Citation: YAO Hua-Gang, LU Xiu-Xia, ZHENG Jia-Xin, XIAO Yong-Le, LIN Huan-Jie, CAI Wei-Yi. Syntheses, Structures and Properties of Two New Coordination Polymers with Flexible Ligands as Linkers[J]. Chinese Journal of Structural Chemistry, ;2016, 35(1): 107-113. doi: 10.14102/j.cnki.0254-5861.2011-0806 shu

Syntheses, Structures and Properties of Two New Coordination Polymers with Flexible Ligands as Linkers

1.
School of Chemistry and Chemical Engineering, Guangdong Pharmaceutical University, Zhongshan 528458, China

Corresponding author: YAO Hua-Gang,
Received Date: 11 May 2015
Available Online: 12 August 2015
Fund Project: Supported by the National Natural Science Foundation of China (No. 21301035) (No. 21301035)

Two new coordination polymers, [ZnL1]_n(1, H₂L1 = 5-(4-pyridyl)-methoxyl iso- phthalic acid) and [Ni(L2)₂(H₂O)₄]_n(2, HL2 = 4-(pyridin-4-ylmethoxy)benzolic acid), have been synthesized and characterized by elemental analysis, PXRD, IR spectra, and single-crystal X-ray diffraction. Compound 1 has a three-dimensional framework constructed by 6-bridged L1^2- anions connecting the Zn₂(O₂C)₄ paddlewheel-like units. Compound 2 contains a mononuclear molecular unit, and the central nickel atom adopts a slightly distorted octahedral geometry by two nitrogen atoms from different L2^- ligands and four oxygen atoms from water molecules. These molecular units link each other via four types of O-H…O hydrogen bonds to form an extended three-dimen- sional (3D) supramolecular network. The thermal and photoluminescent properties of 1 and 2 have also been investigated.
- Zn(Ⅱ) coordination polymer,
- paddlewheel unit,
- flexible ligand,
- hydrogen interaction
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沈阳化工大学材料科学与工程学院沈阳 110142