Citation: HUANG Wen-Huan, LIU Tong, WANG Yan-Xin, LIU Shu-Ya, LI Jia-Zhi, YIN Hai-Ju, ZHANG Ya-Nan. Syntheses, Structures, and Properties of Three New Polymers Based on Flexible and Rigid Ligands[J]. Chinese Journal of Structural Chemistry, ;2016, 35(4): 621-632. doi: 10.14102/j.cnki.0254-5861.2011-0899 shu

Syntheses, Structures, and Properties of Three New Polymers Based on Flexible and Rigid Ligands

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College of Chemistry & Chemical Engineering, Shaanxi University of Science & Technology, Xi'an 710021, China

Received Date: 20 June 2015
Available Online: 29 November 2015
Fund Project: This work was supported by the National Natural Science Foundation of China (No. 21401121) (No. 21401121) Natural Science Foundation of Shaanxi Province (No. 2014JQ2061) (No. 2014JQ2061)Doctor Foundation of Shaanxi Unversity of Science & Technology (BJ14-22) (BJ14-22)

Three new supramolecular polymers,[(IP)(H₂SO₄)(H₂O)] (1),[(H₂SDC)(BPA)] (2) and[Mn(SDC)(IP)₂]_n (3), have been constructed by three modes (rigid IP, rigid SDC+flexible BPA, rigid IP+rigid SDC). Polymers 1 and 2 are supramolecular structures, assembled by hydrogen bonds and π…π interactions. X-ray structure analysis of 3 shows waved 1D chains which form a 3D supramolecular network by hydrogen bonds and π…π interactions. Solid-state properties of thermal stability, luminescent properties, and X-ray powder diffractions for these crystalline materials have also been investigated, and polymer 3 is considered to be a good stable luminescence material.
- rigid ligand,
- flexible ligand,
- coordination polymers,
- supramolecular polymer,
- luminescence
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沈阳化工大学材料科学与工程学院沈阳 110142