Citation: Jian-Feng DIAO, Zhi-Xin XIE, Pei-Xin LI, Guo-Cong GUO. A New 1-D Chain of γ-Hg₃S₂Br₂ Constructed from Hg₄S₄ Squares: Solid-state Synthesis, Structure and Optical Properties[J]. Chinese Journal of Structural Chemistry, ;2021, 40(2): 264-269. doi: 10.14102/j.cnki.0254-5861.2011-2816 shu

A New 1-D Chain of γ-Hg₃S₂Br₂ Constructed from Hg₄S₄ Squares: Solid-state Synthesis, Structure and Optical Properties

a.
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
c.
Department of Chemistry, Faculty of Arts and Science, University of Toronto, Toronto, Ontario M5S3H6, Canada

Corresponding author: Guo-Cong GUO, gcguo@fjirsm.ac.cn
Received Date: 18 March 2020
Accepted Date: 20 April 2020

Fund Project: the NSF of China 21871264the NSF of Fujian Province 2018J01028the NSF of Fujian Province 2018J05034

Figures(4)

A new metal chalcogenide, γ-Hg₃S₂Br₂ (1), has been prepared by moderate-temperature solid-state reaction, and its crystal structure was determined by single-crystal X-ray diffraction analysis. Compound 1 crystallizes in space group Cmmm of orthorhombic system with a = 9.1923(18), b = 18.2262(5), c = 4.6251(7) Å, V = 774.9(3) Å³ and Z = 4. In the structure, two Hg(1), two Hg(2) and four S(1) atoms form a near square Hg₄S₄, and such squares are linked by Hg(3) atoms nearly linearly coordinated to two S1 atoms of two parallel Hg₄S₄ squares to form one-dimensional infinite Hg₆S₄ chains along c direction. Optical absorption spectra reveal the presence of sharp optical gap of 2.80 eV for 1. IR spectrum, TGA and electric resistivity have been investigated.
- crystal structure,
- metal chalcogenides,
- resistance,
- semiconductor,
- solid-state reaction
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A New 1-D Chain of γ-Hg₃S₂Br₂ Constructed from Hg₄S₄ Squares: Solid-state Synthesis, Structure and Optical Properties