two-dimensional CsMnGdTe3: Syntheses, Crystal and Electronic Structures

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通讯作者: 陈斌, bchen63@163.com

Dimensionality Reducing from Three-dimensional RbLu₅Te₈ to Two-dimensional CsMnGdTe₃: Syntheses, Crystal and Electronic Structures