Citation: TANG Pei-Qin, HAO Lu-Jiang, FAN Li-Ming, LIU Xin-Zheng, LI Bin, ZHANG Xiu-Tang. Synthesis, Crystal Structure, and Magnetic Property of One 3D Nickel Coordination Polymer Based on 2-Hydroxy-5-(3',5'-terephthalic acid) Pyridine and 1,4-Bis(1-imdazoly)benzene[J]. Chinese Journal of Structural Chemistry, ;2016, 34(10): 1519-1524. doi: 10.14102/j.cnki.0254-5861.2011-0746 shu

Synthesis, Crystal Structure, and Magnetic Property of One 3D Nickel Coordination Polymer Based on 2-Hydroxy-5-(3',5'-terephthalic acid) Pyridine and 1,4-Bis(1-imdazoly)benzene

1.
a Advanced Material Institute of Research, College of Chemistry and Chemical Engineering, Qilu Normal University, Jinan 250013, China;
2.
b State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China;
3.
c College of Biological Engineering, Qilu University of Technology, Jinan 250353, China

Received Date: 1 April 2015
Available Online: 18 May 2015
Fund Project: National Natural Science Foundation of China (21451001) (ZR2011BL020, ZR2012CM019) and Key Discipline and Innovation Team of Qilu Normal University (21451001)

One novel nickel coordination polymer, {[Ni(OTP)(bib)_1.5(H₂O)]·2H₂O}_n (1, H₂OTP=2-hydroxy-5-(3',5'-terephthalic acid) pyridine, bib=1,4-bis(1-imdazoly)benzene), has been synthesized and characterized by elemental analysis (EA), IR, powder X-ray diffraction (PXRD), and thermogravimetric (TG) analyses. The crystal of 1 crystallizes in monoclinic, space group P2₁/n with a=12.2860(5), b=13.8246(6), c=19.0140(8) Å, β=104.3870(1)°, V=3128.2(2) Å³, Z=4, C₃₂H₂₈N₇NiO₈, M_r=697.32, D_c=1.481 g/cm³, F(000)=1444 and µ(MoKα)=0.684 mm^-1. The final R=0.0704 and wR=0.1764 for 5485 observed reflections with I>2σ(I) and R=0.1087 and wR=0.2010 for all data. Topology analysis reveals that complex 1 is a 3D 2-fold interpenetrated {4⁴·6⁶}-nov net based on the 1D [Ni(OTP)]_n chain and the 2D [Ni₂(bib)₃]_n sql sheet. And the variable-temperature magnetic susceptibility measurements exhibit weak antiferromagnetic coupling interaction.
- 2-hydroxy-5-(3',5'-terephthalic acid) pyridine,
- 1,4-bis(1-imdazoly)benzene,
- nickel,
- topology,
- magnetic property
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