Citation: Shujiao Yang, Lingshuang Qin, Wei Zhang, Rui Cao. The Mechanism of Water Oxidation from Mn-Based Heterogeneous Electrocatalysts[J]. Chinese Journal of Structural Chemistry, ;2022, 41(4): 220402. doi: 10.14102/j.cnki.0254-5861.2022-0029 shu

The Mechanism of Water Oxidation from Mn-Based Heterogeneous Electrocatalysts

Shujiao Yang ¹ ,
Lingshuang Qin ¹ ,
Wei Zhang ^1,, ,
Rui Cao ^1,,

1.
Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, China

Corresponding author: Wei Zhang, zw@snnu.edu.cn Rui Cao, ruicao@snnu.edu.cn
Received Date: 17 February 2022
Accepted Date: 12 March 2022

Figures(10)

Searching for a renewable energy system is always the goal to fulfill sustainable deve-lopment for the future. Water oxidation is considered as a crucial reaction to attain sustainable energy systems. Inspired by the biological Mn₄CaO₅ cluster, considerable effort has been devoted to deve-loping highly efficient Mn-based heterogeneous catalysts and exploring intrinsic mechanism for water oxidation. This review begins with describing the structural characteristics of the Mn₄CaO₅ cluster and the proposed catalytic cycle. Then, the structural characteristics of synthetic Mn-based heterogeneous catalyst are summarized, with emphasis on the understanding of reaction mechanisms and the rate-determining steps. Finally, the strategy of understanding the catalytic mechanism of Mn-based water oxidation is prospected.
- water oxidation,
- Mn-based electrocatalysts,
- oxygen evolution reaction,
- structure,
- mechanism
1. [1]
  Cook, T. R.; Dogutan, D. K.; Reece, S. Y.; Surendranath, Y.; Teets, T. S.; Nocera, D. G. Solar energy supply and storage for the legacy and nonlegacy worlds. Chem. Rev. 2010, 110, 6474‒6502.
2. [2]
  Benson, E. E.; Kubiak, C. P.; Sathrum, A. J.; Smieja, J. M. Electrocatalytic and homogeneous approaches to conversion of CO₂ to liquid fuels. Chem. Soc. Rev. 2009, 38, 89‒99. doi: 10.1039/B804323J
3. [3]
  Turner, J. A. Sustainable hydrogen production. Science 2004, 305, 972‒974. doi: 10.1126/science.1103197
4. [4]
  Marini, S.; Salvi, P.; Nelli, P.; Pesenti, R.; Villa, M.; Berrettoni, M.; Zangari, G.; Kiros, Y. Advanced alkaline water electrolysis. Electrochim. Acta 2012, 82, 384‒391.
5. [5]
  Qi, J.; Zhang, W.; Cao, R. Solar-to-hydrogen energy conversion based on water splitting. Adv. Energy Mater. 2018, 8, 1701620.
6. [6]
  Cheng, F.; Chen, J. Metal-air batteries: from oxygen reduction electrochemistry to cathode catalysts. Chem. Soc. Rev. 2012, 41, 2172‒2192.
7. [7]
  Suen, N. T.; Hung, S. F.; Quan, Q.; Zhang, N.; Xu, Y. J.; Chen, H. M. Electrocatalysis for the oxygen evolution reaction: recent development and future perspectives. Chem. Soc. Rev. 2017, 46, 337‒365. doi: 10.1039/C6CS00328A
8. [8]
  Hong, W. T.; Risch, M.; Stoerzinger, K. A.; Grimaud, A.; Suntivich, J.; Shao-Horn, Y. Toward the rational design of non-precious transition metal oxides for oxygen electrocatalysis. Energy Environ. Sci. 2015, 8, 1404‒1427. doi: 10.1039/C4EE03869J
9. [9]
  Matheu, R.; Garrido-Barros, P.; Gil-Sepulcre, M.; Ertem, M. Z.; Sala, X.; Gimbert-Suriñach, C.; Llobet, A. The development of molecular water oxidation catalysts. Nat. Rev. Chem. 2019, 3, 331‒341.
