Citation: Yan-Jie HU, Yan-Hong YIN, Ming ZHANG, Zi-Ping WU, Zhong-Rong SHEN. In-situ Growth of Carbon Nanosheets Intercalated with TiO₂ for Improving Electrochemical Performance and Stability ofLithium-ion Batteries[J]. Chinese Journal of Structural Chemistry, ;2021, 40(11): 1513-1524. doi: 10.14102/j.cnki.0254-5861.2011-3189 shu

In-situ Growth of Carbon Nanosheets Intercalated with TiO₂ for Improving Electrochemical Performance and Stability ofLithium-ion Batteries

Yan-Jie HU ^{a, b, c} ,
Yan-Hong YIN ^a,, ,
Ming ZHANG ^{b, c} ,
Zi-Ping WU ^a,, ,
Zhong-Rong SHEN ^{b, c,,}

a.
Faculty of Materials Metallurgy and Chemistry, Jiangxi University of Science and Technology, Ganzhou 341000, China
b.
CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
c.
The Laboratory of Rare-earth Functional Materials and Green Energy, Xiamen Institute of Rare Earth Materials, Haixi Institute, Chinese Academy of Sciences, Xiamen 361021, China

Corresponding author: Yan-Hong YIN, yinyanhong@jxust.edu.cn Zi-Ping WU, wuziping724@jxust.edu.cn Zhong-Rong SHEN, z-shen@fjirsm.ac.cn
Received Date: 22 March 2021
Accepted Date: 6 May 2021

Fund Project: the National Natural Science Foundation of China 22062008the China Scholarship Council 201908360233the Jiangxi Provincial Department of Science and Technology GJJ190436the Jiangxi Provincial Department of Science and Technology 2019KY56

Figures(6)

In situ growth of carbon nanomaterials on active substance is a very favorable strategy for the preparation of electrode in lithium-ion batteries with excellent electrochemical performance and high stability. Small-sized TiO₂ nanoparticles intercalated into carbon nanosheets (CNS@TiO₂SNP-600) were successfully synthesized via in-situ polymerization-carbonization method, utilizing layered H₂Ti₄O₉ (HTO) as template and benzidine as carbon source. The morphology and size of TiO₂ are greatly influenced by carbonization temperature. The coin cell with the CNS@TiO₂SNP-600 electrode demonstrates a discharge specific capacity of 430.4 mAh⋅g^-1 at a current density of 0.1 A⋅g^-1, and the capacity retention rate is 88.1% after 100 cycles; and it also displays a high discharge specific capacity of 101.8 mAh⋅g^-1 at a high current density of 12.8 A⋅g^-1. The excellent electrochemical performances can be ascribed to the capacitance effect originated from the intercalated structure of in-situ grown CNS and TiO₂ nanoparticles. We believe this type of materials can be widely used in the lithium-ion batteries and other related green chemical fields.
- carbon nanosheets,
- TiO₂,
- in situ growth,
- template,
- storage lithium
1. [1]
  Zhao, Y.; Wang, L. P.; Sougrati, M. T.; Feng, Z. X.; Leconte, Y.; Fisher, A.; Srinivasan, M.; Xu, Z. C. A review on design strategies for carbon based metal oxides and sulfides nanocomposites for high performance Li and Na ion battery anodes. Adv. Energy Mater. 2017, 7, 1601424−70. doi: 10.1002/aenm.201601424
2. [2]
  Subramanian, V.; Karki, A.; Gnanasekar, K. I.; Eddy, F. P.; Rambabu, B. Nanocrystalline TiO₂ (anatase) for Li-ion batteries. J. Power Sources 2006, 159, 186−192. doi: 10.1016/j.jpowsour.2006.04.027
