Citation: JIANG Da-Yu, SUI Wei, LIU Bo, WANG Qing-Wei. A Novel Three-dimensional(4,4)-Connected Coordination Polymer Based on Benzotriazole and Thiophene-2,5-dicarboxylic Acid: Synthesis, Crystal Structure,and Luminescence Properties[J]. Chinese Journal of Structural Chemistry, ;2016, 35(9): 1445-1450. doi: 10.14102/j.cnki.0254-5861.2011-1136 shu

A Novel Three-dimensional(4,4)-Connected Coordination Polymer Based on Benzotriazole and Thiophene-2,5-dicarboxylic Acid: Synthesis, Crystal Structure,and Luminescence Properties

JIANG Da-Yu ^a,b ,
SUI Wei ^a,b ,
LIU Bo ^a,b ,
WANG Qing-Wei ^a,b

1.
a Key Laboratory of Preparation and Applications of Environmental Friendly Materials (Jilin Normal University), Ministry of Education, Changchun 130103, China;
2.
b Department of Chemistry, Jilin Normal University, Siping 136000, China

Received Date: 18 January 2016
Available Online: 20 April 2016
Fund Project:

A novel coordination polymer[Zn₂(BTA)₂(TDC)]_n(HBTA=benzotriazole, H₂TDC=thiophene-2,5-dicarboxylic acid) has been synthesized by the reaction of zinc(Ⅱ), H₂TDC and HBTA. This compound is fully structurally characterized by elemental analysis, IR, and single-crystal X-ray crystallography. The bulk new materials were further identified by X-ray powder diffraction. Compound 1 crystallizes in the orthorhombic system, space group Pbcn, with a=9.8825(8), b=9.4047(8), c=20.5567(17)Å, V=1910.6(3)Å³, C₁₈H₁₀N₆O₄SZn₂, M_r=537.12, D_c=1.867 g/cm³, μ(MoKα)=2.662 mm^-1, F(000)=1072, Z=4, S=1.058, the final R=0.0201 and wR=0.0530 for 1700 observed reflections(I>2σ(I)). Its compositional stability and photoluminescence properties were further investigated to establish the structure-property relationships. Structural analysis reveals that this compound is a 3D(4, 4)-connected framework with the(6⁶)(6⁴·8²) topology.
- coordination polymer,
- crystal structure,
- thermal stability analysis,
- fluorescence
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