Citation: SUN Yu, ZHOU Ling-Yun, TANG Lin, ZHANG Jian-Yong. Synthesis, Crystal Structure and Luminescence of One Cd^II Coordination Polymer with Bifunctional Zwitterionic Ligand[J]. Chinese Journal of Structural Chemistry, ;2016, 34(10): 1539-1545. doi: 10.14102/j.cnki.0254-5861.2011-0760 shu

Synthesis, Crystal Structure and Luminescence of One Cd^II Coordination Polymer with Bifunctional Zwitterionic Ligand

SUN Yu ^a,, ,
ZHOU Ling-Yun ^a ,
TANG Lin ^a ,
ZHANG Jian-Yong ^b,,

1.
a School of Pharmacy, Wannan Medical College, Wuhu 241002, China;
2.
b Shanghai Institute of Technology, Shanghai 200235, China

Corresponding author: SUN Yu, ZHANG Jian-Yong,
Received Date: 9 April 2015
Available Online: 29 June 2015
Fund Project: Partly supported by the Key Research Foundation of Wannan Medical College (WK2014Z06) (WK2014Z06)Doctoral Starting up Foundation of Wannan Medical College (201219) (201219)

One coordination polymer with bifunctional zwitterionic ligand bearing both carboxylate and tetrazolate groups, [Cd(L¹)(N₃)]_n·nH₂O (1, L¹=1-(carboxylatomethyl)-4-(5-tetrazolato)pyridinium], has been in situ hydrothermally synthesized and structurally characterized. Compound 1 crystallizes in monoclinic with C2/m space group, a=21.8038(17), b=7.6087(6), c=7.8342(6) Å, β=106.166(2)°, V=1248.29(17) Å³, Z=4, M_r=376.62, D_c=2.004 g·cm^-3, F(000)=736, μ=1.772 mm^-1, R_int=0.0217, S=1.088, the final R=0.0415 and wR=0.1128 for 1020 observed reflections with I>2σ(I). The compound exhibits two-dimensional coordination sheets, in which infinite anionic [Cd(CN₄)(N₃)(OCO)]_n chains with the tricomponent (μ-azide)(μ-tetrazolate)(μ-carboxylate) bridges are cross-linked by cationic 1-methylenepyridinium spacers of the L¹ ligand. This compound in the solid state exhibits blue luminescence assignable to intraligand transitions.
- zwitterionic ligand,
- coordination polymers,
- carboxylate,
- tetrazolate,
- luminescence;
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