Citation: SUN Jie, WANG Ai-Yun, LI Qing, ZHOU Ju-Hua. Synthesis, Structure and Luminescence of a ZnII Complex Derived from 1,2-Benzenedicarboxylic Acid Ligand[J]. Chinese Journal of Structural Chemistry, ;2016, 34(10): 1533-1538. doi: 10.14102/j.cnki.0254-5861.2011-0761 shu

Synthesis, Structure and Luminescence of a ZnII Complex Derived from 1,2-Benzenedicarboxylic Acid Ligand

1.
School of Life Science, Ludong University, Yantai 264025, Shandong, China

Received Date: 10 April 2015
Available Online: 17 August 2015
Fund Project:

The reaction of 1,2-benzenedicarboxylic acid (H₂L) with Zn(NO)₃·6H₂O and selfdesigned 1,2-bis(imidazol-1-ylmethyl)-benzene) (2-bimb) in DMA/H₂O results in the formating of double chains Zn^II complex, {[Zn_2.5(L)₂(bimb)(H₂O)]·H₂O}_n (1), which has been characterized by TGA, PXRD and single-crystal X-ray diffraction. Compound 1 crystalizes in monoclinic, space group P1 with a=11.4030(3), b=11.9722(3), c=13.5702(4) Å, α=89.903(3), β=80.692(2), γ=63.999(3)°, C₆₄H₅₆N₈O₂₀Zn₅, M_r=1584.01, V=1638.15(9) Å³, Z=1, D_c=1.606 g·cm^-3, μ=1.885 mm^-1, F(000)=806.0, 2.07< θ< 25°, λ(MoKα)=0.71073 Å, T=293(2) K, the final R=0.0439, wR=0.01393 and S=1.057. X-ray diffraction analysis reveals that complex 1 possesses a 2D double-chain structure. In addition, the solid state luminescent property of complex 1, H₂L, and 2-bimb at room temperature are also investigated.
- zinc complex,
- crystal structure,
- chain,
- luminescence
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