10. [10]
  Najafpour, M. M.; Renger, G.; Hoƚyńska, M.; Moghaddam, A. N.; Aro, E. M.; Carpentier, R.; Nishihara, H.; Eaton-Rye, J. J.; Shen, J. R.; Allakhverdiev, S. I. Manganese compounds as water-oxidizing catalysts: from the natural water-oxidizing complex to nanosized manganese oxide structures. Chem. Rev. 2016, 116, 2886‒936.
11. [11]
  Park, S.; Lee, Y. H.; Choi, S.; Seo, H.; Lee, M. Y.; Balamurugan, M.; Nam, K. T. Manganese oxide-based heterogeneous electrocatalysts for water oxidation. Energy Environ. Sci. 2020, 13, 2310‒2340.
12. [12]
  Shen, J. R. The structure of photosystem II and the mechanism of water oxidation in photosynthesis. Annu. Rev. Plant Biol. 2015, 66, 23‒48.
13. [13]
  Britt, R. D.; Marchiori, D. A. Photosystem II, poised for O₂ formation. Science 2019, 366, 305‒306.
14. [14]
  Askerka, M.; Brudvig, G. W.; Batista, V. S. The O₂-evolving complex of photosystem II: recent insights from quantum mechanics/molecular mechanics (QM/MM), extended X-ray absorption fine structure (EXAFS), and femtosecond X-ray crystallography data. Acc. Chem. Res. 2017, 50, 41‒48.
15. [15]
  Vinyard, D. J.; Brudvig, G. W. Progress toward a molecular mechanism of water oxidation in photosystem II. Annu. Rev. Phys. Chem. 2017, 68, 101‒116.
16. [16]
  Tanaka, A.; Fukushima, Y.; Kamiya, N. Two different structures of the oxygen-evolving complex in the same polypeptide frameworks of photosystem II. J. Am. Chem. Soc. 2017, 139, 1718‒1721.
17. [17]
  Umena, Y.; Kawakami, K.; Shen, J. R.; Kamiya, N. Crystal structure of oxygen-evolving photosystem II at a resolution of 1.9 Å. Nature 2011, 473, 55‒60.
18. [18]
  Yocum, C. The calcium and chloride requirements of the O₂ evolving complex. Coord. Chem. Rev. 2008, 252, 296‒305.
19. [19]
  Yao, R.; Li, Y.; Chen, Y.; Xu, B.; Chen, C.; Zhang, C. Rare-earth elements can structurally and energetically replace the calcium in a synthetic Mn₄CaO₄-cluster mimicking the oxygen-evolving center in photosynthesis. J. Am. Chem. Soc. 2021, 143, 17360‒17365.
20. [20]
  Pantazis, D. A. Missing pieces in the puzzle of biological water oxidation. ACS Catal. 2018, 8, 9477‒9507.
21. [21]
  Suga, M.; Akita, F.; Sugahara, M.; Kubo, M.; Nakajima, Y.; Nakane, T.; Yamashita, K.; Umena, Y.; Nakabayashi, M.; Yamane, T.; Nakano, T.; Suzuki, M.; Masuda, T.; Inoue, S.; Kimura, T.; Nomura, T.; Yonekura, S.; Yu, L. J.; Sakamoto, T.; Motomura, T.; Chen, J. H.; Kato, Y.; Noguchi, T.; Tono, K.; Joti, Y.; Kameshima, T.; Hatsui, T.; Nango, E.; Tanaka, R.; Naitow, H.; Matsuura, Y.; Yamashita, A.; Yamamoto, M.; Nureki, O.; Yabashi, M.; Ishikawa, T.; Iwata, S.; Shen, J. R. Light-induced structural changes and the site of O=O bond formation in PSII caught by XFEL. Nature 2017, 543, 131‒135.
22. [22]
  Kern, J.; Chatterjee, R.; Young, I. D.; Fuller, F. D.; Lassalle, L.; Ibrahim, M.; Gul, S.; Fransson, T.; Brewster, A. S.; Alonso-Mori, R.; Hussein, R.; Zhang, M.; Douthit, L.; de Lichtenberg, C.; Cheah, M. H.; Shevela, D.; Wersig, J.; Seuffert, I.; Sokaras, D.; Pastor, E.; Weninger, C.; Kroll, T.; Sierra, R. G.; Aller, P.; Butryn, A.; Orville, A. M.; Liang, M.; Batyuk, A.; Koglin, J. E.; Carbajo, S.; Boutet, S.; Moriarty, N. W.; Holton, J. M.; Dobbek, H.; Adams, P. D.; Bergmann, U.; Sauter, N. K.; Zouni, A.; Messinger, J.; Yano, J.; Yachandra, V. K. Structures of the intermediates of Kok's photosynthetic water oxidation clock. Nature 2018, 563, 421‒425.
