Citation: XIAO Guang-Can. A New Inorganic-organic Hybrid Based on Biisoquinoline and Hexachloridostannate: Structure, Photoluminescence, Electrochemical Behavior and Theoretical Study[J]. Chinese Journal of Structural Chemistry, ;2014, 33(11): 1689-1696. doi: 10.14102/j.cnki.0254-5861.2011-0466 shu

A New Inorganic-organic Hybrid Based on Biisoquinoline and Hexachloridostannate: Structure, Photoluminescence, Electrochemical Behavior and Theoretical Study

XIAO Guang-Can ^,

1.
Testing Center of Fuzhou University, Fuzhou 350002, China

Corresponding author: XIAO Guang-Can,
Received Date: 1 August 2014
Available Online: 10 October 2014

A new inorganic-organic hybrid constructed from biisoquinoline dication and tin halide, [(BIQBT)(SnCl₆)]_n (1, BIQBT=1,4-bis(isoquinoline) butane), has been synthesized and structurally determined by X-ray diffraction method. 1 crystallizes in the monoclinic system, space group C_c with M_r=644.82, a=16.589(3), b=18.388(4), c=8.5532(17)Å, β=108.75(3)°, V=2470.6(9)Å³, Z=4, D_c=1.736 g/cm³, F(000)=1281, μ(MoKα)=1.697 mm^-1, the final R=0.0197 and wR=0.0493 for 4614 observed reflections with I>2σ(I). 1 consists of BIQBT²⁺ dications and mononuclear hexachloridostannate SnCl₆^2- anion, and hydrogen bonds among them contribute to the formation of a 1-D chain. Strong fluorescence can be detected in 1, which was explained by theoretical calculation. Its electrochemical behavior was investigated, and the theoretical calculations reveal that the π…π stacking interaction is dominated for their structural stabilization.
- inorganic-organic hybrid,
- tin halide,
- biisoquinoline,
- electrochemical property,
- DFT calculation
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