Citation: WU Jia-Mei, WANG Qi, ZENG Li, CHEN Yun, LIU Ping, YI Hai-Bo. Synthesis, Structure and Polymorphism of a Novel Two-dimensional Cobalt(II) Coordination Polymer Constructed from Citrazinate Ligand[J]. Chinese Journal of Structural Chemistry, ;2016, 35(1): 93-99. doi: 10.14102/j.cnki.0254-5861.2011-0809 shu

Synthesis, Structure and Polymorphism of a Novel Two-dimensional Cobalt(II) Coordination Polymer Constructed from Citrazinate Ligand

WU Jia-Mei ^a ,
WANG Qi ^a ,
ZENG Li ^a ,
CHEN Yun ^a ,
LIU Ping ^b ,
YI Hai-Bo ^a

1.
a State Key Laboratory of Chemo/biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China;
2.
b Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Received Date: 11 May 2015
Available Online: 12 December 2015
Fund Project:

The polymeric Co(II) complex [Co(Hdhpc)(py)]_n (1) (py = pyridine, H₃dhpc = 2,6-dihydroxypyridine-4-carboxyl acid) was prepared and characterized. X-ray diffraction data revealed that the compound crystallizes in dimorphic 1α and 1β forms at room and low temperature, respectively. The former crystallizes in the orthorhombic crystal system, space group Pbcm with a = 7.209(1), b = 14.834(3), c = 15.376(3) Å, V = 1644.3(5) Å³, Z = 4, C₁₆H₁₃CoN₃O₄, M_r = 370.22, D_c = 1.496 g/cm³, F(000) = 756, μ = 1.068 mm^-1, R = 0.0633 and wR = 0.1192. While 1β is attributed to the monoclinic space group C2/c with a = 32.102(4), b = 7.022, c = 14.945(2) Å, β = 109.052(5)°, V = 3184.4(6) Å³, Z = 8, D_c = 1.544 g/cm³, F(000) = 1512, μ = 1.103 mm^-1, R = 0.0428 and wR = 0.0797. The conformation changes of pyridines between Co-citrazinate planes leading to a reversible single-crystal to single-crystal transformation. The variable temperature magnetic data indicate a weak ferrimagnetism.
- cobalt(II) complex,
- citrazinic acid,
- single-crystal to single-crystal transformation,
- π-π interaction,
- magnetic property
1. [1]
  (1) Hutchins, K. M.; Rupasinghe, T. P.; Ditzler, L. R.; Swenson, D. C.; Sander, J. R. G.; Baltrusaitis, J.; Tivanski, A. V.; MacGillivray, L. R. Nanocrystals of a metal-organic complex exhibit remarkably high conductivity that increases in a single-crystal-to-single-crystal transformation. J. Am. Chem. Soc. 2014, 19, 6778-6781.
2. [2]
  (2) He, Y. C.; Yang, J.; Liu, Y. Y.; Ma, J. F. Series of solvent-induced single-crystal to single-crystal transformations with different sizes of solvent molecules. Inorg. Chem. 2014, 14, 7527-7533.
3. [3]
  (3) Yang, J.; Wang, X.; Dai, F.; Zhang, L.; Wang, R.; Sun, D. Improving the porosity and catalytic capacity of a zinc paddlewheel metal-organic framework (MOF) through metal-ion metathesis in a single-crystal-to-single-crystal fashion. Inorg. Chem. 2014, 19, 10649-10653.
4. [4]
  (4) Liu, G.; Liu, J.; Liu, Y.; Tao, X. Oriented single-crystal-to-single-crystal phase transition with dramatic changes in the dimensions of crystals. J. Am. Chem. Soc. 2014, 2, 590-593.
5. [5]
  (5) Sarma, D.; Natarajan, S. Usefulness of in situ single crystal to single crystal transformation (SCSC) studies in understanding the temperature-dependent dimensionality cross-over and structural reorganization in copper-containing metal-organic frameworks (MOFs). Cryst. Growth Des. 2011, 12, 5415-5423.
6. [6]
  (6) Khorasani, S.; Fernandes, M. A. Cooperativity and feedback mechanisms in the single-crystal-to-single-crystal solid-state diels-alder reaction of 9-methylanthracene with bis(N-cyclobutylimino)-1,4-dithiin. Cryst. Growth Des. 2013, 12, 5499-5505.
7. [7]
  (7) Park, I. H.; Medishetty, R.; Kim, J. Y.; Lee, S. S.; Vittal, J. J. Distortional supramolecular isomers of polyrotaxane coordination polymers: photoreactivity and sensing of nitro compounds. Angew. Chem. Int. Ed. 2014, 22, 5591-5595.