23. [23]
  Suga, M.; Akita, F.; Yamashita, K.; Nakajima, Y.; Ueno, G.; Li, H.; Yamane, T.; Hirata, K.; Umena, Y.; Yonekura, S.; Yu, L. J.; Murakami, H.; Nomura, T.; Kimura, T.; Kubo, M.; Baba, S.; Kumasaka, T.; Tono, K.; Yabashi, M.; Isobe, H.; Yamaguchi, K.; Yamamoto, M.; Ago, H.; Shen, J. R. An oxyl/oxo mechanism for oxygen-oxygen coupling in PSII revealed by an X-ray free-electron laser. Science 2019, 366, 334‒338.
24. [24]
  Pittkowski, R.; Krtil, P.; Rossmeisl, J. Rationality in the new oxygen evolution catalyst development. Curr. Opin. Electrochem. 2018, 12, 218‒224.
25. [25]
  Rossmeisl, J.; Qu, Z. W.; Zhu, H.; Kroes, G. J.; Nørskov, J. K. Electrolysis of water on oxide surfaces. J. Electroanal. Chem. 2007, 607, 83‒89.
26. [26]
  Man, I. C.; Su, H. Y.; Calle‐Vallejo, F.; Hansen, H. A.; Martínez, J. I.; Inoglu, N. G.; Kitchin, J.; Jaramillo, T. F.; Nørskov, J. K.; Rossmeisl, J. Universality in oxygen evolution electrocatalysis on oxide surfaces. ChemCatChem 2011, 3, 1159‒1165.
27. [27]
  Busch, M.; Ahlberg, E.; Panas, I. Water oxidation on MnO_x and IrO_x: why similar performance? J. Phys. Chem. C 2012, 117, 288‒292.
28. [28]
  Zhao, Y.; Vargas-Barbosa, N. M.; Hernandez-Pagan, E. A.; Mallouk, T. E. Anodic deposition of colloidal iridium oxide thin films from hexahydroxyiridate(IV) solutions. Small 2011, 7, 2087‒2093.
29. [29]
  Takashima, T.; Hashimoto, K.; Nakamura, R. Mechanisms of pH-dependent activity for water oxidation to molecular oxygen by MnO₂ electrocatalysts. J. Am. Chem. Soc. 2012, 134, 1519‒1527.
30. [30]
  Gorlin, Y.; Jaramillo, T. F. A bifunctional nonprecious metal catalyst for oxygen reduction and water oxidation. J. Am. Chem. Soc. 2010, 132, 13612‒13614.
31. [31]
  Zhou, F.; Izgorodin, A.; Hocking, R. K.; Spiccia, L.; MacFarlane, D. R. Electrodeposited MnO_x films from ionic liquid for electrocatalytic water oxidation. Adv. Energy Mater. 2012, 2, 1013‒1021.
32. [32]
  Mette, K.; Bergmann, A.; Tessonnier, J. P.; Hävecker, M.; Yao, L.; Ressler, T.; Schlögl, R.; Strasser, P.; Behrens, M. Nanostructured manganese oxide supported on carbon nanotubes for electrocatalytic water splitting. ChemCatChem 2012, 4, 851‒862.
33. [33]
  Fekete, M.; Hocking, R. K.; Chang, S. L. Y.; Italiano, C.; Patti, A. F.; Arena, F.; Spiccia, L. Highly active screen-printed electrocatalysts for water oxidation based on β-manganese oxide. Energy Environ. Sci. 2013, 6, 2222‒2232.
34. [34]
  Meng, Y.; Song, W.; Huang, H.; Ren, Z.; Chen, S. Y.; Suib, S. L. Structure-property relationship of bifunctional MnO₂ nanostructures: highly efficient, ultra-stable electrochemical water oxidation and oxygen reduction reaction catalysts identified in alkaline media. J. Am. Chem. Soc. 2014, 136, 11452‒11464.
