Citation: ZHU Xiao-Fei, XIE Xiao-Yan, BI Yan-Feng, YANG Yu, ZHOU De-Feng. A New Europium Coordination Compound Supported by 4,6-Dibenzoylisophthalic Acid LigandsTwo Metal-organic Coordination Polymers[J]. Chinese Journal of Structural Chemistry, ;2016, 35(5): 758-764. doi: 10.14102/j.cnki.0254-5861.2011-0938 shu

A New Europium Coordination Compound Supported by 4,6-Dibenzoylisophthalic Acid LigandsTwo Metal-organic Coordination Polymers

a.
a. School of Chemistry and Life Science, Changchun University of Technology, Changchun 130012, China;
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b. College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun 113001, China

Corresponding author: BI Yan-Feng,
Received Date: 10 August 2015
Available Online: 19 November 2015
Fund Project: the Graduate Student (B2015209299)

A unique metal-organic framework (MOF) [Eu₂(L)₃(phen)₂]_n (1, H₂L = 4,6-diben-zoylisophthalic acid, phen = 1,10-phenanthroline) has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray analysis, elemental analyses, powder X-ray diffraction, TGA measurement as well as IR spectra. The crystal is of triclinic system, space group P , C₉₀H₅₂Eu₂N₄O₁₈, M_r = 1781.32, a = 9.8697(4), b = 16.7466(6), c = 22.2556(10) Å, α = 87.113(3), β = 77.575(5), γ = 89.458(3)°, V = 3587.8(3) Å³, Z = 2, D_c = 1.649 g/cm³, F(000) = 1780, μ(MoKa) = 1.813 mm^-1, R_int = 0.0181, R = 0.0260 and wR = 0.0592 for 14000 observed reflections with I> 2σ(I). X-ray analysis shows that the title compound exhibits a 2D layer structure linked by L ligands with two coordination modes and two distinguished conformations, and further linked into a 3D supramolecular architecture through C–H…O weak interactions between hydrogen of phen phenyl ring and the carboxylate oxygen atom of adjacent sheets. In addition, the luminescence property of 1 was investigated.
- 4,
- 6-dibenzoylisophthalic acid,
- europium,
- coordination modes,
- hydrothermal
1. [1]
  (1) Tian, R. J.; Wang, F. X.; Du, C. Y.; Feng, L. J.; Liu, Y.; Zhang, C. L.; Pan, Q. H. Template-directed synthesis of three metal oxalates via 4-connected building units. Chem. Res. Chin. Univ. 2014, 30, 889-893.
2. [2]
  (2) Rocha, J.; Carlos, L. D.; Paz, F. A. A.; Ananias, D. Luminescent multifunctional lanthanides-based metal-organic frameworks. Chem. Soc. Rev. 2011, 40, 926-940.
3. [3]
  (3) Chen, B.; Xiang, S.; Qian, G. Metal-organic frameworks with functional pores for recognition of small molecules. Acc. Chem. Res. 2010, 43, 1115-1124.
4. [4]
  (4) Cui, Y.; Yue, Y.; Qian, G.; Chen, B. Luminescent functional metal-organic frameworks. Chem. Rev. 2012, 112, 1126-1162.
5. [5]
  (5) Ji, B. M.; Deng, D. S.; Wang, W. Z.; Wang, K.; He, M. L. Structural study on four co-crystals of N-containing heteroaromatics with iodofluorobenzene. Chem. Res. Chin. Univ. 2015, 31, 84-90.
6. [6]
  (6) Allendorf, M. D.; Bauer, C. A.; Bhakta, R. K.; Houk, R. J. T. Luminescent metal-organic frameworks. Chem. Soc. Rev. 2009, 38, 1330-1352.
7. [7]
  (7) Bunzli, J. C. G.; Piguet, C. Taking advantage of luminescent lanthanide ions. Chem. Soc. Rev. 2005, 34, 1048-1077.
8. [8]
  (8) Yang, C.; Fu, L. M.; Wang, Y.; Zhang, J. P.; Wong, W. T.; Ai, X. C.; Qiao, Y. F.; Zou, B. S.; Gui, L. L. A highly luminescent europium complex showing visible-light-sensitized red emission: direct observation of the singlet pathway. Angew. Chem., Int. Ed. 2004, 43, 5010-5013.
9. [9]
  (9) Klink, S. I.; Hebbink, G. A.; Grave, L.; Oude Alink, P. G. B.; van Veggel, F. C. J. M.; Werts, M. H. V. Synergistic complexation of Eu³⁺ by a polydentate ligand and a bidentate antenna to obtain ternary complexes with high luminescence quantum yields. J. Phys. Chem. A 2002, 106, 3681-3689.
