Citation: ZHANG Si-Fang, LI Jun. Effect of Anionic Ancillary Ligands on Terpyridine Based Coordination Polymers: Synthesis, Crystal Structure and Fluorescence Property[J]. Chinese Journal of Structural Chemistry, ;2016, 35(5): 811-817. doi: 10.14102/j.cnki.0254-5861.2011-0946 shu

Effect of Anionic Ancillary Ligands on Terpyridine Based Coordination Polymers: Synthesis, Crystal Structure and Fluorescence Property

ZHANG Si-Fang ^a,, ,
LI Jun ^b

a.
a. Department of Chemistry, Taiyuan Normal University, Yuci, Shanxi 030619, China;
b.
b. College of Chemistry and Chemical Engineering, Jinzhong University, Yuci, Shanxi 030619, China

Corresponding author: ZHANG Si-Fang,
Received Date: 14 August 2015
Available Online: 12 November 2015
Fund Project: The work was supported by the Natural Science Foundation of Shanxi Province (2012091003-0102) (2012091003-0102)

By using different anionic ancillary ligands, two new coordination polymers, [Cd(L)I₂]_n (1) and {[Cd(L)₂(1,4-bdc)]·H₂O}_n (2) (L = 2,4,6-tris(4-pyridyl)pyridine, 1,4-H₂bdc = benzene-1,4-dicarboxylic acid), have been synthesized under hydrothermal conditions. Compound 1 crystallizes in monoclinic, space group C2/c with a = 11.625(2), b = 13.871(3), c = 13.676(3) Å, β = 108.11(3)°, V = 2096.0(7) Å³, D_c = 2.144 g/cm³, C₂₀H₁₄I₂N₄Cd, M_r = 676.55, F(000) = 1264, µ(MoKα) = 3.999 mm^–1, Z = 4, R_int = 0.0308, (Δρ)_max = 0.354, (Δρ)_min= 0.289, R = 0.0332 and wR = 0.0721 for 2401 observed reflections (I> 2s(I)). However, compound 2 crystallizes in triclinic, space group P with a = 10.315(2), b = 14.060(3), c = 15.090(3) Å, β = 98.40(3)°, V = 1990.0(9) Å³, D_c = 1.527 g/cm³, C₄₈H₃₄N₈O₅Cd, M_r = 915.23, F(000) = 932, µ(MoKα)= 0.610 mm^–1, Z = 2, R_int= 0.0776, (Δρ)_max = 0.869, (Δρ)_min= 0.843, R = 0.0815 and wR = 0.1930 for 6999 observed reflections (I> 2s(I)). Compound 1 is a 1D chain structure, which adopts inorganic anion I^- as the counterion, and 2 exists a 2D (4,4) network constructed by benzene-1,4-dicarboxylic acid.
- ancillary ligand,
- crystal structure,
- fluorescence
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