Citation: Xun FENG, Ya-Pei SHANG, Li-Ya WANG, Man-Zhou HONG, Hai-Peng FANG, Xin ZHAO, Zhong-Jun LI. A New Manganese Coordination Polymer Based on Azobenzene Tetracarboxylate and Auxiliary Pyridine Ligand: Synthesis, Crystal Structure and Magnetic Property[J]. Chinese Journal of Structural Chemistry, ;2021, 40(2): 217-224. doi: 10.14102/j.cnki.0254-5861.2011-2809 shu

A New Manganese Coordination Polymer Based on Azobenzene Tetracarboxylate and Auxiliary Pyridine Ligand: Synthesis, Crystal Structure and Magnetic Property

a.
College of Chemistry and Chemical Engineering and Henan Key Laboratory of Function Oriented Porous Materials, Luoyang Normal University, Luoyang 471934, China
b.
College of Chemistry and Pharmacy Engineering, Nanyang Normal University, Nanyang 473601, China
c.
College of Chemistry, Zhengzhou University, Zhengzhou 450001, China

Corresponding author: Xun FENG, fengx@lynu.edu.cn; wlya@lynu.edu.cn
Received Date: 16 March 2020
Accepted Date: 2 July 2020

Fund Project: the National Foundation for Science of China U1804131the National Foundation for Science of China 21671114Foundation for Science & Technology Innovation Talents in Henan province 16410010012

Figures(6)

A new manganese coordination polymer (CP) has been synthesized under hydrothermal conditions. It's formula is {Mn₂(Oaobtc)(bpe)(H₂O)₄]}_n, where H₄Oobtc represents oxide azobenzene 2, 2΄, 3, 3΄-tetracarboxyl acid, and bpe is 1,2-bis(4-pyridine) ethylene. It was characterized by elemental analysis, infrared spectrum and X-ray single-crystal diffraction. The coordination polymer crystallizes in the monoclinic system, space group P2₁/c. The central ion was coordinated with H₄Oobtc ligands using bridging model, and carboxylic group connects two adjacent Mn(Ⅱ) ions into dimer units. The oxygen from carboxylates connect these dimer units into a one-dimensional (1D) chain, and N atoms from the bpe further expanded them into three-dimensional (3D) supramolecular edifice, eventually. Variable-temperature magnetic measurements of CP 1 indicate the presence of weak antiferromagnetic exchange between two nearest Mn(Ⅱ) ions with J = –0.367 cm⁻¹.
- acetate bridging,
- manganese(Ⅱ),
- X-ray crystal structure,
- oxidation azoxybenzene-2, 2΄, 3, 3΄-tetracarboxyl acid,
- antiferromagnetic interaction
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