10. [10]
  (10) Wang, L. F.; Kang, L. C.; Zhang, W. W.; Wang, F. M.; Ren, X. M.; Meng, Q. J. New europium coordination polymers with efficient energy transfer from conjugated tetracarboxylate ligands to Eu³⁺ ion: syntheses, structures, luminescence and magnetic properties. Dalton Trans. 2011, 40, 9490-9497.
11. [11]
  (11) He, H.; Yuan, D.; Ma, H.; Sun, D.; Zhang, G.; Zhou, H. C. Control over interpenetration in lanthanide-organic frameworks: synthetic strategy and gas-adsorption properties. Inorg. Chem. 2010, 49, 7605-7607.
12. [12]
  (12) Tao, J.; Tong, M. L.; Chen, X. M. Hydrothermal synthesis and crystal structures of three-dimensional co-ordination frameworks constructed with mixed terephthalate (tp) and 4,4'-bipyridine (4,4'-bipy) ligands: [M(tp)(4,4'-bipy)] (M = Co^II, Cd^II or Zn^II). J. Chem. Soc., Dalton Trans. 2000, 36, 3669-3674.
13. [13]
  (13) Guo, X.; Zhu, G.; Sun, F.; Li, Z.; Zhao, X.; Li, X.; Wang, H.; Qiu, S. Synthesis, structure, and luminescent properties of microporous lanthanide metal-organic frameworks with inorganic rod-shaped building units. Inorg. Chem. 2006, 45, 2581-2587.
14. [14]
  (14) Zhou, Y.; Yan, B. Imparting tunable and white-light luminescence to a nanosized metal-organic framework by controlled encapsulation of lanthanide cations. Inorg. Chem. 2014, 53, 3456-3463.
15. [15]
  (15) Gu, X.; Xue, D. Selected controlled synthesis of three-dimensional 4d-4f heterometallic coordination frameworks by lanthanide carboxylate subunits and silver centers. Cryst. Growth Des. 2006, 6, 2551-2557.
16. [16]
  (16) Black, C. A.; Costa, J. S. N.; Fu, W. T.; Massera, C.; Roubeau, O.; Teat, S. J.; Aromí, G.; Gamez, P.; Reedijk, J. 3-D lanthanide metal-organic frameworks: structure, photoluminescence, and magnetism. Inorg. Chem. 2009, 48, 1062-1068.
17. [17]
  (17) Wang, Y. L.; Jiang, Y. L.; Liu, Q. Y.; Tan, Y. X.; Wei, J. J.; Zhang, J. A series of three-dimensional lanthanide(III) coordination polymers of 2,5-dihydroxy-1,4-benzenedicarboxylic acid based on dinuclear lanthanide units. Cryst. Eng. Comm. 2011, 13, 4981-4987.
18. [18]
  (18) MacNeill, C. M.; Day, C. S.; Marts, A.; Lachgar, A.; Noftle, R. E. Synthesis, crystal structure and properties of novel isostructural two-dimensional lanthanide-based coordination polymers with 2,3,5,6-tetrafluoro-1,4-benzenedicarboxylic acid. Inorg. Chim. Acta 2011, 365, 196-203.
19. [19]
  (19) Zhu, X. F.; Zhang, H.; Luo, Y. H.; Pang, Y.; Tian, D. A novel eight-connected metal-organic replica of CsCl based on heptanuclear zinc clusters. Inorg. Chem. Commun. 2011, 14, 562-565.
20. [20]
  (20) Chen, B.; Yang, Y.; Zapata, F.; Qian, G.; Luo, Y.; Zhang J.; Lobkovsky, E. B. Enhanced near-infrared-luminescence in an erbium tetrafluoroterephthalate framework. Inorg. Chem. 2006, 45, 8882-8886.
21. [21]
  (21) Yue, F. X.; Li, B.; Zhu, X. F.; Luo, Y. H.; Hu, J. K.; Wang, X. F.; Zhang, H. Syntheses, structures, and luminescence of three metal carboxylate polymers of 2,5-dibenzoylterephthalic acid and N-donor auxiliary ligands. J. Coord. Chem. 2013, 66, 243-253.
22. [22]
  (22) Zhu, X. F.; Wang, N.; Xie, X. Y.; Hou, R. B.; Zhou, D. F.; Li, Y. F.; Hu, J.; Li, X. Y.; Liu, H.; Nie, W. A new 3D metal-organic framework with tetranuclear cadmium(II) clusters: synthesis, structure, and luminescent property. Chin. J. Struc. Chem. 2014, 33, 277-283.
23. [23]
  (23) Zhao, X.; Yu, X. Y.; Chen, T. L.; Luo, Y. H.; Yang, J. J.; Zhang, H. A series of lanthanide compounds based on mixed aromatic carboxylate ligands: syntheses, crystal structures and luminescent properties. Inorg. Chem. Commun. 2012, 20, 247-251.
