Citation: ZHANG Hui, CHEN Jin-Huan, YIN Zhen-Ming. Cu(Ⅱ) and Ni(Ⅱ) Complexes with 5,5'-Bis(2-acylphenyl)diazo-dipyrromethane: Syntheses, Structures and Properties[J]. Chinese Journal of Structural Chemistry, ;2015, 34(12): 1876-1882. doi: 10.14102/j.cnki.0254-5861.2011-0749 shu

Cu(Ⅱ) and Ni(Ⅱ) Complexes with 5,5'-Bis(2-acylphenyl)diazo-dipyrromethane: Syntheses, Structures and Properties

1.
College of Chemistry, Tianjin Key Laboratory of Structure and Performance for Functional Molecule, Tianjin Normal University, Tianjin 300387, China (Key Laboratory of Inorganic-organic Hybrid Functional Material Chemistry (Tianjin Normal University, Ministry of Education, Tianjin Normal University, Tianjin 300387, China

Corresponding author: YIN Zhen-Ming,
Received Date: 12 April 2015
Available Online: 20 September 2015
Fund Project: The program was supported by the National Natural Science Foundation of China (NSFC No. 21172174) (NSFC No. 21172174)

The reactions of 5,5'-bis(2-acylphenyl)diazo-dipyrromethane (H₂L) with CuSO₄ and NiCl₂ resulted in the formation of corresponding mononuclear coordination complexes 2 (CuL) and 3 (NiL). The crystal of complex 2 is of monoclinic system, space group P2₁ with a=10.040(5), b=11.900(5), c=11.170(5) Å, β=93.057(8)°, V=1332.8(2) Å³, Z=2, C₂₉H₂₈N₆O₂Cu, M_r=556.11, D_c=1.386 g/cm, F(000)=578 and μ(MoKα)=0.857 mm^-1. The crystal of complex 3 belongs to the monoclinic system, space group P2₁/n with a=12.0445(6), b=17.2101(8), c=16.3304(6) Å, β=128.407(2)°, V=2654.6(2) Å³, Z=4, C₂₉H₂₈N₆O₂Ni, M_r=551.28, D_c=1.380 g/cm, F(000)=1152 and μ(MoKα)=0.770 mm^-1. In both complexes, the metal ions are in square-planar geometry by coordinating to two azo N atoms and two deprotonated pyrrole N atoms. Intramolecular Cu…O=C in complex 2 and intermolecular Ni…O=C in complex 3 were found. The UV-Vis spectra and thermal stability of complexes 2 and 3 were also studied.
- 5,5'-bis(2-acylphenyl)diazo-dipyrromethane,
- metal complexes,
- structures,
- properties
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