Citation: LIN Xiao-Ying, YANG Pan, CHEN Jun, LIU Ming-Hua, LIN Cheng. Solvothermal Synthesis, Crystal Structure and Photoluminescence Property of a 3D Lead(II) Coordination Polymer Based on Terephthalic Acid[J]. Chinese Journal of Structural Chemistry, ;2016, 35(1): 61-68. doi: 10.14102/j.cnki.0254-5861.2011-0948 shu

Solvothermal Synthesis, Crystal Structure and Photoluminescence Property of a 3D Lead(II) Coordination Polymer Based on Terephthalic Acid

1.
a School of Chemical Engineering, Fuzhou University, Fuzhou 350116, China;
2.
b College of Ecological Environment and Urban Construction, Fujian University of Technology, Fuzhou 350118, China;
3.
c College of Environment and Resources, Fuzhou University, Fuzhou 350116, China

Received Date: 18 August 2015
Available Online: 18 October 2015
Fund Project: This work was supported by the Natural Science Foundation of Fujian province (2015J01033) (2015J01033)

Solvothermal reaction of Pb(NO₃)₂·6H₂O with rigid linear ligand terephthalic acid (H₂pta) in N,N-dimethylformamide (DMF) produced a new three-dimensional (3D) lead(II) coordination polymer [Pb₂(pta)_1.5(μ₄-OH)(DMF)]_n 1, and its structure was characterized by single-crystal X-ray diffraction analyses. In polymer 1, the μ₄-OH bridges the nearby lead(II) ions into an infinite one-dimensional (1D) chain, and then the organic ligand pta^2- joins the neighbored chains into a 3D structure by two similar connection modes in different configurations. The solid-state photoluminescent studies revealed that 1 exhibits a strong greenish emission mainly originating from ligand-to-metal charge transfer between the delocalized π bonds of the aromatic carboxylate ligand pta^2- and the p orbitals of the Pb²⁺ centers.
- solvothermal synthesis,
- lead(II) coordination polymer,
- terephthalic acid,
- photoluminescence property,
- crystal structure
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