Citation: WANG Qing, MA Cheng-Bing, CHEN Hui, SUN Lei, HUANG De-Guang, CHEN Chang-Neng. Syntheses and Crystal Structures of the First Row Transition Metals with 1,6-Bis(2'-pyridyl)-2,5-dithiahexane[J]. Chinese Journal of Structural Chemistry, ;2016, 35(9): 1451-1460. doi: 10.14102/j.cnki.0254-5861.2011-1123 shu

Syntheses and Crystal Structures of the First Row Transition Metals with 1,6-Bis(2'-pyridyl)-2,5-dithiahexane

WANG Qing ^a.b ,
MA Cheng-Bing ^a ,
CHEN Hui ^a ,
SUN Lei ^a,b ,
HUANG De-Guang ^a ,
CHEN Chang-Neng ^a,,

1.
a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China;
2.
b University of Chinese Academy of Sciences, Beijing 100039, China

Corresponding author: CHEN Chang-Neng,
Received Date: 11 January 2015
Available Online: 4 March 2016
Fund Project:

Six first row transition metal complexes with 1,6-bis(2'-pyridyl)-2,5-dithiahexane(Py₂S₂), namely, MnPy₂S₂Cl₂(1), FePy₂S₂Cl₂(2), CoPy₂S₂Cl(3), CoPy₂S₂(SCN)₂(4), NiPy₂S₂(SCN)₂(5) and NiPy₂S₂(N₃)₂(6), have been synthesized. A mixture of MCl₂·x H₂O(M=Mn, Co) in MeOH(FeCl₂·4H₂O in MeCN) and the stoichiometric amount of Py₂S₂ was stirred for 4 h at room temperature, then these aiming products 1, 2 and 3 could be obtained by purification. A mixture of MPy₂S₂Cl₂(M=Co, Ni) in MeOH and two equivalents of KSCN or NaN₃ was stirred for 4 h at room temperature. After that, complexes 4, 5 and 6 could be got by purifying. For 1, 2, 3, 4 and 5, the metal centers are hexa-coordinated in a similar distorted octahedral geometry and the crystal structures have the same space group Pbcn. The crystal structure of compound 6 belongs to monoclinic with space group P2_1/c. The coordinated atoms around M(Ⅱ) are two pyridyl N atoms(N(1) and N(2)), two thioether S atoms(S(1) and S(2)) and two chloride ions(Cl(1) and Cl(2)) in compounds 1, 2, and 3, but in 4, 5, and 6, two chloride ions(Cl(1) and Cl(2)) are replaced by another two N atoms from N₃^- or NCS^-.
- Py₂S₂,
- synthesis,
- spectral characterization analysis
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