Citation: REN Yi-Xia, AN Miao, GAO Lou-Jun, CHAI Hong-Mei, HOU Xiang-Yang, ZHOU Gui-Jiang. Structural Diversity and Photoluminescent Properties of Two Mn(II) Sulfoterephthalate Complexes from Multi-pyridine N-containing Ligands[J]. Chinese Journal of Structural Chemistry, ;2016, 35(4): 550-558. doi: 10.14102/j.cnki.0254-5861.2011-0874 shu

Structural Diversity and Photoluminescent Properties of Two Mn(II) Sulfoterephthalate Complexes from Multi-pyridine N-containing Ligands

1.
a Department of Chemistry, Faculty of Science, Xi'an Jiaotong University, Xi'an 710049, China;
2.
b College of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an, Shaanxi 716000, China

Corresponding author: REN Yi-Xia,
Received Date: 30 June 2015
Available Online: 8 October 2015
Fund Project: This project is supported by the Postdoctoral Science Foundation of China (No. 2014M562403) (No. 2014M562403)National Natural Science Foundation of China (No. 21573189) (No. 21573189)

Solvothermal reaction of manganese(Ⅱ) salt with monosodium 2-sulfoterephthalate (2-NaH₂stp) and two multi-pyridine N-containing auxiliary ligands results in the formation of two new complexes formulated with[Mn₂(Hstp)₂(bpp)₂(H₂O)₄] (1) and[Mn₃(stp)₂(tpy)₃(H₂O)](H₂O)₅ (2) (bpp=benz-2,3-pyrimidine-[2,3-f]-1,10-phenanthroline, tpy=2,2':6',2"-terpyridine). X-ray diffraction structural analyses of two complexes reveal their structural diversity (0D and 1D) due to the difference of auxiliary ligands. 1 is a discrete structure, in which the Mn(Ⅱ) ion is hexa-coordinated with one stp, one bpp ligand and two water molecules. Complex 2 is a one-dimensional (1D) chain-like structure with three crystallographically independent Mn(Ⅱ) ions. The photoluminescent properties could be assigned to the π-π^* transition of 2-sulfoterephthalate ligands.
- solvothermal reaction,
- structural diversity,
- photoluminescent property
1. [1]
  Cui, Y. J.; Yue, Y. F.; Qian, G. D.; Chen, B. L. Luminescent functional metal-organic frameworks. Chem. Rev. 2012, 112, 1126-1162.
2. [2]
  (2) Gustafsson, M.; Bartoszewicz, A.; Martin-Matute, B.; Sun, J. L.; Grins, J.; Zhao, T.; Li, Z. Y.; Zhu, G. S.; Zou, X. D. A family of highly stable lanthanide metal-organic frameworks:structural evolution and catalytic activity. Chem. Mater. 2010, 22, 3316-3322.
3. [3]
  (3) Zhao, X. Q.; Cui, P.; Zhao, B.; Shi, W.; Cheng, P. Investigation on structures, luminescent and magnetic properties of Ln^Ⅲ-M (M=Fe^Ⅱ HS, Co^Ⅱ) coordination polymers. Dalton Trans. 2011, 40, 805-819.
4. [4]
  (4) Zeng, M. H.; Tan, Y. X.; He, Y. P.; Yin, Z.; Chen, Q.; Kurmoo, M. A porous 4-fold-interpenetrated chiral framework exhibiting vapochromism, single-crystal-to-single-crystal solvent exchange, gas sorption, and a poisoning effect. Inorg. Chem. 2013, 52, 2353-2360.
5. [5]
  (5) (a) Li, C. P.; Chen, J.; Du, M. Structural diversification and metal-directed assembly of coordination architectures based on tetrabromoterephthalic acid and a bent dipyridyl tecton 2,5-bis(4-pyridyl)-1,3,4-oxadiazole. CrystEngComm. 2010, 12, 4392-4402.
6. [6]
  (b) Zhang, M. L.; Li, D. S.; Wang, J. J. Structural diversity and properties of Zn^Ⅱ and Cd^Ⅱ complexes with a flexible dicarboxylate building block 1,3-phenylenediacetate and various heterocyclic Co-ligands. Dalton Trans. 2009, 38, 5355-5364.
7. [7]
  (6) He, Y. P.; Tan, Y. X.; Zhang, J. Stable Mg-metal-organic framework (MOF) and unstable Zn-MOF based on nanosized tris((4-carboxyl)phenylduryl)amine ligand. Cryst. Growth Des. 2013, 13, 6-9.
8. [8]
  (7) Zheng, B.; Zhang, D. J.; Peng, Y. Syntheses, structures and luminescence properties of two novel lanthanide metal-organic frameworks based on a rigid tetracarboxylate ligand. Inorg. Chem. Commun. 2012, 16, 70-73.
9. [9]
  (8) (a) Yaghi, O. M.; O'Keeffe, M.; Ockwlg, N. W.; Chae, H. K.; Eddaoudi, M.; Kim, J. Reticular synthesis and the design of new materials. Nature 2003, 423, 705-714.
10. [10]
  (b) Ren, Y. W.; Liang, J. X.; Lu, J. X.; Cai, B. W.; Shi, D. B.; Qi, C. R.; Jiang, H. F.; Chen, J.; Zheng, D. 1,4-Phenylenediacetate-based Ln MOFs-synthesis, structures, luminescence, and catalytic activity. Eur. J. Inorg. Chem. 2011, 4369-4376.
11. [11]
  (9) Ren, Y. X.; Zheng, X. J.; Li, L. C.; Yuan, D. Q.; An, M.; Jin, L. P. 3D frameworks based on dodecanuclear Dy-hydroxo wheel-cluster with slow relaxation of magnetization. Inorg. Chem. 2014, 53, 12234-12236.
12. [12]
  (10) (a) Ren, Y. X.; Ma, H. Y.; Fu, F.; Zhang, Z. L.; Zhang. Y. R. Crystal structures and luminescent properties of two lanthanide(Ⅲ) complexes featuring double-stranded helical chains of based on 2-sulfoterephthalate. J. Inorg. Organomet. Polym. 2013, 23, 646-651.
13. [13]
  (b) Ren, Y. X.; Hao, T. T.; Zhang, M. L.; Wang, D. J.; Yu, H.; Wang, Y. Crystal structures and electrochemical properties of two Mn(Ⅱ) 2-sulfoterephthalate complexes with N-donor ligands. Russ. J. Coor. Chem. 2014, 40, 154-159.
14. [14]
  (11) Sheldrick, G. M. SADABS, A Program for Empirical Absorption Correction of Area detector Data. University of Göttingen, Germany 1997.
15. [15]
  (12) Sheldrick, G. M. SHELXS-97, Program for Crystal Structure Solution. University of Göttingen, Germany 1997.
16. [16]
  (13) Sheldrick, G. M. SHELXL-97, Program for Crystal Structure Refinement. University of Göttingen, Germany 1997.
17. [17]
  (14) Ren, Y. X.; Zheng, X. J.; Jin, L. P. Structural analyses and luminescent properties of a series of lead(Ⅱ) metal-organic frameworks based on 2-sulfoterephthalate. CrystEngComm. 2011, 13, 5915-5923.
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