3. [3]
  An, G. H.; Ahn, H. J. Carbon nanofiber/cobalt oxide nanopyramid core-shell nanowires for high-performance lithium-ion batteries. J. Power Sources 2014, 272, 828−836. doi: 10.1016/j.jpowsour.2014.09.032
4. [4]
  Cho, J. S.; Hong, Y. J.; Kang, Y. C. Design and synthesis of bubble-nanorod-structured Fe₂O₃-carbon nanofibers as advanced anode material for Li-ion batteries. ACS Nano 2015, 9, 4026−4035. doi: 10.1021/acsnano.5b00088
5. [5]
  Yan, C. S.; Chen, G.; Zhou, X.; Sun, J. X.; Lv, C. Template-based engineering of carbon-doped Co₃O₄ hollow nanofibers as anode materials for lithium-ion batteries. Adv. Funct. Mater. 2016, 26, 1428−1436. doi: 10.1002/adfm.201504695
6. [6]
  Wang, H. W.; Jia, G. C.; Guo, Y. Y.; Zhang, Y. Q.; Geng, H. B.; Xu, J.; Mai, W. J.; Yan, Q. Y.; Fan, H. J. Atomic layer deposition of amorphous TiO₂ on carbon nanotube networks and their superior Li and Na ion storage properties. Adv. Mater. Interfaces 2016, 3, 1600375−9. doi: 10.1002/admi.201600375
7. [7]
  Wang, X. Y.; Fan, L.; Gong, D. C.; Zhu, J.; Zhang, Q. F.; Lu, B. G. Core-shell Ge@Graphene@ TiO₂ nanofibers as a high-capacity and cycle-stable anode for lithium and sodium ion battery. Adv. Funct. Mater. 2016, 26, 1104−1111. doi: 10.1002/adfm.201504589
8. [8]
  Etacheri, V.; Yourey, J. E.; Bartlett, B. M. Chemically bonded TiO₂-bronze nanosheet/reduced graphene oxide hybrid for high-power lithium ion batteries. ACS Nano 2014, 8, 1491−1499. doi: 10.1021/nn405534r
9. [9]
  Hu, T.; Sun, X.; Sun, H. T.; Yu, M. P.; Lu, F. Y.; Liu, C. S.; Lian, J. Flexible free-standing graphene-TiO₂ hybrid paper for use as lithium ion battery anode materials. Carbon 2013, 51, 322−326. doi: 10.1016/j.carbon.2012.08.059
10. [10]
  Kim, H. K.; Mhamane, D.; Kim, M. S.; Roh, H. K.; Aravindan, V.; Madhavi, S.; Roh, K. C.; Kim, K. B. TiO₂-reduced graphene oxide nanocomposites by microwave-assisted forced hydrolysis as excellent insertion anode for Li-ion battery and capacitor. J. Power Sources 2016, 327, 171−177. doi: 10.1016/j.jpowsour.2016.07.053
11. [11]
  Li, W.; Wang, F.; Liu, Y. P.; Wang, J. X.; Yang, J. P.; Zhang, L. J.; Elzatahry, A. A.; Al-Dahyan, D.; Xia, Y. Y.; Zhao, D. Y. General strategy to synthesize uniform mesoporous TiO₂/graphene/mesoporous TiO₂ sandwich-like nanosheets for highly reversible lithium storage. Nano Lett. 2015, 15, 2186−2193. doi: 10.1021/acs.nanolett.5b00291
12. [12]
  Mo, R. W.; Lei, Z. Y.; Sun, K. N.; Rooney, D. Facile synthesis of anatase TiO₂ quantum-dot/graphene-nanosheet composites with enhanced electrochemical performance for lithium-ion batteries. Adv. Mater. 2014, 26, 2084−2088. doi: 10.1002/adma.201304338
13. [13]
  Qiu, B. C.; Xing, M. Y.; Zhang, J. L. Mesoporous TiO₂ nanocrystals grown in situ on graphene aerogels for high photocatalysis and lithium-ion batteries. J. Am. Chem. Soc. 2014, 136, 5852−5855. doi: 10.1021/ja500873u
14. [14]
  Ren, G. F.; Hoque, M. N. F.; Liu, J. W.; Warzywoda, J.; Fan, Z. Y. Perpendicular edge oriented graphene foam supporting orthogonal TiO₂ (B) nanosheets as freestanding electrode for lithium ion battery. J. Am. Chem. Soc. 2016, 21, 162−171.
