Citation: XIAO Li, LI Wei-Dong, FANG Xu, JIANG Lian-Yan, CHEN Shui-Sheng. Two Three-dimensional Supramolecular Polymer Built from Mixed N-Donor and Carboxylate Ligands[J]. Chinese Journal of Structural Chemistry, ;2016, 35(5): 781-788. doi: 10.14102/j.cnki.0254-5861.2011-0951 shu

Two Three-dimensional Supramolecular Polymer Built from Mixed N-Donor and Carboxylate Ligands

1.
College of Chemistry & Chemical Engineering, Fuyang Normal University, Fuyang 236041, China

Corresponding author: CHEN Shui-Sheng,
Received Date: 20 August 2015
Available Online: 27 November 2015
Fund Project: This work was supported by the National Natural Science Foundation of China (No. 21171040) (No. 21171040)National Undergraduates Innovation Project (201510371010) (No. 2013JCJS01)

Two new complexes, [Mn(L)(mmbda)(H₂O)] (1) and [Co(L)(btc)(H₂O)]·H₂O (2), were synthesized by reacting the corresponding metal(II) salts with rigid ligand 1,4-di(1H-imidazol-4-yl)benzene (L) and two different carboxylic acids of 5-methylisophthalic acid (H₂mmbda) and 1,2,4-benzenetricarboxylic acid (H₃btc), respectively. The structures of the complexes were characterized by single-crystal X-ray diffraction, IR spectroscopy, elemental analysis and PXRD. Complex 1 crystallizes in triclinic, space group P with a = 6.9436(4), b = 9.7306(6), c = 15.5302(10) Å, α = 73.7430(10), β = 85.1010(10), γ = 70.0360(10)°, V = 946.75(10) Å³, Z = 2, C₂₁H₂₀N₄O₅Mn, M_r = 463.33, D_c = 1.618 g/cm³, μ = 0.742^-1, S = 1.002, F(000) = 474, the final R = 0.0285 and wR = 0.0600 for 4328 observed reflections (I> 2σ(I)). Complex 2 crystallizes in monoclinic, space group P2₁/n with a = 12.5216(12), b = 7.3312(8), c = 22.510(2) Å, β = 93.104(2)°, V = 2063.3(4) Å³, Z = 4, C₂₁H₁₈N₄O₈Co, M_r = 513.31, D_c = 1.646 g/cm³, μ = 0.892 mm^-1, S = 1.096, F(000) = 1044, the final R = 0.0673 and wR = 0.1780 for 3594 observed reflections (I> 2σ(I)). Both of complexes are one-dimensional (1D) chain structures and rich hydrogen bonds extend such 1D chains to form three-dimensional (3D) supramolecular polymers.
- synthesis,
- supramolecular polymer,
- non-covalent bonding interactions
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沈阳化工大学材料科学与工程学院沈阳 110142