Citation: HUANG Sheng, JIANG Chang, YAO Feng-Feng, KANG Jie. Syntheses, Crystal Structures, and Magnetic Properties of Two Manganese(II) Coordination Polymers Based on Bifunctional Pyridine-benzene Carboxylic Acids[J]. Chinese Journal of Structural Chemistry, ;2016, 35(8): 1260-1268. doi: 10.14102/j.cnki.0254-5861.2011-1174 shu

Syntheses, Crystal Structures, and Magnetic Properties of Two Manganese(II) Coordination Polymers Based on Bifunctional Pyridine-benzene Carboxylic Acids

1.
College of Pharmacy, Fujian Medical University, Fuzhou 350108, China

Received Date: 22 February 2016
Available Online: 3 May 2016
Fund Project: This work was supported by the NSF of Fujian Province (2015J01597) (2015J01597) Collegiate Natural Science Fund of Fujian Province (JK2012019) (JK2012019)

Two manganese(II) coordination polymers, namely, {[Mn(PIP)(BIBP)]·(BIBP)_0.5}_n (1) and {[Mn(PTA)(BIMBP)(H₂O)]·H₂O_0.69}_n (2) (H₂PIP=5-(4-pyridyl)-isophthalic acid, H₂PTA=6-(4-pyridyl)-terephthalic acid, BIBP=4,4'-bis(imidazol-1-yl)biphenyl, and BIMBP=4,4'-bis(imidazol-1-ylmethyl)biphenyl), have been synthesized by using the bifunctional pyrinde-benzene carboxylic acids and bis(imidazole) linkers as mixed ligands to react with MnSO₄, and further characterized by elemental analysis, IR, and PXRD. Compound 1 is in the triclicnic system, space group P1 with a=10.1089(8), b=13.1927(12), c=14.0638(12)Å, α=69.437(2), β=73.2890(10), γ=78.5320(10)°, V=1671.9(2)Å³, Z=2, D_c=1.449 g/cm³, F(000)=705, μ(MoKα)=0.453 mm^-1, S=1.053, R=0.0491 and wR=0.1367 for 5837 unique reflections (R_int=0.0208) with I>2σ(I). Compound 2 belongs to the monoclicnic system, space group C2/c with a=15.199(3), b=19.731(3), c=21.537(5)Å, β=105.228(3)°, V=6232(2)Å³, Z=8, D_c=1.363 g/cm³, F(000)=2648, μ(MoKα)=0.475 mm^-1, S=1.048, R=0.0489 and wR=0.1151 for 7414 unique reflections (R_int=0.0425) with I>2σ(I). Structural analyses reveal that complex 1 is a 4-connected (4⁴.6²)-sql bilayer structure with binuclear[Mn₂(COO)₂] SBU, while complex 2 is a normally (3,5)-connected (4².6⁷.8)(4².6)-3,5L2 monolayer. And the sheets interacted with the adjacent sheets through weak interactions, finally giving a stable three-dimensional (3D) supramolecule. Besides, the variable-temperature magnetic susceptibility measurement of complex 1 was investigated.
- coordination polymer,
- pyridine-benzene carboxylic acid,
- manganese,
- magnetic property,
- bis(imidazole) linkers
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