Citation: Meng-Ying LV, Cong LV, Guo-Song YAN, Shi ZHOU, Wei JIANG, Bo LIU, Xiu-Mei LI. Syntheses, Crystal Structures and Fluorescent Properties of Two Zinc Complexes Assembled by Bis(imidazol) Ligands[J]. Chinese Journal of Structural Chemistry, ;2020, 39(10): 1885-1891. doi: 10.14102/j.cnki.0254–5861.2011–2709 shu

Syntheses, Crystal Structures and Fluorescent Properties of Two Zinc Complexes Assembled by Bis(imidazol) Ligands

Meng-Ying LV ^a ,
Cong LV ^a ,
Guo-Song YAN ^a ,
Shi ZHOU ^a ,
Wei JIANG ^a ,
Bo LIU ^a,, ,
Xiu-Mei LI ^b,,

a.
Key Laboratory of Preparation and Applications of Environmental Friendly Materials (Jilin Normal University), Ministry of Education, Changchun 130103, China
b.
Faculty of Chemistry, Tonghua Normal University, Tonghua 134002, China

Corresponding author: Bo LIU, 112363305@qq.com Xiu-Mei LI, lixm20032006@163.com
Received Date: 20 December 2019
Accepted Date: 5 February 2020

Fund Project: the Science and Technology Development Plan of Jilin Province 2015052006JHGraduate Innovation Program of Jilin Normal University 201939

Figures(5)

Two new complexes [Zn(nph)(bix)]_n·nH₂O (1) and [Zn(nba)₂(bix)]_n (2) (H₂nph = 4-nitrophthalic acid, Hnba = 4-nitrobenzoic acid, bix = 1, 4-bis(imidazol-1-yl)-benzene) have been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectrum, fluorescence spectrum, single-crystal and power X-ray diffraction. Complex 1 exhibits a three-dimensional (3D) framework, which is stabilized through C–H···O hydrogen bonds and π-π stacking interactions. Complex 2 shows a zero-dimensional structure, which is further extended into a three-dimensional supramolecular structure through C–H···O and C–H···N hydrogen bonding interactions.
- hydrothermal synthesis,
- crystal structure,
- Zn(II) complex,
- 1, 4-bis(imidazol-1-yl)-benzene
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