35. [35]
  Zhang, Y.; Chen, Y.; Liang, Z.; Qi, J.; Gao, X.; Zhang, W.; Cao, R. Controlled synthesis of hexagonal annular Mn(OH)F for water oxidation. Chin. J. Catal. 2019, 40, 1860‒1866.
36. [36]
  Chen, Y.; Yang, S.; Liu, H.; Zhang, W.; Cao, R. An unusual network of α-MnO₂ nanowires with structure-induced hydrophilicity and conductivity for improved electrocatalysis. Chin. J. Catal. 2021, 42, 1724‒1731.
37. [37]
  Smith, P. F.; Deibert, B. J.; Kaushik, S.; Gardner, G.; Hwang, S.; Wang, H.; Al-Sharab, J. F.; Garfunkel, E.; Fabris, L.; Li, J.; Dismukes, G. C. Coordination geometry and oxidation state requirements of corner-sharing MnO₆ octahedra for water oxidation catalysis: an investigation of manganite (γ-MnOOH). ACS Catal. 2016, 6, 2089‒2099.
38. [38]
  Wan, S.; Li, Y.; Xu, L.; Zhang, W.; Cao, R. Autologous Mn oxides as electrocatalysts to identify the origin of the water oxidation activity. Mater. Today Sustain. 2022, 17, 100106.
39. [39]
  Huynh, M.; Shi, C.; Billinge, S. L.; Nocera, D. G. Nature of activated manganese oxide for oxygen evolution. J. Am. Chem. Soc. 2015, 137, 14887‒14904.
40. [40]
  Kang, Q.; Vernisse, L.; Remsing, R. C.; Thenuwara, A. C.; Shumlas, S. L.; McKendry, I. G.; Klein, M. L.; Borguet, E.; Zdilla, M. J.; Strongin, D. R. Effect of interlayer spacing on the activity of layered manganese oxide bilayer catalysts for the oxygen evolution reaction. J. Am. Chem. Soc. 2017, 139, 1863‒1870.
41. [41]
  Robinson, D. M.; Go, Y. B.; Mui, M.; Gardner, G.; Zhang, Z.; Mastrogiovanni, D.; Garfunkel, E.; Li, J.; Greenblatt, M.; Dismukes, G. C. Photochemical water oxidation by crystalline polymorphs of manganese oxides: structural requirements for catalysis. J. Am. Chem. Soc. 2013, 135, 3494‒3501.
42. [42]
  Zhang, B.; Chen, H.; Daniel, Q.; Philippe, B.; Yu, F.; Valvo, M.; Li, Y.; Ambre, R. B.; Zhang, P.; Li, F.; Rensmo, H.; Sun, L. Defective and "c-disordered" hortensia-like layered mnox as an efficient electrocatalyst for water oxidation at neutral pH. ACS Catal. 2017, 7, 6311‒6322.
43. [43]
  Park, J.; Kim, H.; Jin, K.; Lee, B. J.; Park, Y. S.; Kim, H.; Park, I.; Yang, K. D.; Jeong, H. Y.; Kim, J.; Hong, K. T.; Jang, H. W.; Kang, K.; Nam, K. T. A new water oxidation catalyst: lithium manganese pyrophosphate with tunable Mn valency. J. Am. Chem. Soc. 2014, 136, 4201‒4211.
44. [44]
  Yoon, S.; Jin, K.; Lee, S.; Nam, K. T.; Kim, M.; Kwon, Y. K. Effects of paramagnetic fluctuations on the thermochemistry of MnO(100) surfaces in the oxygen evolution reaction. Phys. Chem. Chem. Phys. 2021, 23, 859‒865.
45. [45]
  Jiang, Y.; Yuan, L.; Wang, X.; Zhang, W.; Liu, J.; Wu, X.; Huang, K.; Li, Y.; Liu, Z.; Feng, S. Jahn-Teller disproportionation induced exfoliation of unit-cell scale ɛ-MnO₂. Angew. Chem. Int. Ed. 2020, 59, 22659‒22666.
