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Citation: Jing-Jing CHEN, Yu-Ying ZHENG. [Y(IO3)3(H2O)2]n: a New Rare Earth Iodate Featuring the Circle-shaped I4O12 Polyiodate Anion and Three-order Nonlinear Optical Property[J]. Chinese Journal of Structural Chemistry, ;2020, 39(7): 1307-1313. doi: 10.14102/j.cnki.0254–5861.2011–2580 shu

[Y(IO3)3(H2O)2]n: a New Rare Earth Iodate Featuring the Circle-shaped I4O12 Polyiodate Anion and Three-order Nonlinear Optical Property

  • College of Material Science and Engineering, Fuzhou University, Fuzhou 350108, China

  • Corresponding author: Yu-Ying ZHENG, yyzheng@fzu.edu.cn
  • Received Date: 24 August 2019
    Accepted Date: 27 September 2019

Figures(5)

  • A new layered yttrium iodate [Y(IO3)3(H2O)2]n (1) has been prepared from the hydrothermal reaction of Y(NO3)3·6H2O with I2O5 at 170 ℃, and its structure was determined by X-ray single-crystal diffraction method. It belongs to the triclinic system, space group P\begin{document}$ \overline 1 $\end{document} with a = 7.355(5), b = 7.515(5), c = 9.413(7) Å, α = 79.65(2)º, β = 85.18(3)º, γ = 71.870(19)º, Z = 2, V = 486.2(6) Å3. 1 was further characterized by FTIR, powder X-ray diffraction (PXRD) and UV-Vis spectra. In 1, the Y centers in a monocapped trigonal prism environment are bound by IO3- anion and unique circle-shaped I4O12 polyiodate anion to generate a wave-like 2-D layer. The adjacent layers are further linked with each other by hydrogen bonds to form a quasi-3-D supramolecular network. 1 exhibits a reverse saturation absorption and a self-defocusing effect with the nonlinear absorption coefficient β being –0.66 × 10-5 mW-1, which stems mainly from the electron transition from O-2p to I-5p orbital within iodates upon theoretical calculation.
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