Citation: ZHANG Lei, ZHAO Bin, TIAN Lai-Jin, HOU Ke-Ning, LI Yan-Xin. Synthesis and Crystal Structure of a Novel Bis(chlorido)-bridged One-dimensional Chain-like Copper(II) Polymer[J]. Chinese Journal of Structural Chemistry, ;2016, 35(4): 633-639. doi: 10.14102/j.cnki.0254-5861.2011-0891 shu

Synthesis and Crystal Structure of a Novel Bis(chlorido)-bridged One-dimensional Chain-like Copper(II) Polymer

1.
a College of Chemistry and Chemical Engineering, Qufu Normal University, Qufu, Shangdong 273165, China;
2.
b College of Petrochemical Engineering, Changzhou University, Changzhou 213164, China

Received Date: 13 June 2015
Available Online: 18 November 2015

A copper(Ⅱ) complex[LCu₂C₁₄]_n was synthesized by a new bis-Schiff base ligand containing quinoline unit, 1,4-bis[2-(4-fluorophenyl)iminomethyl-8-quinolinoxy]butane (L). X-ray crystal structure shows that it is a binuclear complex, and the crystal belongs to the triclinic system, space group P1, with a=9.387(2), b=9.968(2), c=10.291(2) Å, α=87.532(3), β=63.762(2), γ=86.628(3)°, V=862.1(3) Å³, Z=1, Dc=1.640 Mg/m³, F(000)=428, R=0.0416 and wR=0.1141. E_ach Cu(Ⅱ) metal ion coordinates with a quinoline N atom, an imine N atom, an ether oxygen atom and three chlorides, forming a distorted six-coordinated octahedronal structure. E_ach copper(Ⅱ) complexation unit links with one of the adjacent ligand copper complexation units through the chlorido bridging groups, thus generating an infinite one-dimensional chain structure. Such 1D chains further construct a 2D network structure by π-π stacking interactions.
- Schiff base,
- copper,
- complex polymer,
- crystal structure,
- quinoline derivatives
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沈阳化工大学材料科学与工程学院沈阳 110142