24. [24]
  (24) Zhou, Y.; Guan, L.; Zhang, H. Synthesis, crystal structure and properties of cobalt(II) and nickel(II) coordination polymers supported by functionalized dicarboxylate ligands. Polyhedron 2009, 28, 2667-2672.
25. [25]
  (25) Guan, L.; Zhou, Y. H.; Zhang, H. A new 3D coordination framework with helical chains in mixed ligands system: preparation, crystal structure and magnetic property. Inorg. Chem. Commun. 2010, 13, 985-987.
26. [26]
  (26) Pang, Y.; Tian, D.; Zhu, X. F.; Luo, Y. H.; Zheng, X.; Zhang, H. Copper(II) and nickel(II) coordination polymers assembled from 2,4-dibenzoylisophthalic acid and different N-donor co-ligands: syntheses, crystal structures, and magnetic properties. Cryst. Eng. Comm. 2011, 13, 5142-5151.
27. [27]
  (27) Pang, Y.; Tian, D.; Luo, Y.; Zhu, X.; Zhang, H. Synthesis, structure, and magnetism of a new 2-D copper(II) complex based on two different dicarboxylates. J. Coord. Chem. 2011, 64, 2002-2009.
28. [28]
  (28) Zhao, X.; Yu, X. Y.; Chen, T. L.; Luo,Y. H.; Yang, J. J.; Zhang, H. A series of lanthanide compounds based on mixed aromatic carboxylate ligands: syntheses, crystal structures and luminescent properties. Inorg. Chem. Commun. 2012, 20, 247-251.
29. [29]
  (29) Yue, F. X.; Yu, X. Y.; Luo, Y. H.; Yang, J. J.; Chen, X.; Zhang, H. Syntheses, structures, and luminescence of three metal carboxylate polymers of 2,5-dibenzoylterephthalic acid and N-donor auxiliary ligands. J. Coord. Chem. 2013, 66, 2843-2851.
30. [30]
  (30) Luo, Y. H.; Yue, F. X.; Yu, X. Y.; Chen, X.; Zhang, H. Coordination polymers of lanthanide complexes with benzene dicarboxylato ligands. Cryst. Eng. Comm. 2013, 15, 6340-6348.
31. [31]
  (31) Zhu, X. F.; Wang, N.; Xie, X. Y.; Hou, R. B.; Zhou, D. F.; Li, Y. F.; Hu, J.; Li, X. Y.; Liu, H.; Nie, W. A serials of interdigitated Cd(II) coordination polymers based on 4,6-dibenzoylisophthalic acid and flexible triazole ligands. RSC Advances 2014, 4, 15816-15819.
32. [32]
  (32) Zhu, X. F.; Li, B.; Jiang, N.; Yang, Y.; Zhou, D. F.; Fu, H.; Wang, N. Hydrothermal assembly of two new 3D zinc(II) pcu nets: coordination chemistry, crystal structures, and fluorescence properties. Z. Anorg. Allg. Chem. 2015, 641, 699-703.
33. [33]
  (33) Du, D.; Jiang, Z.; Liu, C.; Sakho, A. M.; Zhu, D.; Xu, L. Macrocyclic organotin (IV) carboxylates based on benzenedicarboxylic acid derivatives: syntheses, crystal structures and antitumor activities. J. Organomet. Chem. 2011, 696, 2549-2558.
34. [34]
  (34) Sheldrick, G. M. A short history of SHELEX. Acta Crystallogr., Sect. A: Found. Crystallogr. 2008, 64, 112-122.
35. [35]
  (35) Sun, Y. G.; Jiang, B.; Cui, T. F.; Xiong, G.; Smet, P. F.; Ding, F.; Gao, E. J.; Lv, T. Y.; Van den Eeckhout, K.; Poelman, D.; Verpoort, F. Solvothermal synthesis, crystal structure, and properties of lanthanide-organic frameworks based on thiophene-2,5-dicarboxylic acid. Dalton Trans. 2011, 40, 11581-11590.
36. [36]
  (36) Yang, Q. F.; Yu, Y.; Song, T. Y.; Yu, J. H.; Zhang, X.; Xu, J. Q.; Wang, T. G. 2D and 3D networks of lanthanide with mixed dicarboxylate ligands: syntheses, crystal structures and photoluminescent properties. Cryst. Eng. Comm. 2009, 11, 1642-1649.
37. [37]
  (37) Xiao, X. Y.; Wei, Y. Q.; Zheng, W. X.; Wu, K. C. 1D Lanthanide coordination polymers based on 3-(pyridin-4-yl)benzoic acid: syntheses, structures and luminescent properties. Chin. J. Struc. Chem. 2011, 30, 1543-1550.
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