Citation: YANG Yan-Yan, QU Xiao-Shua, WANG Xin-Long, ZHANG Miao-Miao, LIU Shu-Ping. Syntheses, Structures and Electrochemical Investigation of a New Dawson-based Hybrid Material with Cd-BTA Coordination Polymers[J]. Chinese Journal of Structural Chemistry, ;2015, 34(12): 1889-1894. doi: 10.14102/j.cnki.0254-5861.2011-0773 shu

Syntheses, Structures and Electrochemical Investigation of a New Dawson-based Hybrid Material with Cd-BTA Coordination Polymers

a.
a. Jilin Institute of Chemical Technology, Jilin, Jilin 132022, China;
b.
b. Department of Functional Material Chemistry, Key Lab of Polyoxometalate Science of Ministry of Education, Changchun, 130024, China;
c.
c. College of Tourism and Cusine, Harbin University of Commerce, Harbin 150076, China

Received Date: 22 April 2015
Available Online: 13 July 2015
Fund Project:

A new organic-inorganic hybrid based on tungstophosphate anions and benzotriazole cations, [Na(BTA)₂(H₂O)₂]₂[{Cd(BTA)₄(H₂O)}₂(P₂W₁₈O₆₂)]·6H₂O (1) (BTA=benzotriazole) has been synthesized in aqueous solution and characterized by elemental analysis, IR spectroscopy, thermal gravimetric analysis, and single-crystal X-ray diffraction. X-ray analysis showed that both {Na(BTA)₂} and {Cd(BTA)₄} units are supported on the α-Dawson polyoxoanion [P₂W₁₈O₆₂]^6- via the surface bridging oxygen atoms. The electrochemical properties of 1 in aqueous solution are studied at room temperature. It was found that 1 presents good electrocatalytic activities for the reduction of NO₂^-.
- polyoxometalates,
- inorganic-organic hybrid material,
- tungstophosphate
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