15. [15]
  Ren, Y.; Liu, Z.; Pourpoint, F.; Armstrong, A. R.; Grey, C. P.; Bruce, P. G. Nanoparticulate TiO₂ (B): an anode for lithium-ion batteries. Angew. Chem. Int. Ed. 2012, 124, 2206−2209. doi: 10.1002/ange.201108300
16. [16]
  Wang, D. H.; Choi, D.; Li, J.; Yang, Z. G.; Nie, Z. M.; Kou, R.; Hu, D. H.; Wang, C. M.; Saraf, L. V.; Zhang, J. G. Self-assembled TiO₂-graphene hybrid nanostructures for enhanced Li-ion insertion. ACS Nano 2009, 3, 907−914. doi: 10.1021/nn900150y
17. [17]
  Fu, W. W.; Li, Y. T.; Chen, M. S.; Hu, Y. J.; Liu, B. H.; Zhang, K.; Zhan, C. Y.; Zhang, M.; Shen, Z. R. An orderly arrangement of layered carbon nanosheet/TiO₂ nanosheet stack with superior artificially interfacial lithium pseudocapacity. J. Power Sources 2020, 468, 228363−7. doi: 10.1016/j.jpowsour.2020.228363
18. [18]
  Hu, Y. J.; Li, Y. T.; Cheng, J. F.; Chen, M. S.; Fu, W. W.; Liu, B. H.; Zhang, M.; Shen, Z. R. Intercalation of carbon nanosheet into layered TiO₂ grain for highly interfacial lithium storage. ACS Appl. Mater. Inter. 2020, 12, 21709−21719. doi: 10.1021/acsami.0c03775
19. [19]
  Li, Y. T.; Chen, M. S.; Cheng, J. F.; Fu, W. W.; Hu, Y. J.; Liu, B. H.; Zhang, M.; Shen, Z. R. Two-dimensional layered ultrathin carbon/TiO₂ nanosheet composites for superior pseudocapacitive lithium storage. Langmuir 2020, 36, 2255−2263. doi: 10.1021/acs.langmuir.9b03889
20. [20]
  Brezesinski, T.; Wang, J.; Polleux, J.; Dunn, B.; Tolbert, S. H. Templated nanocrystal-based porous TiO₂ films for next-generation electrochemical capacitors. J. Am. Chem. Soc. 2009, 131, 1802−1809. doi: 10.1021/ja8057309
21. [21]
  Mirhashemihaghighi, S.; León, B.; Pére Vicente, C.; Tirado, J. L.; Stoyanova, R.; Yoncheva, M.; Zhecheva, E.; Sáez Puche, R.; Arroyo, E. M.; Romero de Paz, J. Lithium storage mechanisms and effect of partial cobalt substitution in manganese carbonate electrodes. Inorg. Chem. 2012, 51, 5554−5560. doi: 10.1021/ic3004382
22. [22]
  Sasaki, T.; Kooli, F.; Iida, M.; Michiue, Y.; Takenouchi, S.; Yajima, Y.; Izumi, F.; Chakoumakos, B. C.; Watanabe, M. A mixed alkali metal titanate with the lepidocrocite-like layered structure. Preparation, crystal structure, protonic form, and acid-base intercalation properties. Chem. Mater. 1998, 10, 4123−4128. doi: 10.1021/cm980535f
23. [23]
  Ding, W.; Wei, Z. D.; Chen, S. G.; Qi, X. Q.; Yang, T.; Hu, J. S.; Wang, D.; Wan, L. J.; Alvi, S. F.; Li, L. Space-confinement-induced synthesis of pyridinic- and pyrrolic-nitrogen-doped graphene for the catalysis of oxygen reduction. Angew. Chem. Int. Ed. 2013, 125, 11971−11975. doi: 10.1002/ange.201303924
24. [24]
  Akalin, E.; Akyüz, S. Structure and vibrational spectra of benzidine. J. Mol. Struct. 2003, 651, 571−577.
