Citation: Li-Ping XUE, Ke-Xin DING. Synthesis, Structure and Luminescence Property of a New Two-dimensional Znic(Ⅱ) Coordination Polymer[J]. Chinese Journal of Structural Chemistry, ;2020, 39(7): 1295-1300. doi: 10.14102/j.cnki.0254–5861.2011–2561 shu

Synthesis, Structure and Luminescence Property of a New Two-dimensional Znic(Ⅱ) Coordination Polymer

Li-Ping XUE ^a,, ,
Ke-Xin DING ^b

a.
College of Food and Drug, Luoyang Normal University, Luoyang 471934, China
b.
College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471934, China

Corresponding author: Li-Ping XUE, lpxue@163.com
Received Date: 1 August 2019
Accepted Date: 15 November 2019

Fund Project: the National Natural Science Foundation of China 21401097

Figures(7)

Based on 5-dimethylamino-isophthalic acid (H₂dia) and 1,2-bis(4-pyridyl)ethylene (bpe) mixed linkers, a new d¹⁰-configuration Zn(Ⅱ) coordination polymer material, [Zn(dia)(bpe)(H₂O)]_n (1), was synthesized. In the asymmetric unit, there are one Zn²⁺ ion, two dia²⁻ anions, one neutral bpe linker and one free H₂O molecule. In the complex, adjacent Zn²⁺ ions are alternately bridged by the dia²⁻ dianions to generate chains which are further connected by flexible bpe ligands to form a two-dimensional (2D) layer structure. In topology, the structure of 1 represents a non-interpenetrating 4-connected sql topology. Moreover, infrared spectroscopy, elemental analyses, thermogravimetric analysis, powder X-ray diffraction, solid UV-Vis absorption spectra and photoluminescent property of 1 are also investigated.
- Zn coordination polymer,
- crystal structure,
- 5-dimethylamino-isophthalic acid,
- 1,2-bis(4-pyridyl)ethylene,
- UV-Vis absorption spectra,
- luminescence property
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