46. [46]
  Thenuwara, A. C.; Cerkez, E. B.; Shumlas, S. L.; Attanayake, N. H.; McKendry, I. G.; Frazer, L.; Borguet, E.; Kang, Q.; Remsing, R. C.; Klein, M. L.; Zdilla, M. J.; Strongin, D. R. Nickel confined in the interlayer region of birnessite: an active electrocatalyst for water oxidation. Angew. Chem. Int. Ed. 2016, 55, 10381‒10385.
47. [47]
  Cao, X.; Qiao, Y.; Jia, M.; He, P.; Zhou, H. Ion‐exchange: a promising strategy to design Li‐rich and Li‐excess layered cathode materials for Li‐ion batteries. Adv. Energy Mater. 2021, 2003972.
48. [48]
  Jin, K.; Park, J.; Lee, J.; Yang, K. D.; Pradhan, G. K.; Sim, U.; Jeong, D.; Jang, H. L.; Park, S.; Kim, D.; Sung, N. E.; Kim, S. H.; Han, S.; Nam, K. T. Hydrated manganese(II) phosphate (Mn₃(PO₄)₂·3H₂O) as a water oxidation catalyst. J. Am. Chem. Soc. 2014, 136, 7435‒7443.
49. [49]
  Kanan, M. W.; Nocera, D. G. In situ formation of an oxygen-evolving catalyst in neutral water containing phosphate and Co²⁺. Science 2008, 321, 1072‒1075.
50. [50]
  Liu, H.; Gao, X.; Yao, X.; Chen, M.; Zhou, G.; Qi, J.; Zhao, X.; Wang, W.; Zhang, W.; Cao, R. Manganese(II) phosphate nanosheet assembly with native out-of-plane Mn centres for electrocatalytic water oxidation. Chem. Sci. 2019, 10, 191‒197.
51. [51]
  Yang, S.; Wan, S.; Shang, F.; Chen, D.; Zhang, W.; Cao, R. Autologous manganese phosphates with different Mn sites for electrocatalytic water oxidation. Chem. Commun. 2021, 57, 6165‒6168.
52. [52]
  Takashima, T.; Hashimoto, K.; Nakamura, R. Inhibition of charge disproportionation of MnO₂ electrocatalysts for efficient water oxidation under neutral conditions. J. Am. Chem. Soc. 2012, 134, 18153–18156.
53. [53]
  Soldatova, A. V.; Romano, C. A.; Tao, L.; Stich, T. A.; Casey, W. H.; Britt, R. D.; Tebo, B. M.; Spiro, T. G. Mn(II) oxidation by the multicopper oxidase complex Mnx: a coordinated two-stage Mn(II)/(III) and Mn(III)/(IV) mechanism. J. Am. Chem. Soc. 2017, 139, 11381‒11391.
54. [54]
  Gao, X.; Yang, S.; Zhang, W.; Cao, R. Biomimicking hydrogen-bonding network by ammoniated and hydrated manganese(II) phosphate for electrocatalytic water oxidation. Acta Phys. -Chim. Sin. 2021, 37, 2007031.
55. [55]
  Zaharieva, I.; Najafpour, M. M.; Wiechen, M.; Haumann, M.; Kurz, P.; Dau, H. Synthetic manganese-calcium oxides mimic the water-oxidizing complex of photosynthesis functionally and structurally. Energy Environ. Sci. 2011, 4, 2400‒2408.
56. [56]
  Ramírez, A.; Bogdanoff, P.; Friedrich, D.; Fiechter, S. Synthesis of Ca₂Mn₃O₈ films and their electrochemical studies for the oxygen evolution reaction (OER) of water. Nano Energy 2012, 1, 282‒289.
57. [57]
  Gonzalez-Flores, D.; Zaharieva, I.; Heidkamp, J.; Chernev, P.; Martinez-Moreno, E.; Pasquini, C.; Mohammadi, M. R.; Klingan, K.; Gernet, U.; Fischer, A.; Dau, H. Electrosynthesis of biomimetic manga-nese-calcium oxides for water oxidation catalysis-atomic structure and functionality. ChemSusChem 2016, 9, 379‒387.
58. [58]
  Simchi, H.; Cooley, K. A.; Ohms, J.; Huang, L.; Kurz, P.; Mohney, S. E. Cosputtered calcium manganese oxide electrodes for water oxidation. Inorg. Chem. 2018, 57, 785‒792.