8. [8]
  (8) Wang, C.; Li, L.; Bell, J. G.; Lv, X.; Tang, S.; Zhao, X.; Thomas, K. M. Hysteretic gas and vapor sorption in flexible interpenetrated lanthanide-based metal-organic frameworks with coordinated molecular gating via reversible single-crystal-to-single-crystal transformation for enhanced selectivity. Chem. Mater. 2015, 5, 1502-1516.
9. [9]
  (9) Zeng, M. H.; Tan, Y. X.; He, Y. P.; Yin, Z.; Chen, Q.; Kurmoo, M. A porous 4-fold-interpenetrated chiral framework exhibiting vapochromism, single-crystal-to-single-crystal solvent exchange, gas sorption, and a poisoning effect. Inorg. Chem. 2013, 5, 2353-2360.
10. [10]
  (10) Costa, J. S.; Rodríguez-Jiménez, S.; Craig, G. A.; Barth, B.; Beavers, C. M.; Teat, S. J.; Aromí, G. Three-way crystal-to-crystal reversible transformation and controlled spin switching by a nonporous molecular material. J. Am. Chem. Soc. 2014, 10, 3869-3874.
11. [11]
  (11) Ban, Y.; Li, Y.; Peng, Y.; Jin, H.; Jiao, W.; Liu, X.; Yang, W. Metal-substituted zeolitic imidazolate framework ZIF-108: gas-sorption and membrane-separation properties. Chem. Eur. J. 2014, 36, 11402-11409.
12. [12]
  (12) Dong, X. Y.; Li, B.; Ma, B. B.; Li, S. J.; Dong, M. M.; Zhu, Y. Y.; Zang, S. Q.; Song, Y.; Hou, H. W.; Mak, T. C. W. Ferroelectric switchable behavior through fast reversible de/adsorption of water spirals in a chiral 3D metal-organic framework. J. Am. Chem. Soc. 2013, 28, 10214-10217.
13. [13]
  (13) Williams, U. J.; Mahoney, B. D.; Lewis, A. J.; DeGregorio, P. T.; Carroll, P. J.; Schelter, E. J. Single crystal to single crystal transformation and hydrogen-atom transfer upon oxidation of a cerium coordination compound. Inorg. Chem. 2013, 8, 4142-4144.
14. [14]
  (14) Wei, B.; Shang, R.; Zhang, X.; Shao, X. D.; Yao, Y. F.; Wang, Z. M.; Xiong, R. G.; Zhang, W. Uniaxial movements of a metal-cyanide framework switched by weak interactions through dehydration and rehydration. Chem. Eur. J. 2014, 27, 8269-8273.
15. [15]
  (15) Ma, J. P.; Dong, Y. B.; Huang, R. Q.; Smith, M. D.; Su, C. Y. Spontaneously resolved chiral three-fold interpenetrating diamondoidlike Cu(II) coordination polymers with temperature-driven crystal-to-crystal transformation. Inorg. Chem. 2005, 18, 6143-6145.
16. [16]
  (16) Livage, C.; Guillou, N.; Marrot, J.; Férey, G. Construction of two- and three-dimensional coordination polymers from cobalt trimesate. Chem. Mater. 2001, 11, 4387-4392.
17. [17]
  (17) Pan, F.; Wang, T. C. Improved synthesis of citrazinic acid. Natl. Defense Med. Center. 1957, 8-11.
18. [18]
  (18) Sheldrick, G. M. SHELXS-97, Program for the Solution of Crystal Structures. University of Göttingen, Germany 1997.
19. [19]
  (19) Li, B.; Fan, L. M.; Sun, Z.; Zhang, W.; Wei, P. H. Synthesis, crystal structure and property of a series of supramolecular polymers based on novel 3,5-dimethyl- 2,6-bis(3-(pyrid-2-yl)-1,2,4-triazolyl)pyridine ligand. Chin. J. Struct. Chem. 2012, 12, 1829-1836.
20. [20]
  (20) Chen, W. T.; Huang, J. G.; Luo, Q. Y.; Xu, Y. P.; Fu, H. R. A novel terbium-cobalt tetra(4-sulfonatophenyl)porphyrin: synthesis, structure and photophysical and electrochemical properties. J. Porphyr. Phthalocya. 2015, 01-03, 154-159.
