Citation: WANG Xiu-Ren, LI Zi-Jian, GONG Wei, LIU Yan, LIU Bai-Zhan, CUI Yong. A Novel TADDOL-based Chiral Metal-organic Framework:Synthesis, Structure and Photoluminescence Study[J]. Chinese Journal of Structural Chemistry, ;2016, 35(9): 1399-1405. doi: 10.14102/j.cnki.0254-5861.2011-1093 shu

A Novel TADDOL-based Chiral Metal-organic Framework:Synthesis, Structure and Photoluminescence Study

WANG Xiu-Ren ^a ,
LI Zi-Jian ^a ,
GONG Wei ^a ,
LIU Yan ^a,b ,
LIU Bai-Zhan ^b ,
CUI Yong ^a,b

1.
a School of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China;
2.
b China Tobacco, Shanghai 200240, China

Received Date: 21 December 2015
Available Online: 23 February 2016
Fund Project:

A new C₂-symmetric TADDOL-based ligand H₄L was designed and synthesized from readily available tartaric acid and was used to construct a novel TADDOL-based chiral metal-organic framework {[Co₂L(DMA)(H₂O)₅]·2DMA}_n 1(DMA=N,N'-dimethylacetamide). It was characterized by single-crystal and powder X-ray diffraction, Fourier-transform infrared spectra(FTIR), solid-state circular dichroism(CD) and thermal gravimetric analysis(TGA). 1 crystallizes in the chiral orthorhombic space group P2₁2₁2₁ with a=9.7060(8), b=15.5661(1), c=44.564(3)Å, V=6732.9(9)Å³, Z=4, M_r=1394.08, D_c=1.375 g/cm³, F(000)=2888, GOOF=1.032, the final R=0.0607 and wR=0.1582 for 21374 observed reflections with I>2σ(I). Each Co₂ cluster in 1 is linked by three ligands and each ligand is coordinated to three Co₂ clusters with one free carboxylate group, thus generating a 2D network. These 2D networks are further extended into a 3D supramolecule framework by the hydrogen bonding interactions(O-H…O) in an A-B-A-B stacking mode. Additionally, the photoluminescence of 1 and H₄L were also investigated.
- TADDOL,
- chiral metal-organic framework,
- photoluminescence
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