Citation: CHEN Wen-Tong, HU Rong-Hua, LUO Zhi-Gang, CHEN Hua-Long, LIU Juan. A New 3-D Lanthanide Porphyrin: Synthesis, Structure and Photophysical Properties[J]. Chinese Journal of Structural Chemistry, ;2015, 34(2): 279-284. doi: 10.14102/j.cnki.0254-5861.2011-0473 shu

A New 3-D Lanthanide Porphyrin: Synthesis, Structure and Photophysical Properties

a.
a. Institute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Ji'an, Jiangxi 343009, China;
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b. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: CHEN Wen-Tong,
Received Date: 7 August 2014
Available Online: 9 October 2014
Fund Project: We thank the financial support of NNSFC (21361013) (21361013) the NSF of Jiangxi Province (20132BAB203010) (20132BAB203010) the open foundation (No. 20130014) of the State Key Laboratory of Structural Chemistry, and the science and technology project of Jiangxi Provincial Department of Education (GJJ14554) (No. 20130014)

A new lanthanide porphyrin, [Sm^Ⅲ(H₃TPPS^Ⅲ)]_n·nH₂O (1, H₆TPPS=tetra(4-sulfonatophenyl)porphyrin), has been synthesized through a hydrothermal reaction and structurally characterized by single-crystal X-ray diffraction. Compound 1 crystallizes in the P4/mcc space group of tetragonal system: a=15.3683(12), c=9.895(2)Å, V=2337.0(5)Å³, C₄₄H₂₉N₄O₁₃S₄Sm, M_r=1100.30, Z=2, D_c=1.564 g/cm³, S=1.063, μ(MoKα)=1.502 mm^-1, F(000)=1102, R=0.0583 and wR=0.1666. Compound 1 is characteristic of a three-dimensional (3-D) framework with a slightly distorted square-antiprism eight-coordinated Sm³⁺ ion. Fluorescent study revealed that compound 1 exhibits an emission in the red region. The fluorescence quantum yield and lifetime of 1 were determined to be 3.5% and 9.1 ns, respectively. UV-vis absorption spectra were also investigated.
- fluorescence,
- hydrothermal,
- lanthanide,
- porphyrin,
- samarium
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