Citation: Fazheng Huang, Xinhao Li, Zhen Zhang, Ziqi Jiang, Guoqiang Wang, Lingyun Li, Yan Yu. An Ultra-stable Eu³⁺ Doped Yttrium Coordination Polymer with Dual-function Sensing for Cr(VI) and Fe(III) Ions in Aqueous Solution[J]. Chinese Journal of Structural Chemistry, ;2022, 41(4): 220406. doi: 10.14102/j.cnki.0254-5861.2021-0071 shu

An Ultra-stable Eu³⁺ Doped Yttrium Coordination Polymer with Dual-function Sensing for Cr(VI) and Fe(III) Ions in Aqueous Solution

Fazheng Huang ^{1, †} ,
Xinhao Li ^{1, †} ,
Zhen Zhang ^{1, †} ,
Ziqi Jiang ¹ ,
Guoqiang Wang ¹ ,
Lingyun Li ^1,, ,
Yan Yu ^1,,

1.
Key Laboratory of Advanced Materials Technology, College of Materials Science and Engineering, Fuzhou University, Fuzhou 350108, China

Corresponding author: Lingyun Li, lilingyun@fzu.edu.cn Yan Yu, yuyan@fzu.edu.cn

^†

Received Date: 31 December 2021
Accepted Date: 18 February 2022

Figures(7)

The exploration of a dual-functional sensor is the key to effectively detect the Cr(VI) and Fe(III) cations in water, which is important to human health and environmental sustainability. Because of the phase stability and excellent luminescence, the rare-earth coordination polymers have great potential as dual-functional sensors. Here, we develop a Y_0.91Eu_0.09(H₂O)₂{C₆H₃(CO₂)₃}(MIL-92(Y): 9%Eu³⁺)-based dual-function luminescent sensor on Cr(VI) and Fe(III), which exhibits excellent phase stability and dispersibility in water. The luminescence of MIL-92(Y): 9%Eu³⁺ aqueous suspension quenches on Fe³⁺ with Stern-Volmer constant K_sv of 1.79 × 10³ M^-1 and limit of detection of 17 μM. The MIL-92(Y): 9%Eu³⁺ aqueous suspension also has turn-off sensing ability towards Cr₂O₇^2- and CrO₄^2- with K_sv values of 3.5 × 10³ and 6.14 × 10³ M^-1, respectively. It has detection limitations of 10 and 5 μM on Cr₂O₇^2- and Cr₂O₇^2- ions, respectively.
- Cr(VI),
- Fe(III),
- luminescence sensing,
- dual-function detection,
- MIL-92
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An Ultra-stable Eu3+ Doped Yttrium Coordination Polymer with Dual-function Sensing for Cr(VI) and Fe(III) Ions in Aqueous Solution

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An Ultra-stable Eu³⁺ Doped Yttrium Coordination Polymer with Dual-function Sensing for Cr(VI) and Fe(III) Ions in Aqueous Solution