Citation: FAN Yi-Kang, XIE Bin, XIE Feng, WU Wei-Ping, ZOU Li-Ke, NAREN Ge-Ri-Lea, WEI Jiana. Two 3D Metal-organic Frameworks with 4-Fold[2+2]-type Interpenetrated hms Nets Based on a Flexible Tricarboxylic Acid[J]. Chinese Journal of Structural Chemistry, ;2016, 35(4): 605-614. doi: 10.14102/j.cnki.0254-5861.2011-0898 shu

Two 3D Metal-organic Frameworks with 4-Fold[2+2]-type Interpenetrated hms Nets Based on a Flexible Tricarboxylic Acid

FAN Yi-Kang ^a ,
XIE Bin ^a,b ,
XIE Feng ^c ,
WU Wei-Ping ^a,b ,
ZOU Li-Ke ^a,b ,
NAREN Ge-Ri-Lea ^a ,
WEI Jiana ^a

1.
a Institute of Functional Materials, Sichuan University of Science & Engineering, Zigong 643000, China;
2.
b University Key Laboratory of Green Chemistry of Sichuan Institutes of Higher Education, Zigong 643000, China;
3.
c College of Chemistry and Chemical Engineering, Neijiang Normal University, Neijiang 641100, China

Received Date: 16 July 2015
Available Online: 21 October 2015
Fund Project: Sichuan University of Science and Engineering (Y2014018) (LZJ14201)

Two 3D 4-fold interpenetrated metal-organic frameworks,[Mn(L)(bpy)]_n (1) and[Cu(HL)(bpy)]_n (2) (H₃L=4,4',4''-(benzene-1,3,5-triyl-tri(methyleneoxy)) tribenzoic acid, bpy=4,4'-bipyridine), were synthesized under hydrothermal conditions, and characterized by element analyses, IR spectra, thermogravimetric analyses, X-ray powder diffraction and magnetic property studies. The single-crystal X-ray analyses revealed that 1 and 2 are homogeneous. 2 crystallizes in monoclinic, space group Cc with a=26.794(2), b=11.6346(10), c=21.4614(18) Å, β=91.570(2)°, V=6687.9(10) Å³, Z=8, M_r=736.59, Dc=1.463 g·cm^-3, μ=0.458 mm^-1, R_int=0.0524, F(000)=3040, the final R=0.0844 and wR=0.2266 for 8092 observed reflections (I > 2σ(I)). 2 crystallizes in monoclinic, space group Cc with a=27.609(12), b=11.126(10), c=21.490(9) Å, β=92.131(2)°, V=6597(5) Å³, Z=8, M_r=746.21, Dc=1503 g·cm^-3, μ=0.726 mm^-1, R_int=0.0542, F(000)=3080, the final R=0.0681 and wR=0.1831 for 6777 observed reflections (I>2σ(I)). Two compounds are 3D[2+2]-type 4-fold interpenetrated frameworks with (63)(69.8) hms topology. The magnetic study of compound 2 shows the presence of weak antiferromagnetic interaction between the Cu^Ⅱ ions in 2.
- metal-organic frameworks,
- 4,4',4"-(benzene-1,3,5-triyl-tri(methyleneoxy)) tribenzoic acid,
- 4-fold interpenetration,
- hms networks
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