Citation: Chang WANG, Zi-Wei HE, Yuan-Yuan WANG, Shuai-Shuai HAN, Shui-Sheng CHEN. A New Zn(II) Complex Based on Mixed Ligands: Synthesis, Crystal Structure and Optical Properties[J]. Chinese Journal of Structural Chemistry, ;2020, 39(10): 1855-1861. doi: 10.14102/j.cnki.0254–5861.2011–2723 shu

A New Zn(II) Complex Based on Mixed Ligands: Synthesis, Crystal Structure and Optical Properties

School of Chemistry and Chemical Engineering, Fuyang Normal University, Fuyang 236041, China

Corresponding author: Shui-Sheng CHEN, sscfync@163.com
Received Date: 1 January 2020
Accepted Date: 19 February 2020

Fund Project: the Youth Talent Program from Anhui Province gxbjZD19National College Students Innovation Training Program 201910371022

Figures(9)

A new complex {[Zn₂(L)(cpa)₂]·H₂O}_n (1) was prepared under hydrothermal conditions based on 4-carbonylphenylacetic acid (H₂cpa) with multi-N-donor ligand 1, 4-di(1H-imidazol-4-yl)benzene (L). The complex was characterized by IR spectroscopy, TGA, X-ray powder and single-crystal diffraction. It crystallizes in the orthorhombic system, space group Pbca with a = 8.6427(9), b = 16.1616(17), c = 20.941(2) Å, V = 2925.0(5) Å³, Z = 8, C₁₅H₁₃N₂O₅Zn, M_r = 366.64, D_c = 1.665 g/cm³, μ = 1.707 mm^-1, S = 1.011, F(000) = 1496, the final R = 0.0385 and wR = 0.0945 for 3360 observed reflections (I > 2σ(I)). The central metal Zn(II) atom with distorted ZnO₃N tetrahedral coordination geometry is four-coordinated by three oxygen and one nitrogen atoms. The cpa^2- ligands connect Zn(II) atoms to form two-dimensional (2D) double-layer networks which are further pillared by L ligands into a binodal (3, 4)-connected three-dimensional (3D) architecture with a (6³·10³)(6³) tcj/hc topology. Solid-state luminescent property together with quantum yield (QY) and luminescence lifetime is also investigated for compound 1.
- synthesis,
- metal-organic frameworks,
- optical property
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