59. [59]
  Park, S.; Jin, K.; Lim, H. K.; Kim, J.; Cho, K. H.; Choi, S.; Seo, H.; Lee, M. Y.; Lee, Y. H.; Yoon, S.; Kim, M.; Kim, H.; Kim, S. H.; Nam, K. T. Spectroscopic capture of a low-spin Mn(IV)-oxo species in Ni-Mn₃O₄ nanoparticles during water oxidation catalysis. Nat. Commun. 2020, 11, 5230.
60. [60]
  Huang, Z. F.; Song, J.; Dou, S.; Li, X.; Wang, J.; Wang, X. Strategies to break the scaling relation toward enhanced oxygen electrocatalysis. Matter 2019, 1, 1494‒1518.
61. [61]
  Geiger, S.; Kasian, O.; Ledendecker, M.; Pizzutilo, E.; Mingers, A. M.; Fu, W. T.; Diaz-Morales, O.; Li, Z.; Oellers, T.; Fruchter, L.; Ludwig, A.; Mayrhofer, K. J. J.; Koper, M. T. M.; Cherevko, S. The stability number as a metric for electrocatalyst stability benchmarking. Nat. Catal. 2018, 1, 508‒515.
62. [62]
  Huang, Z. F.; Song, J.; Du, Y.; Xi, S.; Dou, S.; Nsanzimana, J. M. V.; Wang, C.; Xu, Z. J.; Wang, X. Chemical and structural origin of lattice oxygen oxidation in Co-Zn oxyhydroxide oxygen evolution electro-catalysts. Nat. Energy 2019, 4, 329‒338.
63. [63]
  Koper, M. T. M. Theory of multiple proton-electron transfer reactions and its implications for electrocatalysis. Chem. Sci. 2013, 4, 2710‒2723.
64. [64]
  Huang, Z. F.; Xi, S.; Song, J.; Dou, S.; Li, X.; Du, Y.; Diao, C.; Xu, Z. J.; Wang, X. Tuning of lattice oxygen reactivity and scaling relation to construct better oxygen evolution electrocatalyst. Nat. Commun. 2021, 12, 3992.
65. [65]
  Warren, J. J.; Tronic, T. A.; Mayer, J. M. Thermochemistry of proton-coupled electron transfer reagents and its implications. Chem. Rev. 2010, 110, 6961‒7001.
66. [66]
  Ooka, H.; Takashima, T.; Yamaguchi, A.; Hayashi, T.; Nakamura, R. Element strategy of oxygen evolution electrocatalysis based on in situ spectroelectrochemistry. Chem. Commun. 2017, 53, 7149‒7161.
67. [67]
  Balamurugan, M.; Saravanan, N.; Heonjin, H.; Lee, Y. H.; Nam, K. T. Involvement of high-valent manganese-oxo intermediates in oxidation reactions: realisation in nature, nano and molecular systems. Nano Converg. 2018, 5, 18.
68. [68]
  Kakizaki, H.; Ooka, H.; Hayashi, T.; Yamaguchi, A.; Bonnet‐Mercier, N.; Hashimoto, K.; Nakamura, R. Evidence that crystal facet orientation dictates oxygen evolution intermediates on rutile manganese oxide. Adv. Funct. Mater. 2018, 28, 1706319.
69. [69]
  Wiechen, M.; Najafpour, M. M.; Allakhverdiev, S. I.; Spiccia, L. Water oxidation catalysis by manganese oxides: learning from evolution. Energy Environ. Sci. 2014, 7, 2203‒2212.
70. [70]
  Zaharieva, I.; González-Flores, D.; Asfari, B.; Pasquini, C.; Mohammadi, M. R.; Klingan, K.; Zizak, I.; Loos, S.; Chernev, P.; Dau, H. Water oxidation catalysis-role of redox and structural dynamics in biological photosynthesis and inorganic manganese oxides. Energy Environ. Sci. 2016, 9, 2433‒2443.
71. [71]
  Huynh, M.; Bediako, D. K.; Nocera, D. G. A functionally stable manganese oxide oxygen evolution catalyst in acid. J. Am. Chem. Soc. 2014, 136, 6002‒6010.
72. [72]
  Zahran, Z. N.; Mohamed, E. A.; Naruta, Y. Kinetics and mechanism of heterogeneous water oxidation by α-Mn₂O₃ sintered on an FTO electrode. ACS Catal. 2016, 6, 4470‒4476.