25. [25]
  Akyüz, S.; Bulat, T.; Özel, A. E.; Basar, G. FT-IR and laser Raman spectroscopic investigation of transition metal halide complexes of benzidine. Vib. Spectrosc 1997, 14, 151−154. doi: 10.1016/S0924-2031(96)00070-7
26. [26]
  Wang, J.; Polleux, J.; Lim, J.; Dunn, B. Pseudocapacitive contributions to electrochemical energy storage in TiO₂ (anatase) nanoparticles. J. Phys. Chem. C 2007, 111, 14925−14931. doi: 10.1021/jp074464w
27. [27]
  Yang, Z. G.; Choi, D.; Kerisit, S.; Rosso, K. M.; Wang, D. H.; Zhang, J.; Graff, G.; Liu, J. Nanostructures and lithium electrochemical reactivity of lithium titanites and titanium oxides: a review. J. Power Sources 2009, 192, 588−598. doi: 10.1016/j.jpowsour.2009.02.038
28. [28]
  Wu, Q. L.; Xu, J. G.; Yang, X. F.; Lu, F. Q.; He, S. M.; Yang, J. L.; Fan, H. J.; Wu, M. M. Ultrathin anatase TiO₂ nanosheets embedded with TiO₂-B nanodomains for lithium-ion storage: capacity enhancement by phase boundaries. Adv. Energy Mater. 2015, 5, 1401756−9. doi: 10.1002/aenm.201401756
29. [29]
  Liu, G. Y.; Zhao, Y. Y.; Tang, Y. F.; Liu, X. D.; Liu, M.; Wu, P. J. In situ sol-gel synthesis of Ti₂Nb₁₀O₂₉/C nanoparticles with enhanced pseudocapacitive contribution for a high-rate lithium-ion battery. Rare Metals 2020, 39, 1063−1071. doi: 10.1007/s12598-020-01462-w
30. [30]
  Luo, R.; Ma, Y. T.; Qu, W. J.; Qian, J.; Li, L.; Wu, F.; Chen, R. J. High pseudocapacitance boosts ultrafast, high-capacity sodium storage of 3D graphene foam encapsulated TiO₂ architecture. ACS Appl. Mater. Inter. 2020, 12, 23939−23950. doi: 10.1021/acsami.0c04481
31. [31]
  Wang, Y. X.; Yang, J. P.; Chou, S. L.; Liu, H. K.; Zhang, W. X.; Zhao, D. Y.; Dou, S. X. Uniform yolk-shell iron sulfide-carbon nanospheres for superior sodium-iron sulfide batteries. Nat. Commun. 2015, 6, 1−9.
32. [32]
  Augustyn, V.; Come, J.; Lowe, M. A.; Kim, J. W.; Taberna, P. L.; Tolbert, S. H.; Abruña, H. D.; Simon, P.; Dunn, B. High-rate electrochemical energy storage through Li⁺ intercalation pseudocapacitance. Nat Mater. 2013, 12, 518−522. doi: 10.1038/nmat3601
33. [33]
  Augustyn, V.; Simon, P.; Dunn, B. Pseudocapacitive oxide materials for high-rate electrochemical energy storage. Energy Environ. Sci. 2014, 7, 1597−1614. doi: 10.1039/c3ee44164d
34. [34]
  Li, D. D.; Zhang, L.; Chen, H. B.; Wang, J.; Ding, L. X.; Wang, S. Q.; Ashman, P. J.; Wang, H. H. Graphene-based nitrogen-doped carbon sandwich nanosheets: a new capacitive process controlled anode material for high-performance sodium-ion batteries. J. Mater. Chem. A 2016, 4, 8630−8635. doi: 10.1039/C6TA02139E
35. [35]
  Li, S.; Qiu, J. X.; Lai, C.; Ling, M.; Zhao, H. J.; Zhang, S. Q. Surface capacitive contributions: towards high rate anode materials for sodium ion batteries. Nano Energy 2015, 12, 224−230. doi: 10.1016/j.nanoen.2014.12.032
36. [36]
  Zhang, M.; Hu, Y. J.; Cheng, J. F.; Fu, W. W.; Shen, Z. R. Synthesis of highly-ordered two-dimensional hierarchically porous carbon nanosheet stacks as advanced electrode materials for lithium-ion storage. ACS Appl. Energy Mater. 2020, 4, 226−232.