21. [21]
  (21) Peng, C. S.; Tokmakoff, A. Identification of lactam-lactim tautomers of aromatic heterocycles in aqueous solution using 2D IR spectroscopy. J. Phys. Chem. Lett. 2012, 22, 3302-3306.
22. [22]
  (22) Atria, A. M.; Garland, M. T.; Baggio, R. A dense hydrogen-bonding network and an unusually large packing index in triaquatris(2,4-dioxo-1,2,3,4-tetrahydropyrimidine-5-carboxylato)neodymium(III) trihydrate. Acta Cryst. 2013, C69, 1378-1382.
23. [23]
  (23) Fang, S. M.; Sañudo, E. C.; Hu, M.; Zhang, Q.; Ma, S. T.; Jia, L. R.; Wang, C.; Tang, J. Y.; Du, M.; Liu, C. S. Hydrothermal syntheses, crystal structures, and magnetic properties of a series of unique three-dimensional lanthanide-organic coordination frameworks with a N-protonated 2,6-dihydroxypyridine-4-carboxylate tecton. Cryst. Growth Des. 2011, 3, 811-8.
24. [24]
  (24) Parkin, S. R.; Behrman, E. J. Channel-forming solvates of 6-chloro-2,5-dihydroxypyridine and its solvent-free tautomer 6-chloro-5-hydroxy-2-pyridone. Acta Cryst. 2009, C65, o529-o533.
25. [25]
  (25) Rutledge, L. R.; Churchill, C. D. M.; Wetmore, S. D. A preliminary investigation of the additivity of π-π or π⁺-π stacking and T-shaped interactions between natural or damaged DNA nucleobases and histidine. J. Phys. Chem. B 2010, 9, 3355-3367.
26. [26]
  (26) Singh, N. J.; Min, S. K.; Kim, D. Y.; Kim, K. S. Comprehensive energy analysis for various types of π-interaction. J. Chem. Theory Comput. 2009, 3, 515-529.
27. [27]
  (27) Montney, M. R.; Supkowski, R. M.; Staples, R. J.; LaDuca, R. L. Synthesis, crystal structure, and magnetic properties of two-dimensional divalent metal glutarate/dipyridylamine coordination polymers, with a single crystal-to-single crystal transformation in the copper. J. Solid State Chem. 2009, 1, 8-17.
28. [28]
  (28) Cheng, X. N.; Zhang, W. X.; Chen, X. M. Single crystal-to-single crystal transformation from ferromagnetic discrete molecules to a spin-canting antiferromagnetic layer. J. Am. Chem. Soc. 2007, 51, 15738-15739.
29. [29]
  (29) Wang, T. W.; Liu, D. S.; Huang, C. C.; Sui, Y.; Huang, X. H.; Chen, J. Z.; You, X. Z. Syntheses, crystal structures, and magnetic properties of two Mn(II) coordination polymers based on the 5-aminotetrazole ligand: effect of sources of ligand on construction of topological networks. Cryst. Growth Des. 2010, 8, 3429-3435.
30. [30]
  (30) Cao, D. K.; Liu, M. J.; Huang, J.; Bao, S. S.; Zheng, L. M. Cobalt and manganese diphosphonates with one-, two-, and three-dimensional structures and field-induced magnetic transitions. Inorg. Chem. 2011, 6, 2278-2287.
31. [31]
  (31) Cariati, E.; Ugo, R.; Santoro, G.; Tordin, E.; Sorace, L.; Caneschi, A.; Sironi, A.; Macchi, P.; Casati, N. Slow relaxation of the magnetization in non-linear optical active layered mixed metal oxalate chains. Inorg. Chem. 2010, 23, 10894-10901.
