Citation: KULAI Ihor, MALLET-LADEIRA Sonia, KOVTUNENKO Volodymyr, VOITENKO Zoia. One-pot Synthesis and X-ray Structure Determination of 7-(Diethylamino)-3-(4-aminophenyl)coumarin[J]. Chinese Journal of Structural Chemistry, ;2015, 34(12): 1841-1844. doi: 10.14102/j.cnki.0254-5861.2011-0842 shu

One-pot Synthesis and X-ray Structure Determination of 7-(Diethylamino)-3-(4-aminophenyl)coumarin

a.
a. IMRCP, CNRS UMR 5623, University of Toulouse, 118, Route de Narbonne 31062 Toulouse, France;
b.
b. Department of Chemistry, Taras Shevchenko National University of Kyiv, 12, Lva Tolstogo Street 01033 Kyiv, Ukraine;
c.
c. ICT, FR CNRS 2599, University of Toulouse, 118, Route de Narbonne 31062 Toulouse, France

Corresponding author: KULAI Ihor,
Received Date: 10 June 2015
Available Online: 21 August 2015
Fund Project: culaire" (GDRI) (GDRI)

7-(Diethylamino)-3-(4-aminophenyl)coumarin has been synthesized in a new one-pot synthesis by a three-step process starting from 4-(diethylamino)salicylaldehyde and 4-nitrophenylacetonitrile. The product was obtained in a good yield with a high degree of purity and characterized by NMR, IR and HR-MS. The orange crystals of the title compound were grown from ethyl acetate solution. The solid state structure was established by X-ray crystallography analysis. The crystal belongs to the orthorombic system, space group Pccn with a=11.1095(5), b=33.0187(15), c=17.2865(7) Å, V=6341.1(5) Å³, C₁₉H₂₀N₂O₂, M_r=308.37, ρ_calc=1.292 g·cm^-3, μ=0.085 mm^-1, F(000)=2624, the final R=0.0480 and wR=0.1265 (I>2σ(I)).
- coumarin,
- dye,
- crystal structure,
- fluorescence,
- one-pot synthesis
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