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Citation: CHEN Lin, WANG Yu-Ling, LIU Qing-Yan, YAO Yang. Solvothermal Synthesis, Crystal Structure and Luminescent Property of a Two-dimensional Lead(II) Compound: [Pb(bmzbc)2]n[J]. Chinese Journal of Structural Chemistry, ;2016, 35(4): 615-620. doi: 10.14102/j.cnki.0254-5861.2011-0886 shu

Solvothermal Synthesis, Crystal Structure and Luminescent Property of a Two-dimensional Lead(II) Compound: [Pb(bmzbc)2]n

  • 1.

    a College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China;

  • 2.

    b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

  • Received Date: 9 July 2015
    Available Online: 16 September 2015

    Fund Project: Science Founds of State key laboratory of Structural Chemistry (20130011) (No. 20151BAB203002)

  • A two-dimensional coordination polymer,[Pb(bmzbc)2]n (1) (Hbmzbc=4-benzimidazole-1-yl-benzoic acid), has been synthesized by the solvothermal reaction of Pb(NO3)2 with Hbmzbc at 120℃ in ethanol solvent. Compound 1 has been characterized by single-crystal X-ray diffraction, powder X-ray diffraction, thermogravimetry analysis, and IR spectrum. Compound 1 crystallizes in the orthorhombic system, space group Pccn, with a=12.5801(7), b=20.0795(11), c=9.1830(6) Å, V=2319.6(2) Å3, Z=4, C28H18N4O4Pb, Mr=681.65, Dc=1.952 g/cm3, μ=7.319 mm-1, F(000)=1312, the final R=0.0336 and wR=0.0965 for 1699 observed reflection with I>2σ(I). In 1, the bmzbc-ligands bridge the Pb(Ⅱ) ions to generate a 2-D sheet with (4, 4) topology. The complex exhibits turquoise photoluminescent emission with a maximum at 480 nm upon excitation at 300 nm.
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