1. [1]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
2. [2]
  Yinling HOU , Jia JI , Hong YU , Xiaoyun BIAN , Xiaofen GUAN , Jing QIU , Shuyi REN , Ming FANG . A rhombic Dy₄-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251
3. [3]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
4. [4]
  Shenhao QIU , Qingquan XIAO , Huazhu TANG , Quan XIE . First-principles study on electronic structure, optical and magnetic properties of rare earth elements X (X=Sc, Y, La, Ce, Eu) doped with two-dimensional GaSe. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2250-2258. doi: 10.11862/CJIC.20240104
5. [5]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542
6. [6]
  Zhaodong WANG . In situ synthesis, crystal structure, and magnetic characterization of a trinuclear copper complex based on a multi-substituted imidazo[1,5-a]pyrazine scaffold. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 597-604. doi: 10.11862/CJIC.20240268
7. [7]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
8. [8]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
9. [9]
  Zhijia Zhang , Shihao Sun , Yuefang Chen , Yanhao Wei , Mengmeng Zhang , Chunsheng Li , Yan Sun , Shaofei Zhang , Yong Jiang . Epitaxial growth of Cu_2-xSe on Cu (220) crystal plane as high property anode for sodium storage. Chinese Chemical Letters, 2024, 35(7): 108922-. doi: 10.1016/j.cclet.2023.108922
10. [10]
  Zhibin Ren , Shan Li , Xiaoying Liu , Guanghao Lv , Lei Chen , Jingli Wang , Xingyi Li , Jiaqing Wang . Penetrating efficiency of supramolecular hydrogel eye drops: Electrostatic interaction surpasses ligand-receptor interaction. Chinese Chemical Letters, 2024, 35(11): 109629-. doi: 10.1016/j.cclet.2024.109629
11. [11]
  Cheng Wang , Ji Wang , Dong Liu , Zhi-Ling Zhang . Advances in virus-host interaction research based on microfluidic platforms. Chinese Chemical Letters, 2024, 35(12): 110302-. doi: 10.1016/j.cclet.2024.110302
12. [12]
  Fengyu Zhang , Yali Liang , Zhangran Ye , Lei Deng , Yunna Guo , Ping Qiu , Peng Jia , Qiaobao Zhang , Liqiang Zhang . Enhanced electrochemical performance of nanoscale single crystal NMC811 modification by coating LiNbO₃. Chinese Chemical Letters, 2024, 35(5): 108655-. doi: 10.1016/j.cclet.2023.108655
13. [13]
  Min Chen , Boyu Peng , Xuyun Guo , Ye Zhu , Hanying Li . Polyethylene interfacial dielectric layer for organic semiconductor single crystal based field-effect transistors. Chinese Chemical Letters, 2024, 35(4): 109051-. doi: 10.1016/j.cclet.2023.109051
14. [14]
  Zhenfei Tang , Yunwu Zhang , Zhiyuan Yang , Haifeng Yuan , Tong Wu , Yue Li , Guixiang Zhang , Xingzhi Wang , Bin Chang , Dehui Sun , Hong Liu , Lili Zhao , Weijia Zhou . Iron-doping regulated light absorption and active sites in LiTaO₃ single crystal for photocatalytic nitrogen reduction. Chinese Chemical Letters, 2025, 36(3): 110107-. doi: 10.1016/j.cclet.2024.110107
15. [15]
  Jun-Jie Fang , Yun-Peng Xie , Xing Lu . Organooxotin and cobalt/manganese heterometallic nanoclusters exhibiting single-molecule magnetism. Chinese Journal of Structural Chemistry, 2025, 44(4): 100515-100515. doi: 10.1016/j.cjsc.2025.100515
16. [16]
  Zhao-Bo Hu , Ling-Ao Gui , Long-He Li , Tong-Tong Xiao , Adam T. Hand , Pagnareach Tin , Mykhaylo Ozerov , Yan Peng , Zhongwen Ouyang , Zhenxing Wang , Zi-Ling Xue , You Song . Co^Ⅱ single-ion magnet and its multi-dimensional aggregations: Influence of the structural rigidity on magnetic relaxation process. Chinese Chemical Letters, 2025, 36(2): 109600-. doi: 10.1016/j.cclet.2024.109600
17. [17]
  Wenli Xu , Yingzhao Zhang , Rui Wang , Chenyang Liu , Jialin Liu , Xiangyu Huo , Xinying Liu , He Zhang , Jianxu Ding . In-situ passivating surface defects of ultra-thin MAPbBr3 perovskite single crystal films for high performance photodetectors. Chinese Journal of Structural Chemistry, 2025, 44(1): 100454-100454. doi: 10.1016/j.cjsc.2024.100454
18. [18]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
19. [19]
  Yuanjin Chen , Xianghui Shi , Dajiang Huang , Junnian Wei , Zhenfeng Xi . Synthesis and reactivity of cobalt dinitrogen complex supported by nonsymmetrical pincer ligand. Chinese Chemical Letters, 2024, 35(7): 109292-. doi: 10.1016/j.cclet.2023.109292
20. [20]
  Minghui Zhang , Na Zhang , Qian Zhao , Chao Wang , Alexander Steiner , Jianliang Xiao , Weijun Tang . Cobalt pincer complex-catalyzed highly enantioselective hydrogenation of quinoxalines. Chinese Chemical Letters, 2025, 36(4): 110081-. doi: 10.1016/j.cclet.2024.110081

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(781)
HTML views(25)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142