73. [73]
  Wang, N.; Zheng, H.; Zhang, W.; Cao, R. Mononuclear first-row transition-metal complexes as molecular catalysts for water oxidation. Chin. J. Catal. 2018, 39, 228‒244.
74. [74]
  Jin, X.; Li, X.; Lei, H.; Guo, K.; Lv, B.; Guo, H.; Chen, D.; Zhang, W.; Cao, R. Comparing electrocatalytic hydrogen and oxygen evolution activities of first-row transition metal complexes with similar coordination environments. J. Energy Chem. 2021, 63, 659‒666.
75. [75]
  Cao, R.; Lai, W.; Du, P. Catalytic water oxidation at single metal sites. Energy Environ. Sci. 2012, 5, 8134‒8157.
76. [76]
  Li, X.; Lei, H.; Xie, L.; Wang, N.; Zhang, W.; Cao, R. Metallo-porphyrins as catalytic models for studying hydrogen and oxygen evolution and oxygen reduction reactions. Acc. Chem. Res. 2022, DOI:10.1021/acs.accounts.1c00753. doi: 10.1021/acs.accounts.1c00753
77. [77]
  Zhang, X. P.; Wang, H. Y.; Zheng, H.; Zhang, W.; Cao, R. O–O bond formation mechanisms during the oxygen evolution reaction over synthetic molecular catalysts. Chin. J. Catal. 2021, 42, 1253‒1268.
78. [78]
  Zhang, X. P.; Chandra, A.; Lee, Y. M.; Cao, R.; Ray, K.; Nam, W. Transition metal-mediated O–O bond formation and activation in chemistry and biology. Chem. Soc. Rev. 2021, 50, 4804‒4811.
79. [79]
  Li, X.; Zhang, X. P.; Guo, M.; Lv, B.; Guo, K.; Jin, X.; Zhang, W.; Lee, Y. M.; Fukuzumi, S.; Nam, W.; Cao, R. Identifying intermediates in electrocatalytic water oxidation with a manganese corrole complex. J. Am. Chem. Soc. 2021, 143, 14613‒14621.
80. [80]
  Lai, W.; Cao, R.; Dong, G.; Shaik, S.; Yao, J.; Chen, H. Why is cobalt the best transition metal in transition-metal hangman corroles for O–O bond formation during water oxidation? J. Phys. Chem. Lett. 2012, 3, 2315‒2319.
81. [81]
  Lei, H.; Liu, C.; Wang, Z.; Zhang, Z.; Zhang, M.; Chang, X.; Zhang, W.; Cao, R. Noncovalent Immobilization of a pyrene-modified cobalt corrole on carbon supports for enhanced electrocatalytic oxygen reduction and oxygen evolution in aqueous solutions. ACS Catal. 2016, 6, 6429‒6437.
82. [82]
  Seo, H.; Jin, K.; Park, S.; Cho, K. H.; Ha, H.; Lee, K. G.; Lee, Y. H.; Nguyen, D. T.; Randriamahazaka, H.; Lee, J. S.; Nam, K. T. Mechanistic investigation with kinetic parameters on water oxidation catalyzed by manganese oxide nanoparticle film. ACS Sustain. Chem. Eng. 2019, 7, 10595‒10604.
83. [83]
  Lee, J.; Choe, I. R.; Kim, Y. O.; Namgung, S. D.; Jin, K.; Ahn, H. Y.; Sung, T.; Kwon, J. Y.; Lee, Y. S.; Nam, K. T. Proton conduction in a tyrosine-rich peptide/manganese oxide hybrid nanofilm. Adv. Funct. Mater. 2017, 27, 1702185.
84. [84]
  Lee, K. G.; Balamurugan, M.; Park, S.; Ha, H.; Jin, K.; Seo, H.; Nam, K. T. Importance of entropic contribution to electrochemical water oxidation catalysis. ACS Energy Lett. 2019, 4, 1918‒1929.
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6. [6]
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13. [13]
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15. [15]
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16. [16]
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17. [17]
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18. [18]
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19. [19]
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20. [20]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459

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沈阳化工大学材料科学与工程学院沈阳 110142