Citation: ZHAO En-Xiao, LI Fei-Fei, ZHAO Dan. Hydrothermal Syntheses, Crystal Structures and Characteristics of Two New Isostructural Ni(II) Coordination Polymers[J]. Chinese Journal of Structural Chemistry, ;2016, 35(11): 1764-1769. doi: 10.14102/j.cnki.0254-5861.2011-1159 shu

Hydrothermal Syntheses, Crystal Structures and Characteristics of Two New Isostructural Ni(II) Coordination Polymers

1.
Department of Physics and Chemistry, Henan Polytechnic University, Jiaozuo 454000, China

Received Date: 1 February 2016
Available Online: 8 April 2016
Fund Project: This project was supported by the Natural Science Foundation of Henan Province (122300410418, 132200410404) (122300410418, 132200410404)

Two new isostructure nickel(Ⅱ) coordination polymers,[Ni₂(5-Me-ip)(1,2-Bie)(H₂O)₂]_n (1) and [Ni₂(5-Br-ip)(1,2-Bie)(H₂O)₂]_n (2) (5-Me-H₂ip=5-methylisophthalic acid, 5-Br-H₂ip=5-mromoisophthalic acid, 1,2-Bie=1,2-bis(imidazole)ethane), have been synthesized and structurally characterized by single-crystal X-ray diffraction. The result shows that complexes 1 and 2 crystallize in orthorhombic system, space group Pna2₁ with a=16.3602(13), b=10.1465(8), c=21.8803(17) Å, V=3632.1(5) Å³, Z=4, D_c=1.525 g/cm³, F(000)=1728, R=0.0292 and wR=0.0668 for 6646 observed reflections (I>2σ(I)) for complex 1 and a=16.409(3), b=10.1625(17), c=21.918(4) Å, V=3654.9(11) Å³, Z=4, D_c=1.752 g/cm³, F(000)=1936, R=0.0309 and wR=0.0600 for 6809 observed reflections (I>2σ(I)) for complex 2. They both feature zigzag 2D layer structures, which are further staked along the a-axis through π…π and hydrogen interactions to form 3D supramolecular structures.
- crystal structure,
- coordination polymer,
- 5-bromoisophthalic acid,
- 1,2-bis(imidazole)ethane
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