Citation: ZHAO Wei-Xing, WEN Pu-Hong, WANG Yan, JIANG Luan, FENG Guo-Dong, LI Zong-Xiao. Synthesis, Crystal Structure and Physical Properties of a Novel Cadmium(II) Supramolecular 3D Framework[J]. Chinese Journal of Structural Chemistry, ;2015, 34(5): 786-793. doi: 10.14102/j.cnki.0254-5861.2011-0576 shu

Synthesis, Crystal Structure and Physical Properties of a Novel Cadmium(II) Supramolecular 3D Framework

1.
College of Chemistry and Chemical Engineering, Baoji University of Arts and Sciences, Shaanxi 721013, China

Corresponding author: ZHAO Wei-Xing,
Received Date: 17 November 2014
Available Online: 11 February 2015
Fund Project: This work was supported by the Natural Science Foundation of China (No.21173003) (No.21173003) the Scientific Research Project (No.13JS007) from Shaanxi Key Laboratory of Phytochemistry and Key Research Project (No.ZK12016) from Baoji University of Arts and Sciences (No.13JS007)

A new inorganic-organic hybrid cadmium(II) complex [Cd₂(H_1/2C₄BIm)₂(CH₃COO)]_n has been prepared by a hydrothermal reaction, and characterized by fluorescence, IR, TGA, and single-crystal X-ray diffraction analysis. In its crystal structure, there are two kinds of coordinating forms for those Cd(II) ions. One is that the Cd(II) ion is coordinated by one carboxylate oxygen atom from one acetate oxygen ligand and three benzimidazole nitrogen atoms from three 2,2'-(1,4-butanediyl)bis (1H-benzimidazole) (H₂C₄BIm) ligands, and the other is that the Cd(II) ion is coordinated by four benzimidazole nitrogen atoms from four H₂C₄BIm ligands to furnish two distorted tetrahedral coordination geometries. It exhibits a beautiful structure for a 2D layer and a 3D network, with its four-connecting nodes provided by the H₂C₄BIm ligands. Furthermore, this complex shows intense luminescent property at room temperature. In [Cd₂(H₂C₂BIm)₂(C₉H₆O₄)₂]_n, the H₂C₂BIm ligand lost the role as a bridging ligand because of the shorter alkyl chain compared with that of H₂C₄BIm ligand.
- cadmium,
- hydrothermal synthesis,
- crystal structure,
- fluorescence
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