Citation: Xin YANG, Zheng-Dong WANG, Yu-Ru FU, Qin LIU, Gao XIAO. Ca₂Nb₂O₇ as a Novel Open-framework Anode Material for Potassium-ion Batteries[J]. Chinese Journal of Structural Chemistry, ;2021, 40(2): 233-238. doi: 10.14102/j.cnki.0254-5861.2011-2862 shu

Ca₂Nb₂O₇ as a Novel Open-framework Anode Material for Potassium-ion Batteries

Xin YANG ^{a, b} ,
Zheng-Dong WANG ^{a, c} ,
Yu-Ru FU ^a ,
Qin LIU ^a,, ,
Gao XIAO ^{c, d,,}

a.
CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
b.
University of Chinese Academy of Sciences, Beijing100039, China
c.
Department of Environmental Science and Engineering, College of Environment and Resources, Fuzhou University, Fuzhou 350108, China
d.
State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou 350116, China

Corresponding author: Qin LIU, liuqin365@fjirsm.ac.cn Gao XIAO, xiaogao@fzu.edu.cn
Received Date: 27 April 2020
Accepted Date: 18 June 2020

Fund Project: the Natural Science Foundation of Fujian Province 2018J01031Open Project Program of the State Key Laboratory of Photocatalysis on Energy and Environment SKLPEE-202013Natural Science Foundation of Fujian Province 2017J01412National Natural Science Foundation of China 21506036

Figures(4)

