Citation: GAO Sheng-Min, XU Zhi-Huang, YE Li-Wang, SU Gen-Bo, ZHUANG Xin-Xin. Synthesis, Crystal Structure and Properties of a Coordination Compound: Ni(C₆H₁₂N₄)₂SO₄·4H₂O[J]. Chinese Journal of Structural Chemistry, ;2015, 34(11): 1682-1688. doi: 10.14102/j.cnki.0254-5861.2011-0723 shu

Synthesis, Crystal Structure and Properties of a Coordination Compound: Ni(C₆H₁₂N₄)₂SO₄·4H₂O

a.
a. Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China;
b.
b. University of Chinese Academy of Science, Beijing 100049, China

Corresponding author: ZHUANG Xin-Xin,
Received Date: 16 March 2015
Available Online: 11 June 2015
Fund Project:

A new coordination compound, Ni(C₆H₁₂N₄)₂SO₄·4H₂O(NSH-HMTA) (HMTA, hexamethylenetetramine, C₆H₁₂N₄), has been synthesized and its single crystals were obtained. NSH-HMTA belongs to the triclinic system, space group P1 with a=9.2534(6), b=13.3131(2), c=16.0373(2) Å, α=65.981(6), β=89.792(3), γ=89.677(4)°, M_r=880.2, Z=2, V=1804.6(3) Å3, μ=1.254 mm^-1, F(000)=932, R=0.0555 (I>2σ(I)) and wR=0.1908 for 19343 observed reflections. HMTA substitutes for water molecules are located at the para-positions, forming a stretching octahedral nickel ion unit. Thermo-gravimetric analysis shows that the dehydration temperature of NSH-HMTA is about 92℃. The characteristic UV peaks are approximately 10 nm red-shifted by the absorption of octahedral HMTA complex ion units.
- crystal structure,
- UV light filter,
- heat-resisting,
- UV absorption
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