Citation: CHEN Shun-Yu, YANG E, XIE Chun-Ling, LIU Yun-Zhen, XIAO Xiu-Feng. Synthesis, Structure and Luminescent Property of a New Zn(Ⅱ) Coordination Polymer Based on 1,3,5-Benzenetricarboxylate and 4,4'-Bipyridine Ligands[J]. Chinese Journal of Structural Chemistry, ;2015, 34(2): 235-240. doi: 10.14102/j.cnki.0254-5861.2011-462 shu

Synthesis, Structure and Luminescent Property of a New Zn(Ⅱ) Coordination Polymer Based on 1,3,5-Benzenetricarboxylate and 4,4'-Bipyridine Ligands

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a. College of Chemistry & Chemical Engineering, Fujian Normal University, Fuzhou 350007, China;
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b. College of Materials Science & Engineering, Fujian Normal University, Fuzhou 350007, China

Corresponding author: XIAO Xiu-Feng,
Received Date: 24 July 2014
Available Online: 1 December 2014
Fund Project: This work was supported by the National Natural Science Foundation of China (60976019) (60976019)the Foundation of Education Committee of Fujian Province (No. JB13007) (No. JB13007)

A new Zn(Ⅱ) coordination polymer [Zn₃(BTC)₂(4,4'-bpy)(CO)₂]_n (1, H₃BTC=1,3,5-benzenetricarboxylic acid, 4,4'-bpy=4,4'-bipyridine) has been prepared through urothermal reaction of zinc nitrate hexahydrate with 1,3,5-benzenetricarboxylic acid and 4,4'-bipyridine, and characterized by elemental analysis, IR spectroscopy, TGA and powder XRD, and its crystal structure was determined by single-crystal X-ray diffraction analysis. The title compound crystallizes in the monoclinic system, space group C2/c, with a=10.262(3), b=18.838(5), c=15.083(4)Å, β=99.203(4)°, V=2878.3(14)Å³, C₃₀H₁₄Zn₃N₂O₁₄, M_r=822.54, Z=4, D_c=1.898 g/cm³, μ=2.561 mm^-1, F(000)=1640, R=0.0363 and wR=0.0932 for 2828 observed reflections (I>2σ(I)). X-ray analysis shows that the asymmetric unit of the title compound contains two crystallographically unique Zn(Ⅱ) atoms which are connected by BTC^3- ligands and 4,4'-bpy coligands to form a 3D framework with 1D channels. The solid luminescence of ligand and the title complex was also studied at room temperature.
- zinc coordination polymer,
- 1,3,5-benzenetricarboxylic acid,
- 4,4'-bipyridine,
- urothermal synthesis,
- photoluminescence
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