Potassium-ion batteries (KIBs) are a promising alternative to Lithium-based energy storage systems owning to the low cost and rich abundance of potassium resources, but are facing challenges in designing low-cost hosts that can reversibly accommodate large-size K⁺ with fast diffusion kinetics. Herein, we report a novel 3D inorganic open framework of Ca₂Nb₂O₇ (CNO) as an anode for KIBs. The open framework structure affords interstitial vacancies available for storing K⁺ and allows a facile diffusion of K⁺, thus resulting in excellent structural stability and fast reaction kinetics. The CNO electrode delivers a reversible specific capacity of 65.3 and 52.2 mAh/g at 5 and 10 mA/g, respectively. Moreover, CNO exhibits excellent long-term cyclability with 92.53% capacity retention over 700 cycles at 10 mA/g. This will trigger more investigations into open-framework-based materials for stable and fast KIBs.
- potassium-ion batteries,
- inorganic-open-framework,
- long lifespan,
- kinetics
1. [1]
  An, W.; Gao, B.; Mei, S.; Xiang, B.; Fu, J.; Wang, L.; Zhang, Q.; Chu, P. K.; Huo, K. Scalable synthesis of ant-nest-like bulk porous silicon for high-performance lithium-ion battery anodes. Nat. Commun. 2019, 10, 1447−1458. doi: 10.1038/s41467-019-09510-5
2. [2]
  Kundu, D.; Adams, B. D.; Duffort, V.; Vajargah, S. H.; Nazar, L. F. A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode. Nat. Energy 2016, 1, 16119−16125. doi: 10.1038/nenergy.2016.119
3. [3]
  Li, D.; Zhang, Y.; Sun, Q.; Zhang, S.; Wang, Z.; Liang, Z.; Si, P.; Ci, L. Hierarchically porous carbon supported Sn₄P₃ as a superior anode material for potassium-ion batteries. Energy Storage Mater. 2019, 23, 367−374. doi: 10.1016/j.ensm.2019.04.037
4. [4]
  Wang, W.; Bao, J. Z.; Sun, C. F. Liquid-phase exfoliated WS₂-graphene composite anodes for potassium-ion batteries. Chin. J. Struct. Chem. 2020, 39, 493−499.
5. [5]
  Zhang, Q.; Wang, Z. J.; Zhang, S. L.; Zhou, T. F.; Mao, J. F.; Guo, Z. P. Cathode materials for potassium-ion batteries: current status and perspective. Electrochem. Energy Rev. 2018, 1, 625−658. doi: 10.1007/s41918-018-0023-y
6. [6]
  Xue, L.; Li, Y.; Gao, H.; Zhou, W.; Lu, X.; Kaveevivitchai, W.; Manthiram, A.; Goodenough, J. B. Low-cost high-energy potassium cathode. J. Am. Chem. Soc. 2017, 139, 2164−2167. doi: 10.1021/jacs.6b12598
7. [7]
  He, G.; Nazar, L. F. Crystallite size control of prussian white analogues for nonaqueous potassium-ion batteries. ACS Energy Lett. 2017, 2, 1122−1127. doi: 10.1021/acsenergylett.7b00179
8. [8]
  Hosaka, T.; Kubota, K.; Kojima, H.; Komaba, S. Highly concentrated electrolyte solutions for 4 V class potassium-ion batteries. Chem. Commun. 2018, 54, 8387−8390. doi: 10.1039/C8CC04433C
9. [9]
  Chihara, K.; Katogi, A.; Kubota, K.; Komaba, S. KVPO₄F and KVOPO₄ toward 4 volt-class potassium-ion batteries. Chem. Commun. 2017, 53, 5208−5211. doi: 10.1039/C6CC10280H
10. [10]
  Park, W. B.; Han, S. C.; Park, C.; Hong, S. U.; Han, U.; Singh, S. P.; Jung, Y. H.; Ahn, D.; Sohn, K. S.; Pyo, M. KVP₂O₇ as a robust high-energy cathode for potassium-ion batteries: pinpointed by a full screening of the inorganic registry under specific search conditions. Adv. Energy Mater. 2018, 8, 1703099−1703111. doi: 10.1002/aenm.201703099
11. [11]
  Han, J.; Xu, M.; Niu, Y.; Li, G. N.; Wang, M.; Zhang, Y.; Jia, M.; Li, C. M. Exploration of K₂Ti₈O₁₇ as an anode material for potassium-ion batteries. Chem. Commun. 2016, 52, 11274−11276. doi: 10.1039/C6CC05102B
12. [12]
  Han, J.; Niu, Y.; Bao, S. J.; Yu, Y. N.; Lu, S. Y.; Xu, M. Nanocubic KTi₂(PO₄)₃ electrodes for potassium-ion batteries. Chem. Commun. 2016, 52, 11661−11664. doi: 10.1039/C6CC06177J
13. [13]
  Zhang, R.; Huang, J.; Deng, W.; Bao, J.; Pan, Y.; Huang, S.; Sun, C. F. Safe, low-cost, fast-kinetics and low-strain inorganic-open-framework anode for potassium-ion batteries. Angew. Chem. Int. Ed. 2019, 58, 16474−16479. doi: 10.1002/anie.201909202
14. [14]
  Zhang, R.; Bao, J.; Pan, Y.; Sun, C. F. Highly reversible potassium-ion intercalation in tungsten disulfide. Chem. Sci. 2019, 10, 2604−2612. doi: 10.1039/C8SC04350G
15. [15]
  Zhao, J.; Zou, X.; Zhu, Y.; Xu, Y.; Wang, C. Electrochemical intercalation of potassium into graphite. Adv. Funct. Mater. 2016, 26, 8103−8110. doi: 10.1002/adfm.201602248
16. [16]
  Zhao, S.; Dong, L.; Sun, B.; Yan, K.; Zhang, J.; Wan, S.; He, F.; Munroe, P.; Notten, P. H. L.; Wang, G. K₂Ti₂O₅@C microspheres with enhanced K⁺ intercalation pseudocapacitance ensuring fast potassium storage and long-term cycling stability. Small 2020, 16, 1906131−1906141. doi: 10.1002/smll.201906131
17. [17]
  Lian, P.; Dong, Y.; Wu, Z. S.; Zheng, S.; Wang, X.; Sen, W.; Sun, C.; Qin, J.; Shi, X.; Bao, X. Alkalized Ti₃C₂ MXene nanoribbons with expanded interlayer spacing for high-capacity sodium and potassium ion batteries. Nano Energy 2017, 40, 1−8. doi: 10.1016/j.nanoen.2017.08.002
18. [18]
  Li, L.; Zhang, W.; Wang, X.; Zhang, S.; Liu, Y.; Li, M.; Zhu, G.; Zheng, Y.; Zhang, Q.; Zhou, T.; Pang, W. K.; Luo, W.; Guo, Z.; Yang, J. Hollow-carbon-templated few-layered V₅S₈ nanosheets enabling ultrafast potassium storage and long-term cycling. ACS Nano 2019, 13, 7939−7948. doi: 10.1021/acsnano.9b02384
19. [19]
  Jia, B.; Yu, Q.; Zhao, Y.; Qin, M.; Wang, W.; Liu, Z.; Lao, C. Y.; Liu, Y.; Wu, H.; Zhang, Z.; Qu, X. Bamboo-like hollow tubes with MoS₂/N-doped-C interfaces boost potassium-ion storage. Adv. Funct. Mater. 2018, 28, 1803409−1803418. doi: 10.1002/adfm.201803409
20. [20]
  Yang, L.; Hong, W.; Zhang, Y.; Tian, Y.; Gao, X.; Zhu, Y.; Zou, G.; Hou, H.; Ji, X. Hierarchical NiS₂ modified with bifunctional carbon for enhanced ootassium-ion storage. Adv. Funct. Mater. 2019, 29, 1903454−1903467. doi: 10.1002/adfm.201903454
21. [21]
  Yao, Q.; Zhang, J.; Li, J.; Huang, W.; Hou, K.; Zhao, Y.; Guan, L. Yolk-shell NiS_x@C nanosheets as K-ion battery anodes with high rate capability and ultralong cycle life. J. Mater. Chem. A 2019, 7, 18932−18939. doi: 10.1039/C9TA06292K
22. [22]
  Tai, Z.; Zhang, Q.; Liu, Y.; Liu, H.; Dou, S. Activated carbon from the graphite with increased rate capability for the potassium ion battery. Carbon 2017, 123, 54−61. doi: 10.1016/j.carbon.2017.07.041
23. [23]
  Adams, R. A.; Varma, A.; Pol, V. G. Temperature dependent electrochemical performance of graphite anodes for K-ion and Li-ion batteries. J. Power Sources 2019, 410−411, 124−131.
24. [24]
  Wu, Q.; Shao, Q.; Li, Q.; Duan, Q.; Li, Y.; Wang, H. G. Dual carbon-confined SnO₂ hollow nanospheres enabling high performance for the reversible storage of alkali metal ions. ACS Appl. Mater. Interfaces 2018, 10, 15642−15651. doi: 10.1021/acsami.8b00605
25. [25]
  Park, M.; Zhang, X.; Chung, M.; Less, G. B.; Sastry, A. M. A review of conduction phenomena in Li-ion batteries. J. Power Sources 2010, 195, 7904−7929. doi: 10.1016/j.jpowsour.2010.06.060
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Ca₂Nb₂O₇ as a Novel Open-framework Anode Material for Potassium-ion Batteries