Citation: GUO Rui, OU Zhong-Ping, YE Li-Na, HUANG Wen-Hao, XUE Zhao-Li, TANG Ji-Jun, FANG Yuan-Yuan. Cobalt Triarylcorroles with Sterically Hindered Haloginated Phenyl Rings: Synthesis, Crystal Structure and Catalytic Activity for Electroreduction of Dioxygen[J]. Chinese Journal of Structural Chemistry, ;2016, 35(11): 1754-1763. doi: 10.14102/j.cnki.0254-5861.2011-1156 shu

Cobalt Triarylcorroles with Sterically Hindered Haloginated Phenyl Rings: Synthesis, Crystal Structure and Catalytic Activity for Electroreduction of Dioxygen

1.
School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu

Received Date: 26 January 2016
Available Online: 8 April 2016
Fund Project: Supported by the National Natural Science Foundation of China (No. 21501070, 21071067) (No. 21501070, 21071067)Jiangsu University Foundation (No. 05JDG051) (No. 05JDG051)

Three new cobalt triarylcorroles with sterically hindered haloginated phenyl rings were synthesized and characterized by UV-vis, ¹H NMR spectroscopy, mass spectrometry and electrochemistry. The compounds are represented as (Ar)₃CorCo(PPh₃), where Cor is a trianion of the corrole macrocycle and Ar is a 2-ClPh (1), 2,6-diClPh (2) or 2,6-diFPh (3) group on each of the three meso-positions. The structures of 1 and 3 were characterized in the solid state by single-crystal X-ray analysis. Rotating-disk electrode was utilized to examine the electrocatalytic activity of the corroles for reduction of O₂ in 1.0 M HClO₄. Effect of the sterically hindered meso-substituents on UV-vis spectra and redox potentials as well as the electrocatalytic activity for reduction of dioxygen was discussed.
- cobalt triarylcorroles,
- synthesis,
- crystal structure,
- electrocatalysis,
- oxygen reduction
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