37. [37]
  Chen, Y. N.; Fu, K.; Zhu, S. Z.; Luo, W.; Wang, Y. B.; Li, Y. J.; Hitz, E.; Yao, Y. G.; Dai, J. Q.; Wan, J. Y.; Danner, V. A.; Li, T.; Hu, L. B. Reduced graphene oxide films with ultrahigh conductivity as Li-ion battery current collectors. Nano Lett. 2016, 16, 3616−3623. doi: 10.1021/acs.nanolett.6b00743
38. [38]
  Ventosa, E.; Madej, E.; Zampardi, G.; Mei, B.; Weide, P.; Antoni, H.; Mantia, F. L.; Muhler, M.; Schuhmann, W. Solid electrolyte interphase (SEI) at TiO₂ electrodes in Li-ion batteries: defining apparent and effective SEI based on evidence from X-ray photoemission spectroscopy and scanning electrochemical microscopy. ACS Appl. Mater. Inter. 2017, 9, 3123−3130. doi: 10.1021/acsami.6b13306
39. [39]
  Ren, H.; Yu, R. B.; Qi, J.; Zhang, L. J.; Jin, Q.; Wang, D. Hollow multishelled heterostructured anatase/TiO₂ (B) with superior rate capability and cycling performance. Adv. Mater. 2019, 31, 1805754−7. doi: 10.1002/adma.201805754
40. [40]
  Hao, B.; Yan, Y.; Wang, X. B.; Chen, G. Synthesis of anatase TiO₂ nanosheets with enhanced pseudocapacitive contribution for fast lithium storage. ACS Appl. Mater. Inter. 2013, 5, 6285−6291. doi: 10.1021/am4013215
41. [41]
  Lou, S. F.; Zhao, Y.; Wang, J. J.; Yin, G. P.; Du, C. Y.; Sun, X. L. Ti-based oxide anode materials for advanced electrochemical energy storage: lithium/sodium ion batteries and hybrid pseudocapacitors. Small 2019, 15, 1904740−44. doi: 10.1002/smll.201904740
42. [42]
  Muller, G. A.; Cook, J. B.; Kim, H. S.; Tolbert, S. H.; Dunn, B. High performance pseudocapacitor based on 2D layered metal chalcogenide nanocrystals. Nano Lett. 2015, 15, 1911−1917. doi: 10.1021/nl504764m
43. [43]
  Que, L. F.; Yu, F. D.; Wang, Z. B.; Gu, D. M. Pseudocapacitance of TiO_2-x/CNT anodes for high-performance quasi-solid-state Li-ion and Na-ion capacitors. Small 2018, 14, 1704508−9. doi: 10.1002/smll.201704508
44. [44]
  Wei, H.; Rodriguez, E. F.; Hollenkamp, A. F.; Bhatt, A. I.; Chen, D. H.; Caruso, R. A. High reversible pseudocapacity in mesoporous yolk-shell anatase TiO₂/TiO₂ (B) microspheres used as anodes for Li-ion batteries. Adv. Funct. Mater. 2017, 27, 1703270−9. doi: 10.1002/adfm.201703270
45. [45]
  Xing, Y. L.; Wang, S. B.; Fang, B. Z.; Song, G.; Wilkinson, D. P.; Zhang, S. C. N-doped hollow urchin-like anatase TiO₂@C composite as a novel anode for Li-ion batteries. J. Power Sources 2018, 385, 10−17. doi: 10.1016/j.jpowsour.2018.02.077
46. [46]
  Augustyn, V.; Come, J.; Lowe, M. A.; Kim, J. W.; Taberna, P.; Tolbert, S. H.; Abruña, H. D.; Simon, P.; Dunn, B. High-rate electrochemical energy storage through Li⁺ intercalation pseudocapacitance. Nat. Mater. 2013, 12, 518−522. doi: 10.1038/nmat3601
47. [47]
  Jiang, J. M.; Zhang, Y. D.; An, Y. F.; Wu, L. Y.; Zhu, Q.; Dou, H.; Zhang, X. G. Engineering ultrathin MoS₂ nanosheets anchored on N-Doped carbon microspheres with pseudocapacitive properties for high-performance lithium-ion capacitors. Small. Methods 2019, 7, 1900081−10.
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In-situ Growth of Carbon Nanosheets Intercalated with TiO2 for Improving Electrochemical Performance and Stability ofLithium-ion Batteries

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In-situ Growth of Carbon Nanosheets Intercalated with TiO₂ for Improving Electrochemical Performance and Stability ofLithium-ion Batteries