Citation: FAN Guang, LI Xiao-Bo, MA Zhan-Ying, DENG Ling-Juan, ZHANG Yin-Li, GUO Jin-Chan. Synthesis, Crystal Structure and Characterization of Energetic Monovalent Copper Azide Complex: [Cu₂(dmpz)(N₃)₂]_n[J]. Chinese Journal of Structural Chemistry, ;2016, 34(10): 1508-1512. doi: 10.14102/j.cnki.0254-5861.2011-0712 shu

Synthesis, Crystal Structure and Characterization of Energetic Monovalent Copper Azide Complex: [Cu₂(dmpz)(N₃)₂]_n

1.
College of Chemistry & Chemical Engineering, Xianyang Normal University,Xianyang, Shaanxi 712000, China

Corresponding author: FAN Guang,
Received Date: 16 March 2015
Available Online: 25 May 2015
Fund Project: Supported by the National Natural Science Foundation of China (No.21203160) (No.21203160) Education Department Foundation of Shaanxi Province (No.12JK0631) (No.12JK0631) Natural Science Foundation of Shaanxi Province (No.2013JM2013) (No.2013JM2013)

A novel cuprous azide complex with the formula of [Cu₂(dmpz)(N₃)₂]_n (1, dmpz: 2,6-dimethylpyrazine) has been synthesized through hydrothermal synthesis with the reducibility of H₃PO₃ and structurally characterized by single-crystal X-ray diffraction method. Single-crystal X-ray diffraction analysis reveals the title complex represents a three-dimensional network structure featuring 2D [CuN₃]_n plane units bridged by bridging dmpz ligands to form a 3D network. Research results reveal that 1 has lower impact sensitivity and friction sensitivity, which may be expected to become insensitive energetic material and have potential applications. Crystal data: monoclinic, space group C2/c, a=17.8599(15), b=8.2889(5), c=14.8076(14) Å, β=113.2580(10)°, V=2014.0(3) Å³, Z=8, S=1.025, the final R=0.0303, wR=0.0825 for 1460 observed reflections with I>2σ(I) and R=0.0386, wR=0.0870 for all reflections. In addition, elemental analysis, IR, and sensitivity characterization are presented.
- monovalent copper azide complex,
- crystal structure,
- energetic complex,
- hydrothermal synthesis,
- high-energy density materials
1. [1]
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