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Citation: LIANG Xiao-Qiang, WU Tao, FAN Zeng-Lu. An 8-Connected Chiral Lanthanide Metal-organic Framework Constructed from Naturally Camphoric Acid:Crystal Structure, Vibrational Circular Dichroism Spectroscopy and Second-order Nonlinear Optical Effect[J]. Chinese Journal of Structural Chemistry, ;2016, 35(11): 1736-1744. doi: 10.14102/j.cnki.0254-5861.2011-1154 shu

An 8-Connected Chiral Lanthanide Metal-organic Framework Constructed from Naturally Camphoric Acid:Crystal Structure, Vibrational Circular Dichroism Spectroscopy and Second-order Nonlinear Optical Effect

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a College of Environmental and Chemical Engineering, Xi'an Polytechnic University, Xi'an 710048, China;
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b College of Textile & Material, Xi'an Polytechnic University, Xi'an 710048, China;
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c State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

Received Date: 25 January 2016
Available Online: 19 February 2016
Fund Project: This work was supported by National Natural Science Foundation of China (21401147) (21401147) Basic Research Program of Natural Science from Shaanxi Provincial Government (2015JQ2032) (2015JQ2032) Scientific Research Program from Education Department of Shaanxi Provincial Government (2013JK0654) (2013JK0654) Opening Foundation from State Key Laboratory of Coordination Chemistry in Nanjing University (201219) (201219)

A chiral lanthanide metal-organic framework based on enantiopure camphoric acid (D-H₂cam),[Nd₃(D-cam)₈(H₂O)₄Cl]_n (1), has been synthesized and characterized by single-crystal X-ray structural analysis, elemental analysis, IR, thermal gravimetric, and X-ray powder diffraction. Crystal data for the title compound are as follows:orthorhombic system, space group P2₁2₁2₁ with a=13.8287(7), b=14.0715(7), c=25.7403(12) Å, V=5008.8(4) Å³, M_r=1333.08, Z=4, F(000)=2644, D_c=1.768 g/cm³, μ(MoKα)=3.189 mm^-1, the final R=0.0351 and wR=0.0814 (I>2σ(I)). Compound 1 displays an 8-connected bcu topology 3D framework and hydrogen-bonding interactions stabilize the solid-state structure. The vibrational circular dichroism (VCD) spectrum and second-order nonlinear optical effect of compound 1 have been studied in the solid state.
- homochiral lanthanide metal-organic framework,
- D-camphoric acid,
- 8-connected,
- VCD spectrum,
- second-order nonlinear optical effect
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