Citation: HAO Xue-Na, ZHENG Bao-Hua, HU Tuo-Ping. Syntheses and Characterizations of Cd(II) and Pr(III) Complexes Based on 5-(Tetrazol-5-yl) Isophthalic Acid[J]. Chinese Journal of Structural Chemistry, ;2016, 35(8): 1186-1194. doi: 10.14102/j.cnki.0254-5861.2011-1072 shu

Syntheses and Characterizations of Cd(II) and Pr(III) Complexes Based on 5-(Tetrazol-5-yl) Isophthalic Acid

1.
College of Science, North University of China, Taiyuan 030051, China

Corresponding author: HU Tuo-Ping,
Received Date: 1 December 2015
Available Online: 15 March 2016
Fund Project: Supported by the International Science & Technology Cooperation Program of China (No. 2011DFA51980) (No. 2011DFA51980) "131" Leading Talents Project in Colleges and Universities, Science and Technology Innovation Project of Shanxi Province (No. 2014101002) (No. 2015081043)

Hydrothermal reactions of 5-(tetrazol-5-yl) isophthalic acid with cadmium nitrate/praseodymium nitrate led to two complexes of [Cd₃(TZI)₂(H₂O)₁₁]_n (1) and [Pr(TZI)(H₂O)5]_n (2). Their structures and properties were determined by X-ray diffraction, IR spectroscopy, fluorescence spectrum, thermal gravimetric analyses and elemental analysis. Complex 1 belongs to monoclinic system, I2/c space group, with a=12.8688(3), b=18.0925(3), c=14.5190(3)Å, β=116.054(3)°, V=3036.92(13)Å³, Z=4; complex 2 crystallizes in triclinic, space group P1, with a=7.9690(5), b=9.7665(8), c=10.4353(9)Å, α=116.709(9), β=107.461(6), γ=95.671(6)°, V=665.54(9)Å³ and Z=2. Complex 1 is a 3D planar structure. Complex 2 is a one-dimensional double chain configuration and extends into a 3D network by hydrogen bonds and π-π interactions.
- metal-organic complexes,
- hydrothermal synthesis,
- 5-(tetrazol-5-yl) isophthalic acid ligand
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