Citation: Bo XU, Xiao-Dong YANG, Ling-Xue KONG. Structure and Thermochromic Property of a Silver(Ⅰ) Complex Based on Dicyanamide and Phosphine Ligands[J]. Chinese Journal of Structural Chemistry, ;2020, 39(7): 1301-1306. doi: 10.14102/j.cnki.0254–5861.2011–2566 shu

Structure and Thermochromic Property of a Silver(Ⅰ) Complex Based on Dicyanamide and Phosphine Ligands

School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China

Corresponding author: Bo XU, chm_xub@ujn.edu.cn
Received Date: 8 August 2019
Accepted Date: 22 November 2019

Fund Project: the China Postdoctoral Science Foundation 2017M612174the Science and Technology Project of University of Jinan XKY1826

Figures(6)

A new silver(Ⅰ) complex {Ag₂(dppm)₂[N(CN)₂]}₂[μ-N(CN)₂]₂ (1) with chelate ligand bis(diphenyl-phosphino)methane (dppm) and bridging ligand dicyanamide (N(CN)₂) was carefully synthesized and fully characterized by single-crystal X-ray crystallography, IR spectrometry, high-resolution mass spectrometry, thermal analysis and ¹H NMR. According to the crystal structure analysis, this complex could be considered as two binucleate moieties {Ag₂(dppm)₂[N(CN)₂]}⁺ linked by two bridging anionic ligands N(CN)₂⁻. It exhibits thermochromic property in solid state. The dependence of color or emission of substance on temperature is known as thermochromism. Various temperature luminescences of complex 1 are tested. Along with the reduction of temperature from 298 K to 77 K, a noticeable emission enhancement as well as lifetime extension is observed.
- silver complex,
- crystal structure,
- dicyanamide,
- bis(diphenylphosphino)methane,
- thermochromic property
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